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In the case of relatively small Φ′(ICT)/Φ(LE) ratios, such as with PP in PrCN at 25°C (Figure 1a, separation of the LE and ICT contributions to the overall fluorescence spectrum will not necessarily result in accurate values for Φ′(ICT)/Φ(LE, as the outcome of the subtraction will depend on the procedure followed. For the spectral separation in the present paper, the ICT emission band of 4-cyano-N-phenylpyrrole in PrCN has been used, whereas the subtraction employed in ref 4 was based on the LE fluorescence spectrum of 4-methyl-N-phenylpyrrole. Even when the resulting values for Φ′(ICT)/Φ(LE) are not exactly the same (see Table 1 and ref 4, the differences in the slope of the plots of ln(Φ′(ICT, ΦLE, vs the reciprocal temperature are small
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