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In the earlier communication,20 we considered that 1 is adsorbed on kaolin as the MnIV-MnIV state on the basis of the UV-vis diffuse reflectance spectroscopic data. However, we reconsider that the species adsorbed on kaolin is the MnIII-MnIV state from the present Mn K-edge XANES data for the 1/mica hybrid
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IV state from the present Mn K-edge XANES data for the 1/mica hybrid.
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31
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32
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84906384373
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IV complex was not observed up to 100 min under the conditions of 1.0 mM 1 and pH = 1.0 in the present work.
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IV complex was not observed up to 100 min under the conditions of 1.0 mM 1 and pH = 1.0 in the present work.
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33
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84906369997
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- ions was observed after the reaction for a 2 or 3 solution and 2 or 3/clay.
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- ions was observed after the reaction for a 2 or 3 solution and 2 or 3/clay.
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34
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84906384372
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- cannot be adsorbed on mica and kaolin at all. Other cationic decomposed species might be adsorbed on clay, but they are not analyzed sufficiently.
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- cannot be adsorbed on mica and kaolin at all. Other cationic decomposed species might be adsorbed on clay, but they are not analyzed sufficiently.
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35
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84906412952
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IV after 30 min.
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IV after 30 min.
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