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Although the presence of some insignificant inherent stress could not be excluded entirely in α-U, the possible effect of such a microfield on the forthcoming oxidation dynamics was ruled out in this study. This could be assured following stress relief thermal treatment tests, run on reference α-U samples. The annealed (at 350°C for 4 h) samples were tested upon oxidation against the untreated samples. No difference (in the annealed versus the untreated samples) in any of the discussed oxidation phenomena could be spotted
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Although the presence of some insignificant inherent stress could not be excluded entirely in α-U, the possible effect of such a microfield on the forthcoming oxidation dynamics was ruled out in this study. This could be assured following stress relief thermal treatment tests, run on reference α-U samples. The annealed (at 350°C for 4 h) samples were tested upon oxidation against the untreated samples. No difference (in the annealed versus the untreated samples) in any of the discussed oxidation phenomena could be spotted.
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2. This would introduce a major issue in fine reconstruction of oxide line-positions, intensity ratios, and line shapes. Strain at specific directions, if not encoded correctly in Rietvield formalism, might further lower the quality of the fit.
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Card # 72-0125 (Calc.), International Center for Diffraction Data (ICDD), 12 Campus Boulevard, Newtown Square, PA, 2003.
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We note that the spectra presented in Figure 10 were derived by autonormalization of U(112) intensities according to the Beer-Lambert relation, utilized for an oxide film of known X-ray absorption (derived by density adaptation of published59 extinction coefficient of U) and thickness calculated from FTIR reflectance
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59 extinction coefficient of U) and thickness (calculated from FTIR reflectance).
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