Atom transfer radical polymerization of methyl acrylate with PVAc-CCl 3 macroinitiator and a novel synthesis of block terpolymers of PVAc-b-poly(MA-co-MMA)

Iranian Polymer Journal (English Edition)

Volumn 15, Issue 10, 2006, Pages 829-839

  Semsarzadeh, Mohammad Ali ^a   Daronkola, Mohammad Reza Rostami ^a  

^a TARBIAT MODARES UNIVERSITY   (Iran)

Author keywords

Atom transfer radical polymerization; Chemical selective ATRP; Macroinitiator; Methyl acrylate; Terpolymer

Indexed keywords

CATALYSIS; ENTHALPY; MOLECULAR WEIGHT; POLYMERIZATION; RATE CONSTANTS; WAVE PROPAGATION;

ATOM TRANSFER RADICAL POLYMERIZATION; CHEMICAL SELECTIVE ATRP; MACROINITIATORS; METHYL ACRYLATE (MA);

TERPOLYMERS;

EID: 33846026378     PISSN: 10261265     EISSN: 10261265     Source Type: Journal    
DOI: None     Document Type: Article

References (34)

1. Matyjaszewski K., Controlled/living radical polymerization progress in ATAP, NMP and RAFT, ACS Symp. Ser., 768, 2-26, 2000.
2. Matyjaszewski K., Advances in Controlled/living radical polymerization, ACS Symp., Ser., 854, 2-9, 2003.
3. Matyjaszewski K., Xia J., Atom transfer radical polymerization, Chem. Rev.,101, 2921-2990, 2001.
4. Kamigato M., Ando T., Sawamoto M., Metal-catalyzed living radical polymerization, Chem. Rev., 101, 3689-3745, 2001.
5. Ambade A.V., Kumar A., Controlling the degree of branching in vinyl polymerization, Prog. Polym. Sci., 25, 1141-1170, 2000.
6. Coessens V., Pintauer T., Matyjaszewski K., Functional polymers by atom transfer radical polymerization, Prog. Polym. Sci., 26, 337-377, 2001.
7. Sun X., Zhang H., Huang X., Wang X., Zhou Q-F., Synthesis of poly (ethylene oxide)-blockpoly(methyl methacrylate)-block-polystyrene triblock copolymers by two-step atom transfer radical polymerization, Polymer, 46, 5251-5257, 2005.
8. Even M., Haddleton D.M., Kukulj D., Synthesis and characterization of amphiphilic triblock polymers by copper mediated living radical polymerization, Eur. Polym. J., 39, 633-639, 2003.
9. Semsarzadeh M.A., Mirzaei A., Telomerization of vinyl acetate with chloroform and block copolymerization of vinylacetate and methylacrylate by atom transfer radical polymerization, Iran. Polym. J., 12, 67-75, 2003.
10. Destarac M., Pees B., Boutevin B., Radical telomerization of vinyl acetate with chloroform. Applications to the synthesis of poly(vinyl acetate)-block-polystyrene copolymers by consecutive telomerization and atom transfer radical polymerization, Macromol. Chem. Phys., 201, 1189-1199, 2000.
11. Semsarzadeh M.A., Mirzaei A., Vasheghani-Farahani E., Nekoomanesh Haghighi M., Atom transfer radical polymerization of (meth)acrylates and their novel block copolymers with vinylacetate, Eur. Polym. J., 39, 2193-2201, 2003.
12. Garcia F.G., Pinto M.R., Soares B.G., Grafting of polymethyl methacrylate from poly(ethylene-covinylacetate) copolymer using atom transfer radical polymerization, Eur. Polym. J., 38, 759-769, 2002.
13. Batt-Coutrot D., Haddleton D.M., Jarvis A.P., Kelly R.L., Synthesis and properties of amphiphilic vinylacetate triblock copolymers prepared by copper mediated living radical polymerization, Eur. Polym. J., 39, 2243-2252, 2003.
14. Chatterjee D.P., Mandal B.M., Facile atom transfer radical homo and block copolymerization of higher alkyl methacrylates at ambient temperature using CuCl/PMDETA/quaternaryammonium halide catalyst system, Polymer, 47, 1812-1819, 2006.
15. Krishnan R., Srinivasan K.S.V., Homo and block copolymers of tert-butyl methacrylate by atom transfer radical polymerization, Eur. Polym. J., 40, 2269-2276, 2004.
16. Yina M., Habichera W.D., Voit B., Preparation of functional poly(acrylates and methacrylates) and block copolymers formation based on polystyrene macroinitiator by ATRP, Polymer, 46, 3215-3222, 2005.
17. Ramakrishnan A., Dhamodharan R., Facile synthesis of ABC and CBABC multiblock copolymers of styrene, tert-Butyl acrylate, and methyl methacrylate via room temperature ATRP of MMA, Macromolecules, 36, 1039-1046, 2003.
18. Xia J., Paik J.H., Matyjaszewski K., Polymerization of vinyl acetate promoted by iron complex, Macromolecules, 32, 8310-8314, 1999.
19. Debuigne A., Caille J-R., Jérôme R., Synthesis of end-functional poly(vinyl acetate) by cobalt-Mediated radical polymerization, Macromolecules, 38, 5452-5458, 2005.
20. o ratio on atom transfer radical polymerization of n-butyl acrylate, J. Polym. Sci. Pol. Chem., 42, 3285-3292, 2004.
21. Xu W., zhu X., Cheng Z., Chen J., Atom transfer radical polymerization of lauryl methacrylate, J. Appl. Polym. Sci., 90, 1117-1125, 2003.
22. Zhang H., Van Deer Linde R., Atom transfer radical polymerization of n-butyl acrylate catalyzed by CuBr / N-(n-hexyl)-2-pyridylmethanimine, J. Polym. Sci. Pol. Chem., 40, 3549-3561, 2002.
23. Berger K.C., Brandrup G., Polymer Handbook. 4th ed., Wiley InterScience, New York, 1999.
24. Davis K.A., Paik H-j., Matyjaszewski K., Kinetic investigation of the atom transfer radical polymerization of methyl acrylate, Macromolecules, 32, 1767-1776, 1999.
25. Zhu C., Sun F., Zhang M., Jin J., Atom transfer radical suspension polymerization of methyl methacrylate catalyzed by CuCl/bpy, Polymer, 45, 1141-1146, 2004.
26. Bisht H.S., Ray S.S., Chatterjee A.K., Resonance, polar and steric effects of substituent on monomer reactivity in radical polymerization of alkyl 4-vinylbenzoate and butyl acrylate, J. Polym. Sci. Pol. Chem., 41, 1864-1866, 2003.
27. Matyjaszewski K., Structural-reactivity correlation in atom transfer radical polymerization, Macromol. Symp., 182, 209-224, 2002.
28. Kelen T., Tüdös F., Analysis of the linear methods for determining copolymerization reactivity ratios. I. A new improved linear graphic method, J. Macromol. Sci. Chem., A9(1), 1-27, 1975.
29. Fineman M., Ross S.D., Linear method for determination monomer reactivity ratios in copolymerization, J. Polym. Sci., 5, 259-262, 1950.
30. Demirelli K., Coskun M., Kaya E., Polymers based on benzyl methacrylates synthesis via atom transfer radical polymerization, characterization, and thermal stabilities, J. Polym. Sci. Pol. Chem., 42, 5964-5973, 2004.
31. 1HNMR, Eur. Polym. J., 39, 1413-1420, 2003.
32. Isobel Y., Nakano T., Okamoto Y., Stereocontrol during the free-radical polymerization of methacrylates with Lewis acids, J. Polym. Sci. Pol. Chem., 39, 1463-1471, 2001.
33. Fuente J.L., Fernandez-García M., Fernandez-Sanz M., Madruga E.L., A comparative study of methyl methacrylate/butyl acrylate copolymerization kinetics by atom-transfer and conventional radical polymerization, Macromol. Rapid. Commun., 22, 1415-1421, 2001.
34. Roos S.G., Muller A.H.E., Copolymerization of n-Butyl Acrylate with methyl methacrylate and PMMA macromonomers: comparison of reactivity ratios in conventional and atom transfer radical copolymerization, Macromolecules, 32, 8331-8335, 1999.