Order and anti-order in olivine I: Structural response to temperature

European Journal of Mineralogy

Volumn 18, Issue 6, 2006, Pages 673-689

  Heinemann, Rolf ^a   Kroll, Herbert ^a   Kirfel, Armin ^b   Barbier, Bruno ^b  

^a UNIVERSITY OF MÜNSTER   (Germany)

^b Mineralogisch Petrologisches Institut   (Germany)

Author keywords

Anti order; Distortion; Geospeedometry; Olivine; Order; Solid solution; Thermal expansion

Indexed keywords

BOND LENGTH; DISTORTION (WAVES); OLIVINE; POSITIVE IONS; SINGLE CRYSTALS; SOLID SOLUTIONS; TEMPERATURE DISTRIBUTION; THERMAL EXPANSION; X RAY DIFFRACTION ANALYSIS;

ANTI-ORDER; DISTORTION PARAMETERS; ELEVATED TEMPERATURE; EQUILIBRIUM DISTRIBUTIONS; GEOSPEEDOMETRY; OCTAHEDRAL DISTORTION; ORDER; TEMPERATURE DEPENDENCE;

CRYSTAL STRUCTURE;

CRYSTAL STRUCTURE; OLIVINE; SOLID SOLUTION; STRUCTURAL RESPONSE; THERMAL EXPANSION; X-RAY DIFFRACTION;

AFRICA; EAST AFRICA; ETHIOPIA; SUB-SAHARAN AFRICA;

EID: 33846025812     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/0935-1221/2006/0018-0673     Document Type: Article

References (53)

1. Aikawa, N., Kumazawa, M., Tokonami, M. (1985): Temperature dependence of intersite distribution of Mg and Fe in olivine and the associated change of lattice parameters. Phys. Chem. Minerals, 12, 1-8.
2. Akamatsu, T. & Kumazawa, M. (1993): Kinetics of intracrystalline cation redistribution in olivine and its implication. Phys. Chem. Minerals, 19, 423-430.
3. Artioli, G., Rinaldi, R., Wilson, C., Zanazzi, P.F. (1995): High-temperature Fe-Mg cation partitioning in olivine: In situ single-crystal neutron diffraction study. Am. Mineral., 80, 197-200.
4. Becker, P.J. & Coppens, P. (1974): Extinction within the limit of validity of the Darwin transfer equations. I. General formalism for primary and secondary extinction and their application to spherical crystals. Acta Cryst., A30, 129-147.
5. Bocquet, J.L., Brébec, G., Limoge, Y. (1983): Diffusion in metals and alloys. in R.W. Cahn & P. Haasen, Eds., Physical Metallurgy (3rd edition), p. 385-475. North-Holland Physics Publishing, Amsterdam.
6. 2+,Mg-Verteilung in synthetischen Olivinen mit IR-Spektroskopie. Diplomarbeit, Westfälische Wilhelms-Universität Münster, 126 pp.
7. Brotzu, P., Morbidelli, L., Piccirillo, E.M., Traversa, G. (1980): Volcanological and magmatological evidences of Boseti Complex (Main Ethiopian Rift). in "Geodynamic Evolution of the Afro-Arabic Rift System". Atti dei Convegni dei Lincei. Acc. Naz. Dei Lincei 4, 47, 317-366.
8. Brown, G.E. Jr (1980): Olivines and silicate spinels. in Orthosilicates. Reviews in Mineralogy, Vol. 5, Mineralogical Society of America.
9. Brown, G.E. Jr & Prewitt, C.T. (1973): High temperature crystal chemistry of hortonolite. Am. Mineral., 58, 577-587.
10. Buening, D.K. & Buseck, P.R. (1973): Fe-Mg lattice diffusion in olivine. Journ. Geophys. Research, 78, 6852-6862.
11. Chakraborty, S. (1997): Rates and mechanisms of Fe-Mg interdiffusion in olivine at 980-1300 °C. Journ. Geophys. Res., 102, 12317-12331.
12. 4 olivine. Am. Mineral., 81, 1519-1522.
13. Cromer, D.T. & Waber, J.T. (1974): Atomic scattering factors for X-rays. in International tables for X-ray crystallography, Vol. IV, J.A. Ibers and W.A. Hamilton, eds., Kynoch, Birmingham.
14. Doyle, P.A. & Turner, P.S. (1968): Relativistic Hartree-Fock X-ray and electron scattering factors. Acta Cryst., A24, 390-397.
15. Eichhorn, K. (1987a): REDUCE. Program for data reduction of stepscan measured reflection profiles of both neutron and X-rays. HASYLAB/DESY, Hamburg, Germany. Unpublished.
16. Eichborn, K. (1987b): ABSCOR. Absorption correction of four-circle diffractometer data. Revised and updated from Coppens (1968). HASYLAB/ DESY, Hamburg, Germany. Unpublished.
17. Finger, L.W. & Prince, E. (1975): A system of FORTRAN IV computer programs for crystal structural computations. NBS Tech. Note, 854.
18. Freiheit V., Heinemann R., Kroll H., Krane H.-G., Kirfel A. (2000) Thermal history of natural olivines from the temperature dependent cation distribution determined by laboratory and synchroton radiation X-ray diffraction. HASYLAB Annual Report 2000.
19. Ganguly, J. (1982): Mg-Fe order-disorder in ferromagnesian silicates. II. Thermodynamics, kinetics, and geological implications. in Advances in Physical Geochemistry, Vol. 2, S.K. Saxena, ed., Springer, New York, 58-99.
20. 2+-Mg interdiffusion in orthopyroxene: retrieval from the data on intracrystalline exchange reaction. Am. Mineral., 79, 930-937.
21. Ganguly, J., Yang, H., Ghose, S. (1994): Thermal history of mesosiderites: Quantitative constraints from compositional zoning and Fe-Mg ordering in orthopyroxenes. Geochim. Cosmochim. Acta, 58, 2711-2723.
22. Hazen, R.M. & Navrotsky, A. (1996): Effects of pressure on order-disorder reactions. Am. Mineral., 81, 1021-1035.
23. Heinemann, R., Staack, V., Fischer, A., Kroll, H., Vad, Th., Kirfel, A. (1999): Temperature dependence of Fe,Mg partitioning in Acapulco olivine. Am. Mineral., 84, 1400-1405.
24. 2+,Mg fractionation in Johnstown meteoritic orthopyroxene. Eur. J. Mineral., 12, 163-176.
25. 2+,Mg-Verteilung in Olivinen. Berichte der Deutschen Mineral. Gesellschaft, Beih. zum Eur. J. Mineral., 15, 78, No 1.
26. Henderson, C.M.B., Knight, K.S., Redfern, S.A.T., Wood, B.J. (1996): High-temperature study of cation exchange in olivine by neutron powder diffraction. Science, 271, 1713-1715.
27. Henderson, C.M.B., Redfern, S.A.T., Smith, R.I., Knight, K.S., Charnock, J.M. (2001): Composition and temperature dependence of cation ordering in Ni-Mg olivine solid solutions: a time-of-flight neutron powder diffraction and EXAFS study. Am. Mineral., 86, 1170-1187.
28. 2. Acta Cryst., A39, 268-269.
29. Kirfel, A. (1993) RINTAN. Interne R-Werte von äquivalenten und multiplen Reflexen. Universität Würzburg, Germany. Unpublished.
30. Kirfel, A. (1996): Cation distributions in olivines and orthopyroxenes. An interlaboratory study. Phys. Chem. Minerals, 19, 503-519.
31. Kroll, H. (2003) Rate equations for non-convergent order-disorder processes - a review and application to orthopyroxene. Eur. J. Min., 15, 7-19.
32. 2+,Mg distribution in orthopyroxene: A critical assessment of its potential as a geospeedometer. Eur. J. Mineral., 9, 705-733.
33. Lager, G.A. & Meagher, E.P. (1978): High-temperature structural study of six olivines. Am. Mineral., 63, 365-377.
34. 5 at 293 K. Acta Cryst., B53, 870-879.
35. 2+-distribution in synthetic olivine (fa50 fo50). Berichte der Deutschen Mineral. Gesellschaft, Beih. zum Eur. J. Mineral., 13, 127, No 1.
36. 50). Eur. J. Mineral., 17, 495-500
37. Mueller, R.F. (1967): Model for order-disorder kinetics in certain quasi-binary crystals of continuously variable composition. J. Phys. Chem. Solids, 28, 2239-2243.
38. Mueller, R.F. (1969): Kinetics and thermodynamics of intracrystalline distributions. Min. Soc. America, Special Paper, 2, 83-93.
39. North, A.C.T., Phillips, D.C., Mathews, F.S. (1968): A semi-empirical method of absorption correction. Acta Cryst., A24, 351-359.
40. 2+ in olivines. Phys. Chem., Minerals, 17, 301-312.
41. 2+ intracrystalline distribution in olivines. Mineral. Petrol., 43, 121-129.
42. Redfern, S.A.T., Henderson, C.M.B., Wood, B.J., Harrison, R.J., Knight, K.S. (1996): Determination of olivine cooling rates from metal-cation ordering. Nature, 381, 407-409.
43. 4 olivines: An in situ neutron diffraction study. Eur. J. Mineral., 9, 287-300.
44. 4 (Fa50). Phys. Chem. Minerals, 27, 630-637.
45. Rinaldi, R. Artioli, G., Wilson, C.C., McIntyre, G. (2000): Octahedral cation ordering in olivine at high temperature. I: In situ neutron single-crystal diffraction studies on natural mantle olivines. (Fa12 and Fa10), Phys. Chem. Minerals, 27, 623-629.
46. Robinson, K., Gibbs, G.V., Ribbe, P.H. (1971) Quadratic elongation: A quantitative measure of distortion in coordination polyhedra. Science, 172, 567-570.
47. Scheufler, C., Engel, K.V., Kirfel, A. (1997): An improved gas-stream heating device for a single-crystal diffractometer. Journ. Appl. Cryst., 30, 411-412.
48. Smyth, J.R. (1975): High temperature crystal chemistry of fayalite. Am. Mineral., 60, 109-1097.
49. Smyth, J.R. & Hazen, R.M. (1973): The crystal structures of forsterite and hortonolite at several temperatures up to 900 °C. Am. Mineral., 58, 588-593.
50. 4]. Diploma Thesis, Mineralogisches Institut der Universität Bonn, 87 pp
51. 4. Zeitschrift für Kristallographie, Supplement Issue No. 21, 82
52. Thompson, J.B. Jr. (1969): Chemical reactions in crystals. Am. Mineral., 54, 341-375.
53. Thompson, J.B. Jr. (1970): Chemical reactions in crystals: Corrections and clarification. Am. Mineral., 55, 528-532.