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note
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In our case 5% Rh-C14c as a catalyst resulted in a too fast reduction and in addition to the desired secondary amine, also the corresponding primary amine was obtained
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44
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33846001121
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Due to steric reasons, in these particular cases the secondary amines react less smoothly with the 4-nitrophenyl active ester of CMPO. Therefore the Arbuzov reaction has been used
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Due to steric reasons, in these particular cases the secondary amines react less smoothly with the 4-nitrophenyl active ester of CMPO. Therefore the Arbuzov reaction has been used
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45
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33845996699
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