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Volumn 17, Issue 8, 2006, Pages 1501-1515

A perspective on applications of ligand-field analysis: Inspiration from electron paramagnetic resonance spectroscopy of coordination complexes of transition metal ions

Author keywords

Coordination chemistry; EPR; Ligand field theory; Spectroscopy

Indexed keywords


EID: 33845753824     PISSN: 01035053     EISSN: 16784790     Source Type: Journal    
DOI: 10.1590/S0103-50532006000800005     Document Type: Conference Paper
Times cited : (35)

References (97)
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    • In Hungarian his name is Teller Ede; another Hungarian whose work is important in this area, and did receive the Nobel Prize (Physics 1963) is Eugene Wigner, Wigner Jeno in Hungarian.
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    • (2005) ORCA, Version 2.4.41
    • Neese, F.1
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    • note
    • The discovery of NMR by Felix Bloch and co-workers and Edward M. Purcell in 1946 was recognized by the Nobel Prize in Physics in 1952, however, no such recognition for the discovery of EPR in 1944 by E. Zavoisky in Kazan, USSR was ever made.
  • 47
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    • note
    • -27 J/T.
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    • note
    • 12 Table 7.22 for equations analogous to 1, including those for hyperfine coupling.
  • 54
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    • Heinrich-Heine-Universität: Düsseldorf, Germany
    • Adamsky, H.; AOMX, Heinrich-Heine-Universität: Düsseldorf, Germany, 1994. See the URL: http://www.aomx.de/docs/html/aomxeh.html.
    • (1994) AOMX
    • Adamsky, H.1
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    • note
    • -1, due to the strongly covalent tetrapyrrole ligand.
  • 61
    • 85088888783 scopus 로고    scopus 로고
    • note
    • III complexes with unsaturated N4 donor sets, such as tetrapyrroles, in many cases.
  • 68
    • 85039143491 scopus 로고    scopus 로고
    • note
    • -1 (100%) are needed for the Br and I complex, respectively, but give the opposite sign of D in both cases (calculated to be positive as with the Cl complex, but experimentally negative).
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    • personal communication
    • B. R. McGarvey, personal communication.
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    • note
    • 12 these terms are referred to by the Γ notation, which was originally used by Bethe. It is more enlightening to give the group theory designations (A, B, E, T (or F)), which are due originally to Robert S. Mulliken.
  • 74
    • 85039142744 scopus 로고    scopus 로고
    • note
    • The symbol λ is often used to indicate the rhombicity, |E/D|, however, this can cause confusion with the multi-electron spin-orbit coupling constant, and is avoided here.
  • 76
    • 85088903150 scopus 로고    scopus 로고
    • note
    • S = ±5/2, so the case is equivalent to 5 = 3/2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.