Origin of convex tetrads in rare earth element patterns of hydrothermally altered siliceous igneous rocks from the Zinnwald Sn-W deposit, Germany

Geochimica et Cosmochimica Acta

Volumn 71, Issue 2, 2007, Pages 335-353

  Monecke, T ^a   Dulski, P ^b   Kempe, U ^c  

^a UNIVERSITY OF OTTAWA   (Canada)

^b GFZ GERMAN RESEARCH CENTRE FOR GEOSCIENCES   (Germany)

^c TU BERGAKADEMIE FREIBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ARGILLITE; FRACTIONAL CRYSTALLIZATION; GRANITE; GREISENIZATION; HYDROTHERMAL ALTERATION; HYDROTHERMAL FLUID; IGNEOUS ROCK; PETROLOGY; RARE EARTH ELEMENT;

CENTRAL EUROPE; EURASIA; EUROPE; GERMANY;

EID: 33845735516     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2006.09.010     Document Type: Article

References (66)

1. Anders E., and Grevesse N. Abundances of the elements: meteoritic and solar. Geochim. Cosmochim. Acta 53 (1989) 197-214
2. Bau M. Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems: evidence from Y/Ho, Zr/Hf, and lanthanide tetrad effect. Contrib. Mineral. Petrol. 123 (1996) 323-333
3. Bau M. The lanthanide tetrad effect in highly evolved felsic igneous rocks - a reply to the comment by Y. Pan. Contrib. Mineral. Petrol. 128 (1997) 409-412
4. Breiter K. The Teplice rhyolite (Krušné Hory Mts., Czech Republic)-chemical evidence of a multiply exhausted stratified magma chamber. Bull. Czech Geol. Surv. 72 (1997) 205-213
5. Cocherie, A., Johan, V., Rossi, P., Štemprok, M., 1991. Trace element variations and lanthanide tetrad effect studied in a Variscan lithium albite granite: case of the Cinovec granite (Czechoslovakia) [abstract]. In: Pagel, M., Leroy, J.L. (Eds.), Source, Transport and Deposition of Metals. Balkema, pp. 745-749.
6. Dolejš D., and Štemprok M. Magmatic and hydrothermal evolution of Li-F granites: Cínovec and Krásno intrusions, Krušné Hory batholith, Czech Republic. Bull. Czech Geol. Surv. 76 (2001) 77-99
7. Dostal J., and Chatterjee A.K. Origin of topaz-bearing and related peraluminous granites of the Late Devonian Davis Lake pluton, Nova Scotia, Canada: crystal versus fluid fractionation. Chem. Geol. 123 (1995) 67-88
8. Dulski P. Interferences of oxide, hydroxide and chloride analyte species in the determination of rare earth elements in geological samples by inductively coupled plasma-mass spectrometry. Fresenius J. Anal. Chem. 350 (1994) 194-203
9. Dulski P. Reference materials for geochemical studies: new analytical data by ICP-MS and critical discussion of reference values. Geostand. Newsl. 25 (2001) 87-125
10. Ďurišová J., Charoy B., and Weisbrod A. Fluid inclusion studies in minerals from tin and tungsten deposits in the Krušné Hory mountains (Czechoslovakia). Bull. Minéral. 102 (1979) 665-675
11. Förster H.J. The chemical composition of REE-Y-Th-U-rich accessory minerals in peraluminous granites of the Erzgebirge-Fichtelgebirge region, Germany, Part I: the monazite-(Ce)-brabantite solid solution series. Am. Mineral. 83 (1998) 259-272
12. Förster, H.J., Tischendorf, G., 1994. The western Erzgebirge-Vogtland granites: implications to the Hercynian magmatism in the Erzgebirge-Fichtelgebirge anticlinorium [abstract]. In: Seltmann, R., Kämpf, H., Möller, P. (Eds.), Metallogeny of Collisional Orogens Focussed on the Erzgebirge and Comparable Metallogenic Settings, Czech Geological Survey, pp. 35-48.
13. Govindaraju K. 1994 compilation of working values and sample description for 383 geostandards. Geostand. Newsl. 18 (1994) 1-158 (special issue)
14. Haichen L., Ying L., and Zhanxia Z. Determination of ultra-trace rare earth elements in chondritic meteorites by inductively coupled plasma mass spectrometry. Spectrochim. Acta 53 (1997) 1399-1404
15. Heinrich C.A., Günther D., Audétat A., Ulrich T., and Frischknecht R. Metal fractionation between magmatic brine and vapor, determined by microanalysis of fluid inclusions. Geology 27 (1999) 755-758
16. Irber W. The lanthanide tetrad effect and its correlation with K/Rb, Eu/Eu*, Sr/Eu, Y/Ho, and Zr/Hf of evolving peraluminous granite suites. Geochim. Cosmochim. Acta 63 (1999) 489-508
17. Jahn B., Wu F., Capdevila R., Martineau F., Zhao Z., and Wang Y. Highly evolved juvenile granites with tetrad REE patterns: the Woduhe and Baerzhe granites from the Great Xing'an Mountains in NE China. Lithos 59 (2001) 171-198
18. Johan V., and Johan Z. Accessory minerals of the Cínovec (Zinnwald) granite cupola, Czech Republic. Part 1: Nb-, Ta- and Ti-bearing oxides. Mineral. Petrol. 51 (1994) 323-343
19. Kawabe I. Tetrad effects and fine structures of REE abundance patterns of granitic and rhyolitic rocks: ICP-AES determinations of REE and Y in eight GSJ reference rocks. Geochem. J. 29 (1995) 213-230
20. Kempe U., and Goldstein S. Eu anomalies, tetrad effect and HREE enrichment in fluorites from Sn deposits: Evidence for two source mixing and phase separation [abstract]. J. Czech Geol. Soc. 42 (1997) 37
21. Kempe U., and Götze J. Cathodoluminescence (CL) behaviour and crystal chemistry of apatite from rare-metal deposits. Mineral. Mag. 66 (2002) 151-172
22. Kempe, U., Gruner, T., Renno, A.D., Wolf, D., 1997. Hf-rich zircons in rare-metal bearing granites: magmatic or metasomatic origin? [abstract]. In: Papunen, H. (Ed.), Mineral Deposits: Research and Exploration Where do They Meet? Balkema, pp. 643-646.
23. Kempe U., Wolf D., and Sala M. Members of the philipsbornite-florencite and chernovite-xenotime solid solution series in metasomatic altered granites of the Zinnwald tin deposit (Erzgebirge, Germany) [abstract]. Beih. 1 Eur. J. Mineral. 11 (1999) 120
24. Lee S.G., Masuda A., and Kim H.S. An early Proterozoic leuco-granitic gneiss with the REE tetrad phenomenon. Chem. Geol. 114 (1994) 59-67
25. Liang Q., and Grégoire D.C. Determination of trace elements in twenty six Chinese geochemistry reference materials by inductively coupled plasma-mass spectrometry. Geostand. Newsl. 24 (2000) 51-63
26. Lobin, M., 1986. Time Sequence and Related Evolution of Permocarbonian Sedimentary Rocks in the Eastern and Central Erzgebirge [in German]. Unpubl. Ph.D. Thesis Bergakademie Freiberg, 63 p.
27. Masau M., Černý P., and Chapman R. Dysprosian xenotime-(Y) from the Annie Claim #3 granitic pegmatite, southeastern Manitoba, Canada: evidence of the tetrad effect?. Can. Mineral. 38 (2000) 899-905
28. Masuda A., and Akagi T. Lanthanide tetrad effect observed in leucogranites from China. Geochem. J. 23 (1989) 245-253
29. Masuda A., Kawakami O., Dohmoto Y., and Takenaka T. Lanthanide tetrad effects in nature: two mutually opposite types, W and M. Geochem. J. 21 (1987) 119-124
30. McLennan S.M. Rare earth element geochemistry and the "tetrad" effect. Geochim. Cosmochim. Acta 58 (1994) 2025-2033
31. Meisel T., Schöner N., Paliulionyte V., and Kahr E. Determination of rare earth elements, Y, Th, Zr, Hf, Nb and Ta in geological reference materials G-2, G-3, SCo-1 and WGB-1 by sodium peroxide sintering and inductively coupled plasma-mass spectrometry. Geostand. Newsl. 26 (2002) 53-61
32. Möller, P., 1998. Eu anomalies in hydrothermal minerals: Kinetic versus thermodynamic interpretation [abstract]. In: Hagni, R.D. (Ed.), Proceedings of the Ninth Quadrennial IAGOD Symposium, Schweizerbart'sche Verlagsbuchhandlung, pp. 239-246.
33. Möller P., and Muecke G.K. Significance of europium anomalies in silicate melts and crystal-melt equilibria: a re-evaluation. Contrib. Mineral. Petrol. 87 (1984) 242-250
34. Monecke T., Monecke J., Mönch W., and Kempe U. Mathematical analysis of rare earth element patterns of fluorites from the Ehrenfriedersdorf tin deposit, Germany: evidence for a hydrothermal mixing process of lanthanides from two different sources. Mineral. Petrol. 70 (2000) 235-256
35. Monecke T., Kempe U., Monecke J., Sala M., and Wolf D. Tetrad effect in rare earth element distribution patterns: a method of quantification with application to rock and mineral samples from granite-related rare metal deposits. Geochim. Cosmochim. Acta 66 (2002) 1185-1196
36. Monecke, T., Kempe, U., Monecke, J., 2003. Comment on the paper "W- and M-type tetrad effects in REE patterns for water-rock systems in the Tono uranium deposit, central Japan" by Takahasi, Y., Yoshida, H., Sato, N., Hama, K., Yusa, Y., Shimizu, H. Chem. Geol. 202, 183-184.
37. Müller A., Breiter K., Seltmann R., and Pécskay Z. Quartz and feldspar zoning in the eastern Erzgebirge volcano-plutonic complex (Germany, Czech Republic): evidence of multiple magma mixing. Lithos 80 (2005) 201-227
38. Münker C. Nb/Ta fractionation in a Cambrian arc/back arc system, New Zealand: source constraints and application of refined ICPMS techniques. Chem. Geol. 144 (1998) 23-45
39. Pälchen, W., 1968. Geochemistry and petrology of post-collisional magmatites in the Variscan Eastern Erzgebirge, Saxony [in German]. Unpubl. Ph.D. Thesis Bergakademie Freiberg, 142 p.
40. Pan Y. Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems: evidence from Y/Ho, Zr/Hf, and lanthanide tetrad effect-a discussion of the article by M. Bau (1996). Contrib. Mineral. Petrol. 128 (1997) 405-408
41. Pan Y., and Breaks F.W. Rare-earth elements in fluorapatite, Separation Lake area, Ontario: evidence for S-type granite-rare-element pegmatite linkage. Can. Mineral. 35 (1997) 659-671
42. Peppard D.F., Mason G.W., and Lewey S. A tetrad effect in the liquid-liquid extraction ordering of lanthanides (III). J. Inorg. Nucl. Chem. 31 (1969) 2271-2272
43. Raimbault L., Baumer A., Dubru M., Benkerrou C., Croze V., and Zahm A. REE fractionation between scheelite and apatite in hydrothermal conditions. Am. Mineral. 78 (1993) 1275-1285
44. Robinson P., Townsend A.T., Yu Z., and Münker C. Determination of scandium, yttrium and rare earth elements in rocks by high resolution inductively coupled plasma-mass spectrometry. Geostand. Newsl. 23 (1999) 31-46
45. Rub A.K., Štemprok M., and Rub M.G. Tantalum mineralization in the apical part of the Cínovec (Zinnwald) granite stock. Mineral. Petrol. 63 (1998) 199-222
46. Sala, M., 1999. Geochemical and Mineralogical Investigations on Altered Rocks from the Upper Part of the Zinnwald Deposit, Eastern Erzgebirge [in German]. Unpubl. Ph.D. Thesis TU Bergakademie Freiberg, 96 p.
47. Seltmann, R., Breiter, K., 1995. Late-Variscan crustal evolution and related tin-tungsten mineralization in the Altenberg-Teplice caldera (eastern Erzgebirge). In: Breiter, K., Seltmann, R. (Eds.), Ore Mineralizations of the Krušné Hory Mts (Erzgebirge), Czech Geological Survey, pp. 65-76.
48. Seltmann, R., Breiter, K., Schilka, W., Benek, R., 1996. The Altenberg-Teplice caldera: reversed zonation of a stratified magma chamber [abstract]. In: Lippolt, H.J. et al. (Eds.), V.M. Goldschmidt Conference Heidelberg. Journal of Conference Abstracts, Cambridge Publications, p. 556.
49. Seltmann, R., Förster, H.J., Gottesmann, B., Sala, M., Wolf, D., Štemprok, M., 1998. The Zinnwald greisen deposit related to post-collisional A-type silicic magmatism in the Variscan eastern Erzgebirge/Krušné Hory. In: Breiter, K. (Ed.), Genetic Significance of Phosphorus in Fractionated Granites. Excursion Guide International Conference IGCP Project 373 in Perslak, Czech Geological Survey, pp. 33-50.
50. Štemprok M. The origin of tin-tungsten mineralization in the Erzgebirge [in German]. Mineral. Deposita 2 (1967) 102-118
51. Štemprok M., and Šulcek Z. Geochemical profile through an ore-bearing lithium granite. Econ. Geol. 64 (1969) 392-404
52. Štemprok, M., Seltmann, R., Breiter, K., 1995. The Cínovec/Zinnwald Sn-W-Li deposit. In: Breiter, K., Seltmann, R. (Eds.), Ore Mineralizations of the Krušné Hory Mts (Erzgebirge), Czech Geological Survey, pp. 77-83.
53. Štemprok M., Holub F.V., and Novák J.K. Multiple magmatic pulses of the eastern volcano-plutonic complex, Krušné Hory/Erzgebirge batholith, and their phosphorus contents. Bull. Geosci. 78 (2003) 277-296
54. Takahashi T., and Kawabe I. Lanthanide tetrad effects in Naegi granite and pegmatite, central Japan [abstract]. Geochim. Cosmochim. Acta 67 Suppl. (2003) A469
55. Takahashi Y., Yoshida H., Sato N., Hama K., Yusa Y., and Shimizu H. W- and M-type tetrad effects in REE patterns for water-rock systems in the Tono uranium deposit, central Japan. Chem. Geol. 184 (2002) 311-335
56. Takahashi Y., Amano K., Hama K., Mizuno T., Yoshida H., and Shimizu H. Reply to the comment by T. Monecke, U. Kempe and J. Monecke on "W- and M-type tetrad effects in REE patterns for water-rock systems in the Tono uranium deposit, central Japan". Chem. Geol. 202 (2003) 185-189
57. Thomas R., Förster H.J., Rickers K., and Webster J.D. Formation of extremely F-rich hydrous melt fractions and hydrothermal fluids during differentiation of highly evolved tin-granite magmas: a melt/fluid-inclusion study. Contrib. Mineral. Petrol. 148 (2005) 582-601
58. Tomlinson K.Y., Hughes D.J., Thurston P.C., and Hall R.P. Plume magmatism and crustal growth at 2.9 to 3.0 Ga in the Steep Rock and Lumby Lake area, western Superior Province. Lithos 46 (1999) 103-136
59. Veksler I.V., Dorfman A.M., Kamenetsky M., Dulski P., and Dingwell D.B. Partitioning of lanthanides and Y between immiscible silicate and fluoride melts, fluorite and cryolite and the origin of the lanthanide tetrad effect in igneous rocks. Geochim. Cosmochim. Acta 69 (2005) 2847-2860
60. Webster J., Thomas R., Förster H.J., Seltmann R., and Tappen C. Geochemical evolution of halogen-enriched granite magmas and mineralizing fluids of the Zinnwald tin-tungsten mining district, Erzgebirge, Germany. Mineral. Deposita 39 (2004) 452-472
61. Wolf L. Drilling the coal occurrence at Schönfeld, eastern Erzgebirge [in German]. Z. Angew. Geol. 6 (1960) 341-344
62. Wolf D., Rene M., and Kempe U. New occurrences of brabandite in Sn-granites of the Erzgebirge and the Slavkovsky les [in German, abstract]. Beih. 1 Eur. J. Mineral. 14 (2002) 177
63. Wood S.A. The geochemistry of rare earth elements and yttrium in geothermal waters. SEG Spec. Pub. 10 (2003) 133-158
64. Yu Z., Robinson P., and McGoldrick P. An evaluation of methods for the chemical decomposition of geological materials for trace element determination using ICP-MS. Geostand. Newsl. 25 (2001) 199-217
65. Yurimoto H., Duke E.F., Papike J.J., and Shearer C.K. Are discontinuous chondrite-normalized REE patterns in pegmatitic granite systems the results of monazite fractionation?. Geochim. Cosmochim. Acta 54 (1990) 2141-2145
66. Zhao J.X., and Cooper J.A. Fractionation of monazite in the development of V-shaped REE patterns in leucogranite systems: evidence from a muscovite leucogranite body in central Australia. Lithos 30 (1993) 23-32