Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems: Evidence from Y/Ho, Zr/Hf, and lanthanide tetrad effect

Contributions to Mineralogy and Petrology

Volumn 123, Issue 3, 1996, Pages 323-333

  Bau, Michael ^a  

^a GFZ GERMAN RESEARCH CENTRE FOR GEOSCIENCES   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS SYSTEM; FRACTIONATION; LANTHANIDE; MAGMATIC SYSTEM; REE; TETRAD EFFECT; TRACE ELEMENT;

EID: 0030435734     PISSN: 00107999     EISSN: None     Source Type: Journal    
DOI: 10.1007/s004100050159     Document Type: Article

References (67)

1. 2O]: implication for a new geochemical index. Geochim Cosmochim Acta 57: 2899-2905
2. Anders E, Grevesse N (1989) Abundances of the elements: meteoritic and solar. Geochim Cosmochim Acta 53: 197-214
3. Bau M, Dulski P (1995) Comparative study of yttrium and rare-earth element behaviours in fluorine-rich hydrothermal fluids. Contrib Mineral Petrol 119: 213-223
4. Bau M, Dulski P (1996) Distribution of yttrium and rare-earth elements in the Penge and Kuruman Iron-Formations. Transvaal Supergroup, South Africa. Precambrian Res (in press)
5. Bau M, Dulski P, Möller P (1995) Yttrium and Holmium South Pacific seawater: vertical distribution and possible fractionation mechanisms. Chem Erde 55: 1-15
6. Bau M, Koschinsky A, Dulski P, Hein JR (1996) Comparison of the partitioning behaviours of titanium, yttrium, and rare-earth elements between hydrogenetic marine ferromanganese crusts and seawater. Geochim Cosmochim Acta (in press)
7. Beattie P (1994) Systematics and energetics of trace-element partitioning between olivine and silicate melts: implications for the nature of mineral/melt partitioning. Chem Geol 117: 57-71
8. Blundy J, Wood B (1994) Prediction of crystal-melt partition coefficients from elastic moduli. Nature 372: 452-454
9. 4SCN - Adogen-464SCN extraction system. Radiochim Acta 56: 31-35
10. Boswell SM, Elderfield H (1988) The determination of zirconium and hafnium in natural waters by isotope dilution mass spectrometry. Mar Chem 25: 197-210
11. Breaks FW, Moore JM Jr (1992) The Ghost Lake Batholith, Superior Province of northwestern Ontario: a fertile, S-type, peraluminous granite - rare-element pegmatite system Can Mineral 30: 835-875
12. Brenan JM, Watson EB (1991) Partitioning of trace elements between olivine and aqueous fluids at high P and T: implications for the effect of fluid composition on trace-element transport. Earth Planet Sci Lett 107: 672-688
13. Burns RG (1993) Mineralogical applications of crystal field theory, 2nd edn. Cambridge university Press, Cambridge
14. Butler JR, Thompson AJ (1965) Zirconium: hafnium ratios in some igneous rocks. Geochim Cosmochim Acta 29: 167-175
15. Byrne RH, Kim KH (1990) Rare earth element scavenging in seawater, Geochim Cosmochim Acta 54: 2645-2656
16. Černý P (1993) Fractionation in granite + rare-element pegmatite systems: facts and fiction. In: Hach-Ali F et al (eds) Current research in geology applied to ore deposits Univ Granada, Granada, pp 23-26
17. Černý P, Meintzer RE, Anderson AJ (1985) Extreme fractionation in rare-element granitic pegmatites: selected examples of data and mechanisms. Can Mineral 23: 381-421
18. Cotten J, Le Dez A, Bau M, Caroff M, Maury RC, Dulski P, Fourcade S, Bohn M, Brousse R (1995) Origin of anomalous rare-earth element and yttrium enrichments in subaerially exposed basalts: evidence from French Polynesia. Chem Geol 119: 115-138
19. de Baar HJW, Schijf J, Byrne RH (1991) Solution chemistry of the rare earth elements in seawater. Eur J Solid State Inorg Chem 28: 357-373
20. Duke EF, Papike JJ, Laul JC (1992) Geochemistry of a boron-rich peraluminous granite pluton: the Calamity Peak layered granite-pegmatite complex, Black Hills, South Dakota. Can Mineral 30: 811-833
21. Dulski P (1994) Interferences of oxide, hydroxide and chloride analyte species in the determination of rare earth elements in geological samples by inductively coupled plasma - mass spectrometry. Fresenius J Anal Chem 304: 193-203
22. Dupuy C, Liotard JM, Dostal J (1992) Zr/Hf fractionation in intraplate basaltic rocks: carbonate metasomatism in the mantle source. Geochim Cosmochim Acta 56: 2417-2423
23. Ebeling J (1994) Petrographische und spurenelementgeochemische Untersuchungen zur Liefergebietsanalyse paläozoischer Pelite am Nordrand des Linksrheinischen Schiefergebirges. Unpublished. diploma thesis. RWTH Aachen/GFZ Potsdam
24. Ellison AJ, Hess PC (1986) Solution behavior of +4 cations in high silica melts: petrologic and aeochemical implications. Contrib Mineral Petrol 94: 343-351
25. Fidelis I, Siekierski S (1966) The regularities in stability constants of some rare earth complexes. J Inorg Nucl Chem 28: 185-188
26. Fleet ME, Pan Y (1995) Crystal chemistry of rare earth elements in fluorapatite and some calesilicates. Eur J Mineral 7: 591-605
27. Fleischer M, Altschuler ZS (1986) The lanthanides and yttrium in minerals of the apatite group - an analysis of the available data, Neues Jahrb Mineral Monatsh 1986/10: 467-480
28. Förster HJ, Tischendorf G (1994) The western Erzgebirge-Vogtland granites: implications 10 the Hercynian magmatism in the Erzgebirge-Fichtelgebirge anticlinorium. In: Seltmann R et al (eds) Metallogeny of collisional orogens. Czech Geol Surv. Prague, pp 35-48
29. Garg AN (1981) The role of crystal chemical effects in zirconium-hafnium fractionation in oceanic basalts from Ascension Island. Chem Geol 34: 235-241
30. Goldschmidt VM (1937) The principles of distribution of chemical elements in minerals and rocks. J Chem Soc (1937): 655-673
31. Govindaraju K (1994) 1994 compilation of working values and sample description for 383 geostandards. Geostand Newsl 18: 1-158
32. Hinton RW, Upton BGJ (1991) The chemistry of zircon: variations within and between large crystals from syenite and alkali basalt xenoliths. Geochim Cosmochim Acta 55: 3287-3302
33. Irber W, Seltmann R, Möller P, Dulski P (1994) REE-Verteilungsmuster in hoch spezialisierten magmatischen Systemen des Erzgebirges. Eur J Mineral Beih 1: 123
34. Jahn S (1994) Alteration processes and related shift of elements: the albite granite of Abu Dahbab. Egypt. Eur J Mineral Beih 1: 124
35. Jensen BB (1973) Patterns of trace element partitioning. Geochim Cosmochim Acta 37: 2227-2242
36. Jochum KP, Seufert HM, Spettel B, Palme H (1986) The solar system abundances of Nb, Ta, and Y, and the relative abundances of refractory lithophile elements in differentiated planetary bodies, Geochim Cosmochim Acta 50: 1173-1183
37. Jochum KP, McDonough WF, Palme H, Spettel B (1989) Compositional constraints on the continental lithospheric mantle from trace elements in spinel peridotite xenoliths. Nature 340: 548-550
38. Jolliff BL, Papike JJ, Shearer CK, Shimizu N (1989) Inter-and intra-crystal REE variations in apatite from the Bob Ingersoll pegmatite, Black Hills, South Dakota. Geochim Cosmochim Acta 53: 429-441
39. Jørgensen CK (1970) The "tetrad effect" of Peppard is a variation of the nephelauxetic ratio in the third decimal. J Inorg Nucl Chem 32: 3127-3128
40. 3+ ionic radii and refined spin-pairing energy theory. Geochem J 26: 309-335
41. Kawabe I, Kitahara Y, Naito K (1991) Non-ehondritic yttrium/holmium ratio and lanthanide tetrad effect observed in pre-Cenozoic limestones. Geochem J 25: 31-44
42. Keppler H (1993) Influence of fluorine on the enrichment of high field strength trace elements in granitic rocks. Contrib Mineral Petrol 114: 479-488
43. Lee JH, Byrne RH (1993) Complexation of trivalent rare-earth elements (Ce, Eu, Gd, Tb, Yb) by carbonate ions. Geochim Cosmochim Acta 57: 295-302
44. Little EJ, Jones MM (1960) A complete table of electronegativities. J Chem Educ 37: 231-233
45. London D (1986) Magmatic-hydrothermal transition in the Tanco rare-element pegmatite: evidence from fluid inclusions and phase-equilibrium experiments. Am Mineral 71: 376-395
46. London D (1987) Internal differentiation of rare-element pegmatites: effects of boron, phosphorus, and fluorine. Geochim Cosmochim Acta 51: 403-420
47. Masuda A, Akagi T (1989) Lanthanide tetrad effect observed in leucogranites from China. Geochem J 23: 245-253
48. Masuda A, Kawakami O, Dohmoto Y, Takenaka T (1987) Lanthanide tetrad effects in nature: two mutually opposite types, W and M. Geochem J 21: 119-124
49. McLennan SM (1994) Rare earth element geochemistry and the "tetrad" effect. Geochim Cosmochim Acta 58: 2025-2033
50. Möller P (1988) The dependence of partition coefficients on differences of ionic volumes in crystal-melt systems. Contrib Mineral Petrol 99: 62-69
51. Möller P, Dulski P (1983) Fractional ion of Zr and Hf in cassiterite. Chem Geol 40: 1-12
52. Möller P, Dulski P, Luck J (1992) Determination of rare-earth elements in seawater by inductively coupled plasma - mass spectrometry. Spectrochim Acta 47B: 1379-1387
53. Möller P, Dulski P, Bau M (1994) Rare-earth element adsorption in a seawater profile above the East Pacific Rise. Chem Erde 54: 129-149
54. Mohamed FH (1993) Rare metal-bearing and barren granites, Eastern Desert of Egypt: geochemical characterization and metallogenetic aspects. J Afr Earth Sci 17: 525-539
55. Onuma N, Higuchi H, Wakita H, Nagasawa H (1968) Trace element partition between two pyroxenes and the host lava. Earth Planet Sci Lett 5: 47-51
56. Paterson BA, Stephens WE. Rogers G, Williams IS, Hinton RW, Herd DA (1992) The nature of zircon inheritence in two granite plutons. Trans R Soc Edinburgh Earth Sci 83: 459-471
57. Peppard DF, Mason GW, Lewey S (1969) A tetrad effect in the liquid-liquid extraction ordering of lanthanide(III). J Inorg Nucl Chem 31: 2271-2272
58. Philpotts JA (1978) The law of constant rejection. Geochim Cosmochim Acta 42: 909-920
59. Ponader CW, Brown GE (1989) Rare earth elements in silicate glass/melt systems. II. Interactions of La, Gd, and Yb with halogens. Geochim Cosmochim Acta 53: 2905-2914
60. Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr A32: 751-767
61. Shaw DM (1968) A review of K/Rb fractionation trends by covariance analysis. Geochim Cosmochim Acta 32: 573-601
62. Skulski T, Minarik W, Watson EB (1994) High-pressure experimental trace-element partitioning between clinopyroxene and basaltic melts. Chem Geol 117: 127-147
63. Taylor RP (1992) Petrological and geochemical characteristics of the Pleasant Ridge zinnwaldite-topaz granite, southern New Brunswick, and comparisons with other topaz-bearing felsic rocks. Can Mineral 30: 895-921
64. Taylor SR (1965) The application of trace element data to problems in petrology. In: Ahrens LH et al (eds) Physics and chemistry of the Earth, vol. 6. Pergamon Press, Oxford, pp 133-213
65. Walker JB, Choppin GR (1967) Thermodynamic parameters of fluoride complexes of the lanthanides. Adv Chem 71: 127-140
66. Wang Ru Cheng, Fontan F, Monchoux P (1992) Minéraux disséminés comme indicateurs du caractère pegmutique du Granite de Beauvoir. Massif d'Échassières. Allier. France. Can Mineral 30: 763-770
67. Zhang J, Amakawa H, Nozaki Y (1994) The comparative behaviors of yttrium and lanthanides in the seawater of the North Pacific. Geophys Res Lett 21: 2677-2680