Synthesis, structure, and property of a triruthenium cluster having a μ-alkyl ligand: Transformation of a μ3(⊥)-alkyne ligand into a μ-alkyl ligand via a μ3-vinylidene complex

Journal of Organometallic Chemistry

Volumn 692, Issue 1-3, 2007, Pages 442-454

  Tenjimbayashi, Ryu ichi ^a   Murotani, Eisuke ^a   Takemori, Toshifumi ^a   Takao, Toshiro ^a   Suzuki, Hiroharu ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Agostic interaction; Alkyl complex; Alkyne complex; Hydrido complex; Triruthenium cluster

Indexed keywords

CARBON MONOXIDE; CHEMICAL BONDS; MOLECULAR STRUCTURE; ORGANOMETALLICS; SYNTHESIS (CHEMICAL);

AGOSTIC INTERACTION; ALKYL COMPLEXES; ALKYNE COMPLEXES; HYDRIDO COMPLEXES; TRIRUTHENIUM CLUSTER;

RUTHENIUM COMPOUNDS;

EID: 33845683037     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.08.070     Document Type: Article

References (67)

1. Brookhart M., and Green M.L.H. J. Organomet. Chem. 250 (1983) 395-408
2. Crabtree R.H. The Organometallic Chemistry of the Transition Metals. third ed. (2001), Wiley, New York p. 392 (Chapter 13)
3. Calvert R.B., and Shapley J.R. J. Am. Chem. Soc. 99 (1977) 5225-5226
4. Calvert R.B., Shapley J.R., Schultz A.J., Williams J.M., Suib S.L., and Stucky G.D. J. Am. Chem. Soc. 100 (1978) 6240-6241
5. Calvert R.B., and Shapley J.R. J. Am. Chem. Soc. 100 (1978) 7726-7727
6. Schultz A.J., Williams J.M., Calvert R.B., Shapley J.R., and Stucky G.D. Inorg. Chem. 18 (1979) 319-323
7. Velde D.G.V., Holmgren J.S., and Shapley J.R. Inorg. Chem. 26 (1987) 3077-3078
8. Riehl J.-F., Koga N., and Morokuma K. J. Am. Chem. Soc. 116 (1994) 5414-5424
9. Fehlner T.P. Polyhedron 9 (1990) 1955-1963
10. Dawkins G.M., Green M., Orpen A.G., and Stone F.G.A. J. Chem. Soc., Chem. Commun. (1982) 41-43
11. Casey C.P., Fagan P.J., and Miles W.H. J. Am. Chem. Soc. 104 (1982) 1134-1136
12. Jeffery J.C., Orpen A.G., Robinson W.T., Stone F.G.A., and Went M.J. J. Chem. Soc., Chem. Commun. (1984) 396-398
13. Davies D.L., Gracey B.P., Guerchais V., Knox S.A.R., and Orpen A.G. J. Chem. Soc., Chem. Commun. (1984) 841-843
14. Jeffery J.C., Orpen A.G., Stone F.G.A., and Went M.J. J. Chem. Soc., Dalton Trans. (1986) 173-186
15. Gao Y., Jennings M.C., and Puddephatt R.J. Organometallics 20 (2001) 1882-1888
16. Cabon N., Schollhammer P., Pétillon F.Y., Talarmin J., and Muir K.W. Organoemtallics 21 (2002) 448-450
17. Trepanier S.J., McDonald R., and Cowie M. Organometallics 22 (2003) 2638-2651
18. Rowsell B.D., McDonald R., and Cowie M. Organometallics 23 (2004) 3873-3883
19. Wigginton J.R., Trepanier S.J., McDonald R., Ferguson M.J., and Cowie M. Organometallics 24 (2005) 6194-6211
20. Vites J.C., Jacobsen G., Dutta T.K., and Fehlner T.P. J. Am. Chem. Soc. 107 (1985) 5563-5565
21. Bower D.K., and Keister J.B. J. Organomet. Chem. 312 (1986) C33-C36
22. Dutta T.K., Vites J.C., Jacobsen G.B., and Fehlner T.P. Organometallics 6 (1987) 842-847
23. Bower D.K., and Keister J.B. Organometallics 9 (1990) 2321-2327
24. Ahlgré M., Pakkanen T.T., and Tahvanainen I. J. Organomet. Chem. 323 (1987) 91-102
25. Barreto R.D., and Fehlner T.P. J. Am. Chem. Soc. 110 (1988) 4471-4472
26. Barreto R.D., Puga J., and Fehlner T.P. Organometallics 9 (1990) 662-668
27. Takao T., Takaya Y., Murotani E., Tenjimbayashi R., and Suzuki H. Organometallics 23 (2004) 6094-6096
28. Park J.W., Mackenzie P.B., Schaefer W.P., and Grubbs R.H. J. Am. Chem. Soc. 108 (1986) 6402-6404
29. Ozawa F., Mackenzie P.B., Schaefer W.P., Henling L.M., and Grubbs R.H. J. Am. Chem. Soc. 111 (1989) 1319-1327
30. Cabon N., Goff A.L., Roy C.L., Pétillon F.Y., Schollhammer P., Talarmin J., McGrady J.E., and Muir K.W. Organoemtallics 24 (2005) 6268-6278
31. Duggan T.P., Barnett D.J., Muscatella M.J., and Keister J.B. J. Am. Chem. Soc. 108 (1986) 6076-6077
32. Clauss A.D., Shapley J.R., and Wilson S.R. J. Am. Chem. Soc. 103 (1981) 7387-7388
33. Douglas G., Manojlović-Muir L., Muir K.W., Rashidi M., Anderson C.M., and Puddephatt R.J. J. Am. Chem. Soc. 109 (1987) 6527-6528
34. Rivomanana S., Lavigne G., Lugan N., and Bonnet J.-J. Inorg. Chem. 30 (1991) 4112-4117
35. Peng J.-J., Peng S.-M., Lee G.-H., and Chi Y. Organometallics 14 (1995) 626-633
36. Smith A.K., and Harding R.A. J. Chem. Soc., Dalton Trans. (1996) 117-123
37. Rivomanana S., Mongin C., and Lavigne G. Organometallics 15 (1996) 1195-1207
38. Mays M.J., Raithby P.R., Sarveswaran K., and Solan G.A. Dalton (2002) 1671-1677
39. Takao T., Kakuta S., Tenjimbayashi R., Takemori T., Murotani E., and Suzuki H. Organometallics 23 (2004) 6090-6093
40. Takemori T., Inagaki A., and Suzuki H. J. Am. Chem. Soc. 123 (2001) 1762-1763
41. Schnering C., Albeiz T., Berhardt W., and Vahrenkamp H. Angew. Chem., Int. Ed. Engl. 25 (1986) 279-280
42. Jensen M.P., and Shriver D.F. Organometallics 11 (1992) 3385-3389
43. Adams H., Gill L.J., and Morris M.J. Organometallics 15 (1996) 4182-4189
44. Cabeza J.A., del Río I., García-Granda S., Riera V., and Suárez M. Organometallics 23 (2004) 3501-3511
45. Rashidi M., and Puddephatt R.J. J. Am. Chem. Soc. 108 (1986) 7111-7112
46. Keister J.B., Payne M.W., and Muscatella M.J. Organometallics 2 (1983) 219-225
47. Bavaro L.M., Montangero P., and Keister J.B. J. Am. Chem. Soc. 105 (1983) 4977-4981
48. Duggan T.P., Golden M.J., and Keister J.B. Organometallics 9 (1990) 1656-1665
49. Sheldrick G.M., and Yesiniwski J.P. J. Chem. Soc., Dalton Trans. (1975) 873-876
50. Castiglioni M., Gervasio G., and Sappa E. Inorg. Chim. Acta 49 (1981) 217-225
51. Rahman Z.A., Beanan L.R., Bavaro L.M., Modi S.P., Keister J.B., and Churchill M.R. J. Organomet. Chem. 263 (1984) 75-92
52. Connelly N.G., Forrrow N.J., Knox S.A.R., Macpherson K.A., and Orpen A.G. J. Chem. Soc., Chem. Commun. (1985) 16-17
53. Churchill M.R., Duggan T.P., Keister J.B., and Ziller J.W. Acta Crystallogr., Sect. C 43 (1987) 203
54. Kakigano T., Suzuki H., Igarashi M., and Moro-oka Y. Organometallics 9 (1990) 2192-2194
55. Nevinger L.R., Keister J.B., Lake C.H., and Churchill M.R. Organometallics 11 (1992) 1819-1824
56. Adams K.J., Barker J.J., Knox S.A.R., and Orpen A.G. Dalton (1996) 975-988
57. Matsubara K., Okamura R., Tanaka M., and Suzuki H. J. Am. Chem. Soc. 120 (1998) 1108-1109
58. Matsubara K., Inagaki A., Tanaka M., and Suzuki H. J. Am. Chem. Soc. 121 (1999) 7421-7422
59. Takao T., Takemori T., Moriya M., and Suzuki H. Organometallics 21 (2002) 5190-5203
60. Inagaki A., Takao T., Moriya M., and Suzuki H. Organometallics 22 (2003) 2196-2198
61. Griffith C.S., Koutsantonis G.A., Skelton B.W., and White A.H. J. Organomet. Chem. 672 (2003) 17-21
62. Davies D.L., Howard J.A.K., Knox S.A.R., Marsden K., Mead K.A., Morris M.J., and Rendle M.C. J. Organomet. Chem. 279 (1985) C37-C41
63. Försterling F.H., and Barnes C.E. J. Am. Chem. Soc. 119 (1997) 7585-7586
64. Barnes C.E., and Försterling F.H. Polyhedron 17 (1998) 1045-1054
65. Nakajima Y., Kameo H., and Suzuki H. Angew. Chem. Int. Ed. 45 (2006) 950-952
66. Inagaki A., Takemori T., Tanaka M., and Suzuki H. Angew. Chem. Int. Ed. 39 (2000) 404-406
67. International Tables for X-ray Crystallography, vol. 4, Kynoch Press, Birmingham, UK, 1975.