Thermal skeletal rearrangement of a nido-ruthenacyclopentadiene complex involving reversible rupture and formation of a ruthenium-ruthenium bond

Organometallics

Volumn 22, Issue 11, 2003, Pages 2196-2198

  Inagaki, Akiko ^a   Takao, Toshiro ^a   Moriya, Makoto ^a   Suzuki, Hiroharu ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BOND CLEAVAGE; NIDORUTHENACYCLOPENTADIENE LIGAND; THERMOLYSIS; TRIRUTHENIUM COMPLEX;

BOND STRENGTH (CHEMICAL); HEATING; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION KINETICS; RUTHENIUM COMPOUNDS;

ORGANOMETALLICS;

EID: 0038262776     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om030175s     Document Type: Article

References (18)

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14. 5), -22.44 (s, 1H, RuH).
15. -1, R1 = 0.048, wR2 = 0.105 for 6750 reflections with I > 2σ(I). Since the hydrogen atom attached to the ruthenium atom could not be located in the difference Fourier map, it was omitted.
16. Takao, T.; Takemori, T.; Moriya, M.; Suzuki, H. Organometallics 2002, 21, 5190.
17. -1, R1 = 0.0311, wR2 = 0.0738 for 5413 reflections with I > 2σ(I).
18. Inagaki, A.; Musaey, D. G.; Takemori, T.; Suzuki, H.; Morokuma, K. Organometallics 2003, 22, 1718.