Pyroxene europium valence oxybarometer: Effects of pyroxene composition, melt composition, and crystallization kinetics

American Mineralogist

Volumn 91, Issue 10, 2006, Pages 1565-1573

  Shearer, C K ^a   Papike, J J ^a   Karner, J M ^a  

^a UNIVERSITY OF NEW MEXICO   (United States)

Author keywords

4 Vesta; Eu valence; Moon; Oxybarometer; Pyroxene; V valence

Indexed keywords

ALUMINUM; ASTEROIDS; BASALT; CALCIUM COMPOUNDS; COOLING; CRYSTALLIZATION KINETICS; EUROPIUM; FELDSPAR; IRON COMPOUNDS; KINETICS; MOON;

4 VESTA; COUPLED SUBSTITUTION; CRYSTALLIZING PHASIS; EFFECTIVE MEASURES; MELT COMPOSITIONS; OXYBAROMETER; PYROXENE; SEVERAL VARIABLES;

GROWTH RATE;

BASALT; COOLING; CRYSTALLIZATION; EUROPIUM; MAGMA; MELT; MOON; PIGEONITE; PYROXENE;

EID: 33845647244     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2006.2098     Document Type: Article

References (52)

1. Bence, A.E. and Papike, J.J. (1971) A martini glass clinopyroxene from the Moon. Earth Planetary Science Letters, 10, 245-251.
2. _ (1972) Pyroxene as recorders of lunar basalt petrogenesis: Chemical trends due to crystal-liquid interaction. Proceedings of the 3rd Lunar Science Conference, 1, 431-469.
3. Bence, A.E., Papike, J.J., and Prewitt, C.T. (1970) Apollo 12 clinopyroxenes: Chemical trends. Earth and Planetary Science Letters, 8, 393-399.
4. Bence, A.E., Papike, J.J., and Lindsley, D.H. (1971) Crystallization histories of clinopyroxenes in two porphyritic rocks from Oceanus Procellarum. Proceedings of the 2nd Lunar Science Conference, 1, 559-574.
5. Blundy, J. and Wood, B. (1994) Prediction of crystal-melt partitioning coefficients elastic moduli. Nature, 372, 452-454.
6. _ (2003) Partitioning of trace elements between crystals and melts. Earth and Planetary Science Letters (Frontiers), 210, 387-397.
7. Boyd, F.R., Jr. and Smith, D. (1971) Compositional zoning in pyroxenes from lunar rock 1201, Oceanus Procellarum. Journal of Petrology, 12, 439-464.
8. Brett, R., Butler, P.J., Meyer, C., Jr., Reid, A.M., Takeda, H., and Williams, R. (1971) Apollo 12 igneous rocks 12004, 12008, 12009, and 12022: A mineralogical and petrological study. Proceedings of the 2nd Lunar Science Conference, Geochimica et Cosmochimica Acta, Suppl. 2, 1, 301-317.
9. BVSP (Basaltic Volcanism Study Project) (1981) Basaltic volcanism on the terrestrial planets, 1286 p. Pergamon Press, New York.
10. Cameron, M. and Papike, J.J. (1981) Structural and chemical variations in pyrorene. American Mineralogist, 66, 1-50.
11. Canil, D. and Fedortchouk, Y. (2001) Olivine-liquid partitioning of vanadium and other trace elements, with applications to modern and ancient picrites. Canadian Mineralogist, 39, 319-330.
12. Delano, J.W. (1990) Experimental constraints on the oxidation state of the lunar mantle. Lunar and Planetary Science, XXI, 278-279.
13. Drake, M.J. (1975) The oxidation state of europium as an indicator of oxygen fugacity. Geochimica et Cosmochimica Acta, 39, 55-64.
14. Fogel, R.A. and Rutherford, M.J. (1995) Magmatic volatiles in primitive lunar glasses: I. FTIR and EPMA analyses of Apollo 15 green and yellow glasses and revision of the volatile-assisted fire-fountain theory. Geochimica et Cosmochimica Acta, 59.201.
15. th Lunar and Planetary Science Conference, 1549-1579. Pergamon Press, New York.
16. 2+ partitioning between olivine and liquid in the presence of spinel. American Mineralogist, 83, 669-684.
17. Jones, J.H. (2004) Redox conditions among the terrestrial planets. Lunar and Planetary Science, XXXV, abstract 1264. CD-ROM.
18. Karner, J.M., Papike, J.J., and C.K. Shearer (2003) Olivine from Planetary basalts: Chemical signatures that indicate planetary parentage and those that record igneous setting and process. American Mineralogist, 88, 806-816.
19. Karner, J.M., Papike, J.J., and Shearer, C.K. (2006a) Comparative planetary mineralogy: Major and minor element chemistry and the partitioning of vanadium into pyroxene from planetary basalts. American Mineralogist, 91, 1574-1582.
20. Karner, J.M., Sutton, S.R., Papike, J.J., Shearer, C.K., Jones, J.H., and Newville, M. (2006b) Application of a new Vanadium Valence Oxybarometer to Basaltic Glasses from Earth, Moon, and Mars. American Mineralogist, 91, 270-277.
21. th Lunar Science Conference, 79-99. Pergamon Press, New York.
22. Lundstrom, C.C., Shaw, H.F., Ryerson, F.J., Williams, Q., and Gill, J. (1998) Crystal chemical control of clinopyroxene-melt partitioning in the Di-Ab-An system: Implications for the elemental fractionations in the depleted mantle. Geochimica et Cosmochimica Acta, 62, 2849-2862.
23. McCanta, M.C. and Rutherford, M.J. (2002) Oxygen fugacity recorded in pigeonite: Indications of a heterogeneous martian magma source region? In A.H. Treiman and C.D.K. Herd, Eds., Unmixing the SNCs: Chemical, Isotopic, and Petrologic Components of Martian Meteorites, p. 35. LPI Contribution 1134, Lunar and Planetary Institute, Houston.
24. McKay, G.A. (1989) Partitioning of rare earth elements between major silicate minerals and basaltic melts. In B.R. Lipin and G.A McKay, Eds., Geochemistry and Mineralogy of Rare Earth Elements, 21, p. 45-77. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
25. McKay, G., Wagstaff, J., and Yang, S.-R. (1986) Clinopyroxene REE distribution coefficients for shergottites: The REE content of the Shergotty melt, Geochimica ct Cosmochimica Acta, 50, 927-937.
26. th Lunar and Planetary Science Conference, 883-884.
27. McKay, G.A., Le, L., Wagstaff, J., and Crozaz, G. (1994b) Experimental partitioning of rare earth elements and strontium: Constraints on petrogenesis and redox conditions during crystallization of Antarctic angrite Lewis Cliff 86010. Geochimica et Cosmochimica Acta, 58, 2911-2919.
28. McKay, G.A., Le, L., Schwandt, C., Mikouchi, T., Koizumi, E., and Jones, J. (2004) Yamato 980459: The most primitive shergottite? Lunar and Planetary Science Conference, XXXV, abstract 2154 (CD-ROM).
29. Musselwhite, D.S. and Jones, J.H. (2003) Oxygen fugacity of the martian mantle from pyroxene/melt partitioning of REE. Lunar and Planetary Science Conference, XXXIV, abstract 2032 (CD-ROM).
30. Musselwhite, D.S., Jones, J.H., and Shearer, C.K. (2004) Oxygen fugacity of the martian mantle from pigeonite/melt partitioning of Sm, Eu, and G. Workshop on Oxygen in the Terrestrial Planets, abstract 3027 (CD-ROM).
31. Papike, J.J. and Bence, A.E. (1978) Lunar mare vs. terrestrial mid-ocean ridge basalts: planetary constraints on basaltic volcanism. Geophysical Research Letters, 5, 803-806.
32. Papike, J.J., Hodges, F.N., Bence, A.E., Cameron, M., and Rhodes, J.M. (1976) Mare basalts: Crystal chemistry, mineralogy, and petrology. Reviews in Geophysics and Space Physics, 14, 475-540.
33. Papike, J.J., Ryder, G., and Shearer, C.K. (1998) Lunar Samples. In J.J. Papike, Ed., Planetary Materials, 36, p. 5-1-5-234. Reviews in Mineralogy, Mineralogical Society of America, Chantilly, Virginia.
34. Papike, J.J., Kamer, J.M., and Shearer, C.K. (2005) Comparative planetary mineralogy: Valence state partitioning of Cr, Fe, Ti, and V among crystallographic sites in olivine, pyroxene, and spinel from planetary basalts. American Mineralogist, 90, 277-290.
35. 3+ concentrations in natural phases. Earth and Planetary Science Letters, 9, 257-268.
36. Prowatke, S. and Klemme, S. (2005) Effect of melt composition on the partitioning of trace elements between titanite and silicate melt. Geochimica et Cosmochimica Acta, 69, 695-709.
37. Pun, A. and Papike, J.J. (1995) Ion microprobe investigation of exsolved pyroxene in cumulate eucrites: Determination of selected trace-element partition coefficients. Geochimica et Cosmochimica Acta, 59, 2279-2289.
38. Sato, M. (1976) Oxygen fugacity and other thermochemical parameters of Apollo 17 high-Ti basalts and their implications on the reduction mechanism. Proceedings of the 7th Lunar Science Conference, 1323-1344.
39. Schnetzler, C.C. and Philpotts, J.A. (1970) Partition coefficients of the rare earth elements between igneous matrix material and rock-forming mineral phenocrysts-II. Geochimica et Cosmochimica Acta, 34, 333-340.
40. Schwandt, C.S. and McKay, G.A. (1998) Rare earth element partition coefficients from enstatite/melt synthesis experiments. Geochimica et Cosmochimica Acta, 62, 2845-2848.
41. Shearer, C.K. and Larsen, L.M. (1994) Sector-Zoned Aegirine from the Ilimaussag Alkaline Intrusion, South Greenland. Implications for trace-element behavior in pyroxene. American Mineralogist, 79, 340-352.
42. Shearer, C.K., Papike, J.J., Simon, S.B., and Shimizu, N. (1989) An ion microprobe study of the intra-crystalline behavior of REE and selected trace elements in pyroxene from mare basalts with different cooling and crystallization histories. Geochimica et Cosmochimica Acta, 53, 1041-1054.
43. Shearer, C.K., Karner, J., Papike, J.J., and Sutton, S.R. (2004) Oxygen fugacity of mare Basalts and the lunar mantle. Application of a new microscale oxybarometer based on the valence state of vanadium. Lunar Planetary Science Conference, XXXV, abstract 1617.
44. 2 of the Martian Mantle. AGU Fall Meeting, abstracts with programs.
45. Sobolev, A.V., Migdisov, A.A., and Portnyagin, M.V. (1996) Incompatible element partitioning between clinopyroxene and basalt liquid revealed by the study of melt inclusions in minerals from Troodos lavas. Cyprus.Petrology, 4(3), 307-317.
46. Stolper, E (1977) Experimental petrology of eucrite meteorites. Geochimica et Cosmochimica Acta, 41, 587-611.
47. Sutton, S.R., Karner, J., Papike, J.J., Delaney, J.S., Shearer, C.K., Newville, M., Eng, P., Rivers, M., and Dyer, M.D. (2005) A new microscale oxybarometer for solar system basaltic glasses based on a vanadium K-edge XANES. Geochimica et Cosmochimica Acta, 69, 2333-2348.
48. Wadhwa, M. (2001) Redox state of Mars' upper mantle and crust from Eu anomalies in shergottite pyroxenes. Science, 291, 1527-1530.
49. Weill, D.F. and Drake, M.J. (1973) Europium anomaly in plagioclase feldspar. Experimental results and semiquantitative model. Science, 180, 1059-1060.
50. Weill, D.F. and McKay, G.A. (1975) The partitioning of Mg. Fe, Sr, Ce, Sm, Eu, and Yb in lunar igneous systems and a possible origin of KREEP by equilibrium partial melting. Proceedings of the 6th Lunar Science Conference, 1143-1158. Pergamon Press, New York.
51. th Lunar Science Conference, 1337-1352.
52. Yurimoto, H. and Sueno, S. (1987) Anion and cation partitioning between three pyroxenes, chrome spinel phenocrysts, and the host boninite magmas: an ion microprobe study. Geochemical Journal, 21, 85-104.