Molybdenum and tungsten in volcanic rocks and in surface and <100 °C ground waters in Iceland

Geochimica et Cosmochimica Acta

Volumn 71, Issue 2, 2007, Pages 284-304

  Arnórsson, Stefán ^a   Óskarsson, Níels ^a  

^a UNIVERSITY OF ICELAND   (Iceland)

Author keywords

[No Author keywords available]

Indexed keywords

GEOCHEMISTRY; GROUNDWATER; MID-OCEAN RIDGE BASALT; MOLYBDENUM; RHYOLITE; THOLEIITE; TUNGSTEN; WATER-ROCK INTERACTION;

ARCTIC; ICELAND;

EID: 33845602656     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2006.09.030     Document Type: Article

References (98)

1. Adelson J.M., Helz G.R., and Miller C.V. Reconstructing the rise of recent coastal anoxia; molybdenum in Chesapeake Bay sediments. Geochim. Cosmochim. Acta 65 (2001) 237-252
2. Allegre C.J., Dupre B., Negrel P., and Gaillardet J. Sr-Nd-Pb isotope systematics in Amazon and Congo River systems: constraints about erosion processes. Chem. Geol. 131 (1996) 93-112
3. Annersten H., and Ekström T. Distribution of major and minor elements in coexisting minerals from a metamorphosed iron formation. Lithos 4 (1971) 185-204
4. Árnason B. Hydrothermal systems in Iceland traced by deuterium. Geothermics 5 (1977) 125-151
5. Arnórsson, S., 1969. A geochemical study of selected elements in thermal waters in Iceland. Unpubl. Ph.D. thesis, Imperial College, Univ. London, 353 p.
6. Arnórsson S. Arsenic in surface- and up to 90 °C ground waters in a basalt area, N-Iceland: processes controlling its mobility. Appl. Geochem. 18 (2003) 1297-1312
7. Arnórsson S., and Andrésdóttir A. Processes controlling the distribution of B and Cl in natural waters in Iceland. Geochim. Cosmochim. Acta 59 (1995) 4125-4146
8. sat. In: Ármannsson (Ed.) Proceedings of the 5th International Symposium on Geochemistry of the Earth's Surface, Rotterdam, Balkema, pp. 425-428.
9. Arnórsson S., and Ívarsson G. Molybdenum in Icelandic geothermal waters. Contrib. Mineral. Petrol. 90 (1985) 179-189
10. Arnórsson S., and Lindvall R. The distribution of arsenic, molybdenum and tungsten in natural waters in basaltic terrain, N-Iceland. In: Cidu R. (Ed). Water-Rock Interaction (2001), Abingdon, Balkema 961-964
11. Arnórsson S., and Stefánsson A. Assessment of feldspar solubility constants in water in the range 0° to 350 °C at vapour saturation pressures. Am. J. Sci. 299 (1999) 173-209
12. Arnórsson S., and Sveinbjörnsdóttir A.E. Age and chemical evolution of groundwaters in Skagafjördur, Iceland. J. Geochem. Explor. (2000) 459-463
13. Arnórsson S., Gunnarsson I., Stefánsson A., Andrésdóttir A., and Sveinbjörnsdóttir A.E. Major element chemistry of surface and ground waters in basaltic terrain, N-Iceland. I. Primary mineral saturation. Geochim. Cosmochim. Acta 66 (2002) 4015-4046
14. 2 and Ar in pure water. Science Institute report 17-96, 20 pp.
15. Arnórsson S., Sigurdsson S., and Svavarsson H. The chemistry of geothermal waters in Iceland. I. Calculation of aqueous speciation from 0° to 370 °C. Geochim. Cosmochim. Acta 46 (1982) 1513-1532
16. Bennett B., and Dudmas M.J. Release of arsenic and molybdenum by reductive dissolution of iron oxides in a soil with enriched levels of native arsenic. J. Environ. Eng. Sci. 2 (2003) 265-272
17. Bjarnason, J.O., 1994. The speciation program WATCH version 2.1. Reykjavík, National Energy Autority Report, 7pp.
18. Bykova E.Y., Znamenskii V.S., Kovalenker V.A., Arsii I.M., and Baturin S.V. Associations and deposition conditions of molybdenum minerals in exhalation products of the Kudryavyi volcano, Iturup, Kuril Islands. Geol. Ore Deposits 37 (1995) 227-235
19. Carmichael I.S.E., and McDonald A. The geochemistry of some natural acid glasses from the North Atlantic Tertiary Province. Geochim. Cosmochim. Acta 25 (1961) 189-222
20. Chan K.M., and Riley J.P. The determination of molybdenum in natural waters, silicates and biological materials. Anal. Chim. Acta 36 (1966) 220-229
21. Chaussidon M., and Jambon A. Boron content and isotopic composition of oceanic basalts-geochemical and cosmochemical implications. Earth Planet. Sci. Lett. 128 (1994) 731-733
22. Dalai T.K., Nishimura K., and Nozaki Y. Geochemistry of molybdenum in the Chao Phraya River estuary, Thailand: role of suboxic diagenesis and pore water transport. Chem. Geol. 218 (2005) 189-202
23. -(aq). Geochim. Cosmochim. Acta 63 (1999) 2247-2261
24. Edmond J.M., Palmer M.R., Measures C.L., Grant B., and Stallard R.F. The fluvial geochemistry and denudation rate of the Guayana Shield in Venezuela, Columbia and Brazil. Geochim. Cosmochim. Acta 59 (1995) 3301-3325
25. Ellis A.J., and Mahon W.A.J. Natural hydrothermal systems and experimental hot water/rock interactions. Geochim. Cosmochim. Acta 28 (1964) 1323-1357
26. Ellis A.J., and Mahon W.A.J. Natural hydrothermal systems and experimental hot water/rock interactions. Geochim. Cosmochim. Acta 31 (1967) 519-538
27. Ellis A.J., and Sewell J.R. Boron in rocks and waters of New Zealand hydrothermal areas. N.Z. J. Sci. 6 (1963) 589-606
28. Erickson B.E., and Helz G.R. Molybdenum (VI) speciation in sulfidic waters: stability and lability of thiomolybdates. Geochim. Cosmochim. Acta 64 (2000) 1149-1158
29. Gaillardet J., Dupre B., Allegre C.J., and Negrel P. Chemical and physical denudation in the Amazon River Basin. Chem. Geol. 142 (1997) 141-173
30. 4, a new mineral from Vulcano, Aeolian Islands, Italy. Am. Mineral. 79 (1994) 381-384
31. Garavelli A., Laviano R., and Vurro F. Sublimate deposition from hydrothermal fluids at the Fossa crater-Vulcano, Italy. Eur. J. Mineral. 9 (1997) 423-432
32. Giggenbach W.F. Chemical techniques in geothermal exploration. In: D'Amore F. (Ed). Application of Geochemistry in Geothermal Reservoir Development (1991), UNITAR/UNDP Centre on Small Energy Resources, Rome 119-144
33. Gíslason S.R., Arnórsson S., and Ármannsson H. Chemical weathering of basalt as deduced from the composition of precipitation, rivers, and rocks in Iceland. Am. J. Sci. 296 (1996) 837-907
34. Gunnarsson I., and Arnórsson S. Amorphous silica solubility and the thermodynamic properties of aqueous silica in the range 0-350 °C. Geochim. Cosmochim. Acta 64 (2000) 2295-2307
35. Gunnlaugsson E., and Arnórsson S. The chemistry of iron in geothermal systems in Iceland. J. Volc. Geothermal Res. 14 (1982) 281-299
36. Gurenko A.A., and Chaussidon M. Oxygen isotope variations in primitive tholeiites of Iceland: evidence from SIMS study of glass inclusions, olivine phenocrysts and pillow rim glasses. Earth Planet. Sci. Lett. 207 (2004) 181-182
37. Hall G.E.M., Jefferson C.W., and Michelb F.A. Determination of W and Mo in natural spring waters by ICP-AES (inductively coupled plasma emission spectrography) and ICP-MS (inductively coupled plasma mass spectrometry): application to South Nahanni river area N.W.T. Can. J. Geochem. Explor. 30 (1988) 63-84
38. Hamasaki S. Volcanic-related alteration and geochemistry of Iwodake volcano, Satsuma-Iwojima, Kyushu, SW Japan. Earth Planets Space 54 (2002) 217-229
39. Hartung M. Tungsten. In: Merian E. (Ed). Metals and Their Compounds in the Environment-Occurrence, Analysis, and Biological Relevance (1991), VCH Publ. Inc, New York 1269-1273
40. Hervig R.L., Moore G.M., Williams L.B., Peacock S.M., Holloway J.R., and Roggensack K. Isotopic and elemental partitioning of boron between hydrous fluid and silicate melt. Am. Mineral. 87 (2002) 769-774
41. Hodge V.F., Johannesson K.H., and Stetzenbach K.J. Rhenium, molybdenum, and uranium in groundwater from the southern Great Basin. USA: evidence for conservative behavior. Geochim. Cosmochim. Acta 60 (1996) 3197-3214
42. Ishibashi M., Fujinaga T., and Kawamoto T. Fundamental investigation of the dissolution and deposition of molybdenum, tungsten and vanadium in the sea. Records Oceanog. Works Japan, Spec. 6 (1962) 215-218
43. Ivanova G.F., and Butuzova Ye.G. Distribution of tungsten, tin and molybdenum in granites of eastern Transbaikalia. Geochemistry 6 (1968) 572-583
44. Jóhannesson H. The mountains west of Eyjafjördur. II. Reykjavík. The Iceland Tourist Association Yearbook 1991 (1991) 246 (in Icelandic)
45. Johannesson K.H., Lyons W.B., Graham E.Y., and Welch K.A. Oxyanion concentrations in eastern Sierra Nevada rivers-3. Boron, molybdenum, vanadium, and tungsten. Aquat. Geochem. 6 (2000) 19-46
46. Johnson J.W., Oelkers E.H., and Helgeson H.C. SUPCRT92: a software package for calculating the standard molal properties of minerals, gases, aqueous species and reactions among them from 1 to 5000 bars and 0 to 1000 °C. Comp. Geosci. 18 (1992) 899-947
47. Jónasson K. Rhyolite volcanism in the Krafla central volcano, north-east Iceland. Bull. Volcanol. 56 (1994) 516-528
48. Jónasson K. Magmatic evolution of the Hei{eth}arspordur ridge, NE-Iceland. J. Volc. Geothermal Res. 147 (2005) 109-124
49. Kaback D.S., and Runnells D.D. Geochemistry of molybdenum in some stream sediments and waters. Geochim. Cosmochim. Acta 44 (1980) 447-456
50. Kim Y.A., and Zeitlin H. The determination on molybdenum in seawater. Limnol. Oceanog. 13 (1968) 534-537
51. Kishida K., Sohrin Y., Okamura K., and Ishibashi J. Tungsten enriched in submarine hydrothermal fluids. Earth Planet. Sci. Lett. 222 (2004) 819-827
52. Kist A.A. Investigation of element speciation in atmosphere. Biol. Trace Elem. Res. 43-44 (1994) 259-266
53. Kletzin A., and Adams M.W.W. Tungsten in biological systems. FEMS Microbiol. Rev. 18 (1996) 5-63
54. Koga A. Germanium, molybdenum, copper and zinc in New Zealand thermal waters. N.Z. J. Sci. 10 (1967) 428-446
55. Konhauser K.O., Powell M.A., Fyfe W.S., Longstaffe S., and Tripathy S. Trace element chemistry of major rivers in Orissa State, India. Environ. Sci. Tehnol. 26 (1997) 1433-1444
56. Koutsospyros A., Braida W., Christodoulatos C., Dermatas D., and Strigul N. A review of tungsten: from environmental obscurity to scrutiny. J. Hazard. Mater. 136 (2006) 1-19
57. Krainov S.R. Geochemistry of fluorine, tungsten and germanium in nitrogenous thermal waters of crystalline rocks. Geochemistry 1965 (1965) 1001-1011
58. Krauskopf K.B. Tungsten. In: Wedepohl H.K. (Ed). Handbook of Geochemistry vol. 5 (1974), Springer, New York
59. Kristmannsdóttir, H., 1979. Alteration of basaltic rock by hydrothermal activity at 100-300 °C. In: Proceedings of the Sixth International Clay Conference, Oxford, pp. 277-284.
60. Kunzendorf H., and Glasby G.P. Tungsten accumulation in Pacific ferro-manganese deposits. Miner. Deposita 27 (1992) 147-152
61. Kuroda P.K., and Sandell E.B. Geochemistry of molybdenum. Geochim. Cosmochim. Acta 6 (1954) 35-63
62. Levy D.B., Amrhein C., and Anderson M.A. Mineral precipitation and trace oxyanion behavior during evaporation of saline waters. J. Environ. Qual. 23 (1994) 944-954
63. Manheim F.T., and Landergren S. Molybdenum. In: Wedepohl H.K. (Ed). Handbook of Geochemistry vol. 4 (1974), Springer, New York
64. Neuhoff P.S., Fridriksson Th., Arnórsson S., and Bird D.K. Porosity, evolution and mineral paragenesis during low-grade metamorphism of basaltic lavas at Teigarhorn, eastern Iceland. Am. J. Sci. 299 (1999) 467-501
65. Neal C., Williams R.J., Neal M., Bhardwaj L.C., Wickham H., Harrow M., and Hill L.K. The water quality of the River Thames at a rural site downstream of Oxford. Sci. Total Environ. 251 (2000) 441-457
66. Óskarsson N., Sigvaldason G.E., and Steinthórsson S. A dynamic model of the rift zone petrogenesis and the regional petrology of Iceland. J. Petrol. 23 (1982) 28-74
67. Pálmason G., and Saemundsson K. Iceland in relation to the Mid-Atlantic Ridge. Ann. Rev. Earth Planet. Sci. 2 (1974) 25-50
68. Paulsen S.C., and List E.J. A study of transport and mixing in natural waters using ICP-MS: water-particle interactions. Water Soil Pollut. 99 (1997) 149-156
69. Pokrovski G.S., Schott J., Salvi S., Gout R., and Kubicki J.D. Structure and stability of aluminium-silica complexes in neutral to basic solutions. Experimental study and molecular orbital calculations. Min. Mag. 62A (1998) 1194-1195
70. Rabinovich A.V., Muraveva A.N., and Zhdanova M.V. Molybdenum content of certain rocks and minerals in the intrusives of eastern Transbaikal. Geochemistry(1958) (1958) 155-163
71. Rekharskii V.I. Molybdenum in intrusive rock minerals [in Russian]. In: Feodotiev K.M. (Ed). Ocherki Geokhimii, Rtuti, Molibdena Sery Gidroterm (1970), Nauka, Protsesse, Moscow (in Russian)
72. 5 Pascals) pressure and at higher temperatures. U.S. Geol. Surv. Bull. 2131 (1995) 461
73. Saemundsson K., and Fridleifsson I.B. Application of geology in geothermal research in Iceland. Náttúrufraedingurinn 60 (1980) 157-188 (In Icelandic with an English summary)
74. Saemundsson K., Kristjánsson L., McDougall I., and Watkins N.D. K-Ar dating, geological and paleomagnetic study of a 5 km lava succession in northern Iceland. J. Geophys. Res. 85 (1980) 3628-3646
75. Seiler R.L., Stollenwerk K.G., and Garbarino J.R. Factors controlling tungsten concentrations in ground water, Carson Desert, Nevada. Appl. Geochem. 20 (2005) 423-441
76. Sen N., Nockolds S.R., and Allen R. Trace elements in minerals from rocks of the S. Californian batholith. Geochim. Cosmochim. Acta 16 (1959) 58-78
77. Shannon R.D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. A 32 (1976) 751-767
78. Shaw T.J., Gieskes J.M., and Jahnke R.A. Early diagenesis in differing depositional environments: the response of transition metals in pure water. Geochim. Cosmochim. Acta 55 (1990) 1233-1246
79. Shiller A.M., and Boyle E.A. Trace-elements in the Mississippi river-delta outflow region-behavior at high discharge. Geochim. Cosmochim. Acta 55 (1991) 3241-3251
80. Shock E.L., Sassani D.C., Willis M., and Sverjensky D.A. Inorganic species in geologic fluids: correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes. Geochim. Cosmochim. Acta 61 (1997) 907-950
81. Smedley P.L., and Kinniburgh D.G. A review of the source, behavior and distribution of arsenic in natural waters. Appl. Geochem. 17 (2002) 517-568
82. Smith G.R. Materials flow of tungsten in the United States. United States of the Interior, Bureau of Mines, Information Circular (1994) C9388
83. Sohrin Y., Matsui M., and Nakayama E. Tungsten in North Pacific waters. Mar. Chem. 22 (1987) 95-103
84. Sohrin J., Matsui M., and Nakayama E. Contrasting behavior of tungsten and molybdenum in the Okinawa Trough, the East China Sea and the Yellow Sea. Geochim. Cosmochim. Acta 63 (1999) 2357-3466
85. Steinthórsson S., Óskarsson N., and Sigvaldason G.E. Origin of alkali basalts in Iceland-a plate tectonic model. J. Geophys. Res. 90 (1985) 27-42
86. Sugawara, K., 1967. Migration of elements through phases of the hydrosphere and atmosphere. In: A.P. Vinogradov (Ed.), Geochemistry of the Earth's Crust, vol. 2, Jerusalem.
87. Sun Y.C., Mierzwa J., and Lan C.R. Direct determination of molybdenum in seawater by adsorption cathodic stripping square-wave voltametry. Talanta 52 (2000) 417-424
88. Sveinbjörnsdóttir A.E., Arnórsson S., and Heinemeier J. Isotopic and chemical characteristics of old "ice age" groundwater, North Iceland. In: Cidu R. (Ed). Water-Rock Interaction (2001), Abingdon, Balkema 205-208
89. Taddeucci J., Pompilio M., and Scarlato P. Conduit processes during the July-August 2001 explosive activity of Mt. Etna (Italy): inferences from glass chemistry and crystal size distribution of ash particles. J. Volc. Geothermal Res. 137 (2004) 33-54
90. Tauson L.V., Sheremet E.M., and Antipin V.S. Trends in the distribution of molybdenum in the granitoids of northeastern Transbaikalia. Geochem. Int. 7 (1970) 637-642
91. Turekian K.K. Oceans (1968), Prentice Hall, Engelwood Cliffs, New Jersey
92. Van der Sloot H.A., Hoede D., Wijkstra J., Duinker J.C., and Nolting R.F. Anionic species of V, As, Se, Mo, Sb, Te and W in the Scheldt and Rhine estuaries and the Southern Bight (North Sea). Est. Coast Shelf Sci. 21 (1985) 633-651
93. Viollier E., Michard G., Jezequel D., Pepe M., and Sarazin G. Geochemical study of a crater lake: Lake Pavin, Puy de Dome, France. Constraints afforded by the particulate matter distribution in the elements cycling within the lake. Chem. Geol. 142 (1997) 225-241
94. Wager, L.R., Mitchell, R.L., 1948. The distribution of Cr, V, Ni, Co and Cu during the fractional crystallization of a basic magma. Internat. Geol. Congr. Report of the 18th Session, Great Britain, Part II.
95. Wager L.R., and Mitchell R.L. The distribution of trace elements during the strong fractionation of a basic magma-a further study of the Skaergaard intrusion, East Greenland. Geochim. Cosmochim. Acta 1 (1951) 129-208
96. Walker G.P.L. Zeolite zones and dike distribution in relation to the structure of the basalts of eastern Iceland. J. Geol. 68 (1960) 515-528
97. Wedepohl K.H. The composition of the continental crust. Geochim. Cosmochim. Acta 59 (1995) 1217-1232
98. Zheng Y., Anderson R.G., van Geen A., and Kuwabara J. Authigenic molybdenum formation in marine sediments: a link to pore water sulfide in the Santa Barbara Basin. Geochim. Cosmochim. Acta 64 (2000) 4165-4178