Homolytic dissociation of the vulcanization accelerator tetramethylthiuram disulfide (TMTD) and structures and stabilities of the related radicals Me 2NCSn• (n = 1-4)

Journal of Organic Chemistry

Volumn 71, Issue 25, 2006, Pages 9302-9311

  Steudel, Ralf ^a   Steudel, Yana ^a   Mak, Adrian Matthew ^b   Ming, Wah Wong ^b  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATION; CROSSLINKING; DISSOCIATION; PARAMAGNETISM; SYNTHETIC RUBBER; ZINC;

AB INITIO CALCULATIONS; HOMOLYTIC DISSOCIATION; SPIN DENSITY; TETRAMETHYLTHIURAM DISULFIDE (TMTD); ZINC IONS;

VULCANIZATION;

CATION; DISULFIDE; LIGAND; LITHIUM ION; METHYL GROUP; RADICAL; RUBBER; SULFUR; SULFUR DERIVATIVE; TETRAMETHYLTHIURAM TRISULFIDE; THIRAM; ZINC ION; ZINC OXIDE;

AB INITIO CALCULATION; ARTICLE; ATOM; CHELATION; CHEMICAL MODEL; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; COVALENT BOND; CROSS LINKING; DISSOCIATION; DISULFIDE BOND; ELECTRON; ELECTRON SPIN RESONANCE; ENTHALPY; ISOMER; MOLECULAR STABILITY;

EID: 33845530522     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo061345o     Document Type: Article

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