The mechanism of zinc(II)-dithiocarbamate-accelerated vulcanization uncovered; theoretical and experimental evidence

Journal of the American Chemical Society

Volumn 121, Issue 1, 1999, Pages 163-168

  Nieuwenhuizen, Peter J ^a   Ehlers, Andreas W ^b   Haasnoot, Jaap G ^b   Janse, Sander R ^a   Reedijk, Jan ^a,b   Baerends, Evert Jan ^b  

^a LEIDEN UNIVERSITY   (Netherlands)

^b VU UNIVERSITY AMSTERDAM   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

DITHIOCARBAMIC ACID DERIVATIVE; HYDROGEN SULFIDE; RUBBER; SULFIDE; ZINC COMPLEX;

CATALYSIS; CHEMICAL REACTION; CROSS LINKING; ENERGY; HEATING; NOTE; REACTION ANALYSIS; THERMODYNAMICS;

EID: 0033550527     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982217n     Document Type: Note

References (30)

1. Bateman, L.; Moore, C. G.; Porter, M.; Saville, B. In The Chemistry and Physics of Rubber-like Substances, 1st ed.; Bateman, L., Ed.; Maclaren & Sons Ltd.: London, 1963; pp 449-561.
2. Nieuwenhuizen, P. J.; Reedijk, J.; van Duin, M.; McGill, W. J. Rubber Chem. Technol., Rubber Rev. 1997, 70, 368-429.
3. Hofmann, W. Rubber Technology Handbook; Carl Hanser Verlag: Munich, 1989; pp 242-239.
4. Nieuwenhuizen, P. J.; Timal, S.; Haasnoot, J. G.; Spek, A. L.; Reedijk, J. Chem. Eur. J. 1997, 3, 1846-1851.
5. Scott, W.; Bedford, C. W. Ind. Eng. Chem. 1921, 13, 125-128.
6. Bedford, C. W.; Sebrell, L. B. Ind. Eng. Chem. 1922, 14, 25-31.
7. Nieuwenhuizen, P. J.; Ehlers, A. W.; Hofstraat, J. W.; Janse, S. R.; Nielen, M. W. F.; Reedijk, J.; Baerends, E. J. Chem. Eur. J. 1998, 4, 1816-1821.
8. Bonamico, M.; Dessy, G.; Fares, V.; Scaramuzza, L. J. Chem. Soc. (A) 1971, 3191-3195.
9. Versloot, P. Ph.D. Thesis, Leiden University, 1993.
10. Fonseca-Guerra, C.; Visser, O.; Snijders, J. G.; te Velde, G.; Baerends, E. J. In METECC-95; Clementi, E., Corongiu, C., Eds.; Cagliari, 1995; p 307.
11. Snijders, J. G.; Vernooijs, P.; Baerends, E. J. Internal report, Vrije Universteit Amsterdam: The Netherlands, 1981.
12. Snijders, J. G.; Baerends, E. J.; Vernooijs, P. At. Nucl. Data Tables 1982, 99, 84.
13. Baerends, E. J.; Ellis, D. E.; Ros, P. Chem. Phys. 1973, 2, 41.
14. Krijn, K.; Baerends, E. J. Internal Report, Vrije Universiteit Amsterdam: The Netherlands, 1984.
15. Baerends, E. J.; te Velde, G. J. Comput. Phys. 1992, 84.
16. Vosko, S. H.; WiIk, L.; Nusair, M. Can. J. Phys. 1980, 58, 1200.
17. Becke, A. D. Phys. Rev. A 1988, 38, 3098.
18. Perdew, J. P. Phys. Rev. B 1986, 33, 8822.
19. Versluis, L.; Ziegler, T. J. Chem. Phys. 1988, 322, 88.
20. Fan, L.; Versluis, L.; Ziegler, T.; Baerends, E. J.; Raveneck, W. Int. J. Quantum Chem.; Quantum. Chem. Symp. 1988, S22, 173.
21. Nieuwenhuizen, P. J.; Timal, S.; van Veen, J. M.; Haasnoot, J. G.; Reedijk, J. Rubber Chem. Technol. 1998, In press.
22. Versloot, P.; Haasnoot, J. G.; Reedijk, J.; van Duin, M.; Duynstee, E. F. J.; Put, J. Rubber Chem. Technol. 1992, 65, 343-349.
23. Versloot, P.; Haasnoot, J. G.; Reedijk, J.; van Duin, M.; Put, J. Rubber Chem. Technol. 1994, 67, 263-279.
24. Hammond, G. S. J. Am. Chem. Soc. 1955, 77, 334.
25. Peach, M. E. In The Chemistry of the Thiol Group; Patai, S., Ed.; John Wiley & Sons: London, 1974; Chapter 16.
26. Hahn, J. Z. Naturforsch. 1985, 40B, 263-272.
27. Holmberg, B. Ann. 1908, 359, 81-99.
28. Böhme, H.; Zimmer, G. Ann. 1954, 585, 142-149.
29. Fluharty, A. L. In The Chemistry of the Thiol Group; Patai, S., Ed.; John Wiley & Sons: London, 1974; Chapter 13.
30. Baldwin, F. P. Rubber Chem. Technol. 1972, 45, 1348-1365.