Metastable fluorides and potent oxidizers: Their preparation in liquid anhydrous HF, at room and lower temperatures

Actualite Chimique

Volumn , Issue 301-302, 2006, Pages 37-39

  Žemva, Boris ^a,b   Bartlett, Neil ^a,b  

^a JO EF STEFAN INSTITUTE   (Slovenia)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Electronegativity; High oxidation states; Liquid anhydrous HF; Oxidizers; Platinum metals

Indexed keywords

EID: 33845455827     PISSN: 01519093     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Review

References (33)

1. Moissan H., Le fluor et ses composés, G. Steinheil, Paris, 1900.
2. Sharpe A.G., Emeléus H.J., Chemistry of the inter-halogen compounds. Part I, The reactions of bromine trifluoride with metallic halides, J. Chem. Soc., 1948, p. 2135.
3. Sharpe A.G., Simple and complex fluorides of some noble metals, J. Chem. Soc., 1950, p. 3444.
4. 4, J. Chem. Soc., Chem. Communs., 1989, p. 346.
5. 4, J. Fluorine Chem., 1997, 89, p. 101.
6. Whalen J.M., Lucier G.M., Chacón L., Bartlett N., The room temperature conversion of nickel difluoride to hexafluoronickelate(IV) salts of alkali cations, J. Fluorine Chem., 1997, 88, p. 107.
7. Bartlett N., Hepworth M.A., Pure palladium difluoride, Chemistry and Industry, 1956, p. 1425.
8. Bartlett N., Maitland R., The crystal structure of palladium difluoride, Acta Cryst., 1958, 11, p. 747.
9. Bartlett N., Lohmann D.H., Fluorides of the noble metals. Part III. The fluorides of platinum, 1964, J. Chem. Soc., p. 619.
10. -, Proc. Chem. Soc., 1962, p. 115;
11. J. Chem. Soc., 1962, p. 5253.
12. -, Proc. Chem. Soc., 1962, p. 218.
13. 6 par diffraction neutronique, C.R. Acad. Sci. Paris, 1976, 282, Série C, p. 1069.
14. Bartlett N., Quail J.W., The preparation of palladium difluoride and complex fluorides of palladium in selenium tetrafluoride, J. Chem. Soc., 1961, p. 3728.
15. Bartlett N., Rao P.R., New fluorides of palladium: Palladium(II) hexafluoropalladate(IV) and related compounds and palladium tetrafluoride, Proc. Chem. Soc., 1964, p. 393.
16. 3, C.R. Sciences Acad. Sci., Ser. 2, 1983, 297, p. 117.
17. Christe K., Chemical synthesis of elemental fluorine, Inorg. Chem., 1986, 25, p. 3721.
18. Einstein F.W.B., Rao P.R., Trotter J., Bartlett N., The crystal structure of gold trifluoride, J. Chem. Soc. (A), 1967, p. 478.
19. O'Donnell T.A., Comprehensive Inorganic Chemistry, A.F. Trotman-Dickenson (ed), Pergamon Press, Oxford, New York, 1973, 2, p. 1038-1047.
20. Slivnik J., Šmalc A., Lutar K., Žemva B., Frlec B., A new method for the preparation of krypton difluoride, J. Fluorine Chem., 1975, 5, p. 273.
21. -, Inorg. Chem., 1989, 20, p. 3467.
22. 3, J. Amer. Chem. Soc., 1991, 113, p. 4192.
23. 3 syntheses and some properties, J. Amer. Chem. Soc., 1995, 117, p. 10025.
24. Klemm W., Huss E., Fluorokomplexe I. Eisen-, kobalt-, nickel- und kupferkomplexe, Z. Anorg. Chem., 1949, 258, p. 221.
25. Elder S.H., Lucier G.M., Hollander F.J., Bartlett N., The synthesis of Au(II) fluorocomplexes and their structural and magnetic properties, J. Amer. Chem. Soc., 1997, 119, p. 1020.
26. Žemva B., Hagiwara R., Casteel W.J. Jr., Lutar K., Jesih A., Bartlett N., The spontaneous oxidation of xenon to Xe(II) by cationic Ag(II) in anhydrous hydrogen fluoride solutions, J. Amer. Chem. Soc., 1990, 112, p. 4846.
27. Levin R.D., Lias S.G, Ionization potential and appearance potential measurements 1971-1981, NSRDS-NBS71, US Department of Commerce, Washington, DC 20234, October 1982.
28. Lucier G.M., Shen J., Casteel W.J. Jr., Chacón L., Bartlett N., Some chemistry of high oxidation state transition metal fluorides in anhydrous HF, J. Fluorine Chem., 1995, 72, p. 157.
29. 6, Acta Chim. Slov., 1999, 46(2), p. 141.
30. 2- anions, Inorg. Chem., 2000, 39, p. 2794.
31. - and characterization by fluorine-19 nuclear magnetic resonance spectroscopy, Inorg. Chem., 1974, 13, p. 1230.
32. - salts and their characterization by fluorine-19 nuclear magnetic resonance and Raman spectroscopy, Inorg. Chem., 1976, 15, p. 22.
33. 4, J. Fluorine Chem. (Christe issue), 2001, 112, p. 165.