Concurrent N-H and α-C-H bond activations of pyrrolidine and piperidine under ambient conditions by 18e tungsten allyl nitrosyl complexes

Journal of the American Chemical Society

Volumn 128, Issue 46, 2006, Pages 14762-14763

  Tsang, Jenkins Y K ^a   Fujita Takayama, Chikako ^a   Buschhaus, Miriam S A ^a   Patrick, Brian O ^a   Legzdins, Peter ^a  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

PIPERIDINE; PYRROLIDINE DERIVATIVE; TUNGSTEN DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; REACTION ANALYSIS; SOLID STATE;

EID: 33845219139     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja065663g     Document Type: Article

References (7)

1. Activation and Functionalization of C-H Bonds; Goldberg, K. I., Goldman, A. S., Eds.; ACS Symposium Series 885; American Chemical Society: Washington, DC, 2004.
2. Ng, S. H. K.; Adams, C. S.; Hayton, T. W.; Legzdins, P.; Patrick, B. O. J. Am. Chem. Soc. 2003, 125, 15210.
3. Complete experimental details and characterisation data are provided in the Supporting Information.
4. 2) = 0.94 for 12520 reflections and 264 variables.
5. A search of the Cambridge Structural Database reveals that typical W= N distances fall between 1.70 and 1.80 Å.
6. 1- pyrrolines, see Shvekhgeimer, M.-G. A. Chem. Heterocycl. Comp. 2003, 39, 405.
7. 2) = 1.065 for 6277 reflections and 272 variables.