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note
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3 symmetry. In the absence of chiral centers, the assemblies are present as a racemic mixture of P and M helices. If one enantiomer of a barbituric or cyanuric acid with a chiral center is used in the self-assembly, only one diastereoisomer of the double rosette (of P or M helicity) is formed, which represents an induction of supramolecular chirality. The diastereoisomerism of the double-rosette assemblies allows them to be studied by CD.
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The intercolumn distance h is calculated with the formula h = d/ cos(π/6), where d is the distance between the (100) planes, which corresponds to the distance between adjacent layers of double-rosette columns.
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