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Volumn 25, Issue 22, 2006, Pages 5435-5448

Chiral platinum duphos terminal phosphido complexes: Synthesis, structure, phosphido transfer, and ligand behavior

Author keywords

[No Author keywords available]

Indexed keywords

CHIRAL PLATINUM DUPHOS; LIGANDS; PHOSPHIDO COMPLEXES; PHOSPHIDO TRANSFER;

EID: 33751393607     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om060614y     Document Type: Article
Times cited : (30)

References (46)
  • 9
    • 0037073219 scopus 로고    scopus 로고
    • We showed earlier that Pd((R,R)-Me-Duphos)(Ph)(PMeIs) was a ca. 40:1 mixture of diastereomers at -60 °C (Moncarz, J. R.; Laritcheva, N. F.; Glueck, D. S. J. Am. Chem. Soc. 2002, 124, 13356-13357). These complexes decompose by P - C reductive elimination at room temperature, but the Pt analogues reported here are thermally stable.
    • (2002) J. Am. Chem. Soc. , vol.124 , pp. 13356-13357
    • Moncarz, J.R.1    Laritcheva, N.F.2    Glueck, D.S.3
  • 10
    • 33644934051 scopus 로고    scopus 로고
    • For the use of the phosphido complexes as catalyst precursors in asymmetric alkylation of PHMe(Is), see: (a) Scriban, C.; Glueck, D. S. J. Am. Chem. Soc. 2006, 128, 2788-2789. For the related use of chiral cationic Pt - bis(phosphine) moieties for the selective binding of chiral phosphines or amines, see:
    • (2006) J. Am. Chem. Soc. , vol.128 , pp. 2788-2789
    • Scriban, C.1    Glueck, D.S.2
  • 16
    • 14844332720 scopus 로고    scopus 로고
    • This phenomenon has been observed for related electron-rich terminal phosphido complexes which could also not be isolated in analytically pure form; see: Giner Planas, J.; Hampel, F.; Gladysz, J. A. Chem. Eur. J. 2005, 11, 1402-1416.
    • (2005) Chem. Eur. J. , vol.11 , pp. 1402-1416
    • Giner Planas, J.1    Hampel, F.2    Gladysz, J.A.3
  • 17
    • 0035961019 scopus 로고    scopus 로고
    • For protonation of air-sensitive tertiary phosphines to yield air-stable phosphonium salts, see: Netherton, M. R.; Fu, G. C. Org. Lett. 2001, 3, 4295-4298.
    • (2001) Org. Lett. , vol.3 , pp. 4295-4298
    • Netherton, M.R.1    Fu, G.C.2
  • 28
    • 33751423661 scopus 로고    scopus 로고
    • References 7b,c
    • (b) References 7b,c.
  • 38
    • 33751398255 scopus 로고    scopus 로고
    • note
    • 11
  • 44
    • 0010952895 scopus 로고
    • 22 was observed in the Pt satellites. For similar observations in Pt - phosphine complexes, see: (a) Sperline, R. P.; Beaulieu, W. B.; Roundhill, D. M. Inorg. Chem. 1978, 17, 2032-2035.
    • (1978) Inorg. Chem. , vol.17 , pp. 2032-2035
    • Sperline, R.P.1    Beaulieu, W.B.2    Roundhill, D.M.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.