Terminal Platinum(II) Perfluoroacyl Phosphido Complexes: Synthesis and Dynamic Processes

Organometallics

Volumn 18, Issue 24, 1999, Pages 5130-5140

  Wicht, Denyce K ^a   Glueck, David S ^a   Liable Sands, Louise M ^b   Rheingold, Arnold L ^b  

^a Dartmouth College   (United States)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000346162     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9903691     Document Type: Article

References (42)

1. For examples, see: (a) Zwick, B. D.; Dewey, M. A.; Knight, D. A.; Buhro, W. E.; Arif, A. M.; Gladysz, J. A. Organometallics 1992, 11, 2673-2685.
2. (b) Buhro, W. E.; Zwick, B. D.; Georgiou, S.; Hutchinson, J. P.; Gladysz, J. A. J. Am. Chem. Soc. 1988, 110, 2427-2439.
3. (c) Simpson, R. D.; Bergman, R. G. Organometallics 1992, 11, 3980-3993.
4. Crisp, G. T.; Salem, G.; Wild, S. B.; Stephan, F. S. Organometallics 1989, 8, 2360-2367.
5. (e) Malisch, W.; Maisch, R.; Meyer, A.; Greissinger, D.; Gross, E.; Colquhoun, E. J.; McFarlane, W. Phosphorus Sulfur 1983, 18, 299-302.
6. (f) Baker, R. T.; Whitney, J. G.; Wreford, S. S. Organometallics 1983, 2, 1049-1051.
7. (g) Bonnet, G.; Kubicki, M. M.; Moise, C.; Lazzaroni, R.; Salvadori, P.; Vitulli, G. Organometallics 1992, 11, 964-967.
8. (h) Fryzuk, M. D.; Joshi, K.; Chadha, R. K.; Rettig, S. J. J. Am. Chem. Soc. 1991, 113, 8724-8736.
9. Malisch, W.; Gunzelmann, N.; Thirase, K.; Neumayer, M. J. Organomet. Chem. 1998, 571, 215-222.
10. (j) For a review, see: Rogers, J. R.; Wagner, T. P. S.; Marynick, D. S. Inorg. Chem. 1994, 33, 3104-3110.
11. Wicht, D. K.; Kovacik, I.; Glueck, D. S.; Liable-Sands, L. M.; Incarvito, C. D.; Rheingold, A. L. Organometallics 1999, 18, 5141.
12. Bryndza, H. E.; Calabrese, J. C.; Wreford, S. S. Organometallics 1984, 3, 1603-1604.
13. Wicht, D. K.; Paisner, S. N.; Lew, B. M.; Glueck, D. S.; Yap, G. P. A.; Liable-Sands, L. M.; Rheingold, A. L.; Haar, C. M.; Nolan, S. P. Organometallics 1998, 17, 652-660.
14. Brauer, D. J.; Bitterer, F.; Dörrenbach, F.; Hebler, G.; Stelzer, O.; Krüger, C.; Lutz, F. Z. Naturforsch. 1996, 51B, 1183-1196.
15. 31P NMR spectrum is due to a dynamic process involving rotation around the Pt-PPhIs bond (see below).
16. Bennett, M. A.; Chee, H.-K.; Robertson, G. B. Inorg. Chem. 1979, 18, 1061-1070.
17. Bennett, M. A.; Ho, K.-C.; Jeffery, J. C.; McLaughlin, G. M.; Robertson, G. B. Aust. J. Chem. 1982, 35, 1311-1321.
18. Pt-P = 4370, P trans to NCMe). Appleton, T. G.; Bennett, M. A. Inorg. Chem. 1978, 17, 738-747.
19. (a) Bohle, D. S.; Jones, T. C.; Rickard, C. E. F.; Roper, W. R. Organometallics 1986, 5, 1612-1619.
20. (b) Deeming, A. J.; Doherty, S.; Marshall, J. E.; Powell, J. L.; Senior, A. M. J. Chem. Soc., Dalton Trans. 1993, 1093-1100.
21. (c) Handler, A.; Peringer, P.; Müller, E. P. J. Chem. Soc., Dalton Trans. 1990, 3725-3727.
22. (d) Ref 1b.
23. Friebolin, H. In Basic One- and Two-Dimensional NMR Spectroscopy, 2nd ed.; VCH: New York, 1993; pp 287-314. See the Experimental Section for more details and error analysis.
24. Gallaher, K. L.; Yokozeki, A.; Bauer, S. H. J. Phys. Chem. 1974, 78, 2389-2395.
25. Ohkita, K.; Kurosawa, H.; Hirao, T.; Ikeda, I. J. Organomet. Chem. 1994, 470, 179-182.
26. Deeming, A. J.; Doherty, S. Polyhedron 1996, 15, 1175-1190.
27. (a) Deeming, A. J.; Cockerton, B. R.; Doherty, S. Polyhedron 1997, 16, 1945-1956.
28. (b) Dobbie, R. C.; Mason, P. R. J. Chem. Soc., Dalton Trans. 1976, 189-191.
29. Maassarani, F.; Davidson, M. F.; Wehman-Ooyevaar, I. C. M.; Grove, D. M.; van Koten, M. A.; Smeets, W. J. J.; Spek, A. L.; van Koten, G. Inorg. Chim. Acta 1995, 235, 327-338.
30. 2 fluorines inequivalent even if inversion were fast on the NMR time scale.
31. 31P NMR spectrum of Pt(dppe)(Me)(PPhIs) (2).
32. Baechler, R. D.; Mislow, K. J. Am. Chem. Soc. 1971, 93, 773-774.
33. Mislow, K. Trans. N. Y. Acad. Sci. 1973, 35, 227-242.
34. Mayer, J. M. Comments Inorg. Chem. 1988, 8, 125-135.
35. Dahlenburg, L.; Hock, N.; Berke, H. Chem. Ber. 1988, 121, 2083-2093.
36. Butts, M. D.; Scott, B. L.; Kubas, G. J. J. Am. Chem. Soc. 1996, 118, 11831-11843.
37. Dahlenburg and co-workers (ref 21) include similar mixing with a d-orbital of this symmetry, but use a slightly different coordinate system.
38. Vedejs, E.; Donde, Y. J. Am. Chem. Soc. 1997, 119, 9293-9294.
39. Wicht, D. K.; Kourkine, I. V.; Kovacik, I.; Glueck, D. S.; Concolino, T. E.; Yap, G. P. A.; Incarvito, C. D.; Rheingold, A. L. Organometallics, accepted for publication.
40. Carr, G. E.; Chambers, R. D.; Holmes, J. F.; Parker, D. G. J. Organomet. Chem. 1987, 325, 13-23.
41. Schollz, M.; Roesky, H. W.; Stalke, D.; Keller, K.; Edelmann, F. T. J. Organomet. Chem. 1989, 366, 73-85.
42. Walker, N.; Stuart, D. Acta Crystallogr. 1983, A39, 158-166.