Coupling reactions of alkynes with half-open titanocenes: Agostic (C-C) → Ti interactions in a tetra(alkyne) coupling product with the Ti(C5H5)(c-C8H11) fragment

Journal of Organometallic Chemistry

Volumn 691, Issue 24-25, 2006, Pages 5211-5217

  Harvey, Benjamin G ^a   Arif, Atta M ^a   Ernst, Richard D ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

Agostic; Cyclooctadienyl; Metallacyclobutane; Metallacyclobutene; Pentadienyl

Indexed keywords

COMPLEXATION; ORGANOMETALLICS; REACTION KINETICS; TITANIUM COMPOUNDS;

AGOSTIC; CYCLOOCTADIENYL; METALLACYCLOBUTANE; METALLACYCLOBUTENE; PENTADIENYL;

HYDROCARBONS;

TETRA;

EID: 33751210615     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.08.086     Document Type: Article

References (29)

1. Harvey B.G., Mayne C.L., Arif A.M., Tomaszewski R., and Ernst R.D. J. Am. Chem. Soc. 127 (2005) 16426 (corrn.: 128 (2006) 1770)
2. Tomaszewski R., Hyla-Kryspin I., Mayne C.L., Arif A.M., Gleiter R., and Ernst R.D. J. Am. Chem. Soc. 120 (1998) 2959
3. Wilson A.M., Waldman T.E., Rheingold A.L., and Ernst R.D. J. Am. Chem. Soc. 114 (1992) 6252
4. Tillack A., Baumann W., Ohff A., Lefeber C., Spannenberg A., Kempe R., and Rosenthal U. J. Organomet. Chem. 520 (1996) 187
5. Rosenthal U., Pellny P.-M., Kirchbauer F.G., and Burlakov V.V. Acc. Chem. Res. 33 (2000) 119
6. Jaffart J., Etienne M., Reinhold M., McGrady J.E., and Maseras F. Chem. Commun. (2003) 876
7. For a lithium complex, see. Goldfuss B., Schleyer P.v.R., and Hampel F. J. Am. Chem. Soc. 118 (1996) 12183
8. Herisson J.L., and Chauvin Y. Makromol. Chem. 141 (1970) 161
9. Soufflet J.P., Commereuc D., and Chauvin Y. Compt. Rend., Ser. C. 276 (1973) 169
10. Katz T.J. Adv. Organomet. Chem. 16 (1977) 283
11. Schrock R.R., and Hoveyda A.H. Angew. Chem. Intl. Ed. 42 (2003) 45
12. In: Grubbs R.H. (Ed). Handbook of Metathesis (2003), Wiley, New York
13. Hoveyda A.H., and Schrock R.R. Comp. Asym. Catal. Suppl. 1 (2004) 207
14. Grubbs R.H. Tetrahedron 60 (2004) 7117
15. Suresh C.H., and Koga N. Organometallics 23 (2004) 76
16. Suresh C.H., and Baik M.-H. Dalton Trans. (2005) 2982
17. Wilson A.M., West F.G., Rheingold A.L., and Ernst R.D. Inorg. Chim. Acta 300-302 (2000) 65
18. Hyla-Kryspin I., Waldman T.E., Meléndez E., Trakarnpruk W., Arif A.M., Ziegler M.L., Ernst R.D., and Gleiter R. Organometallics 14 (1995) 5030
19. V. Kulsomphob, Ph.D. Dissertation, University of Utah, 1999.
20. Kulsomphob V., Harvey B.G., Arif A.M., and Ernst R.D. Inorg. Chim. Acta 334 (2002) 17
21. Basta R., Harvey B.G., Arif A.M., and Ernst R.D. Inorg. Chim. Acta 357 (2004) 3883
22. Wilson A.M., West F.G., Arif A.M., and Ernst R.D. J. Am. Chem. Soc. 117 (1995) 8490
23. S. Otsuka, A. Nakamura, in: R. West, F.G.A. Stone (Eds.), Advances in Organometallic Chemistry, vol. 14, 1976, p. 245.
24. J. Templeton, in: R. West, F.G.A. Stone (Eds.), Advances in Organometallic Chemistry, vol. 29, 1989, p. 1.
25. Tebbe F.N., and Harlow R.L. J. Am. Chem. Soc. 102 (1980) 6149
26. See also:. McKinney R.J., Tulip T.H., Thorn D.L., Coolbaugh T.S., and Tebbe F.N. J. Am. Chem. Soc. 103 (1981) 5584
27. Ogoshi S., and Stryker J.M. J. Am. Chem. Soc. 120 (1998) 3514
28. Binger P., Müller P., Herrmann A.T., Phillips P., Gabor B., Langhauser F., and Krüger C. Chem. Ber. 124 (1991) 2165
29. B.G. Harvey, Ph.D. Dissertation, University of Utah, 2005.