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33751063452
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note
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4 and the crude reaction residue, obtained after solvent removal, was purified by column chromatography (CC) on silica gel (hexane/AcOEt, 99:1) and then crystallized or precipitated from an appropriate solvent system. Further details are given for the individual compounds in Supplementary data.
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23
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0004146786
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30144438056
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0010406433
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Van Duynhoven J.P.M., Janssen R.G., Verboom W., Franken S.M., Casnati A., Pochini A., Ungaro R., de Mendoza J., Nieto P.M., Prados P., and Reinhoudt D.N. J. Am. Chem. Soc. 116 (1994) 5814-5822
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32
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33751034271
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note
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3, produced precipitation of 1c.
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33
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33751039681
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note
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2s were positioned by splitting the chains into at least two models (three and four for those attached to calixarene rings E and A, respectively). In all instances, pentadecafluoroheptyl chains were found to adopt random anti and gauche conformations. The oxadiazole residue attached to ring A along with the tert-butyl groups of rings A and E were also found to be disordered. Crystallographic data (excluding structure factors) for the structure in this paper have been deposited with the Cambridge Crystallographic Data centre as Supplementary Publication Number CCDC 621722. Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax: +44 (0)1223 336033 or e-mail: deposit@ccdc.cam.ac.uk].
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34
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37049074917
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This type of distorted conformation is quite common for calix[5]arene derivatives. See:
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This type of distorted conformation is quite common for calix[5]arene derivatives. See:. Barrett G., McKervey M.A., Malone J.F., Walker A., Arnaud-Neu F., Guerra L., Schwing-Weill M.-J., Gutsche C.D., and Stewart D.R. J. Chem. Soc., Perkin Trans. 2 (1993) 1475-1479
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Barrett, G.1
McKervey, M.A.2
Malone, J.F.3
Walker, A.4
Arnaud-Neu, F.5
Guerra, L.6
Schwing-Weill, M.-J.7
Gutsche, C.D.8
Stewart, D.R.9
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35
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0001208018
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Bell S.E., Browne J.K., McKee V., McKervey M.A., Malone J.F., O'Leary M., and Walker A. J. Org. Chem. 63 (1998) 489-501
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O'Leary, M.6
Walker, A.7
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