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The Royal Society of Chemistry, Cambridge
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(Eds.: Z. Asfari, V. Böhmer, J. Harrowfield, J. Vicens), Kluwer, Dordrecht, The Netherlands
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[1g] (Eds.: Z. Asfari, V. Böhmer, J. Harrowfield, J. Vicens), Calixarenes 2001, Kluwer, Dordrecht, The Netherlands, 2001.
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In comparison, only a 50% yield is achieved for the monoarylation of phenol: A. Loupy, N. Philippon, P. Pigeon, H. Galons, Heterocycles 1991, 32, 10, 1947-1953.
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[13a] L. C. Groenen, J. D. van Loon, W. Verboom, S. Harkema, A. Casnati, R. Ungaro, A. Pochini, F. Ugozzoli, D. N. Reinhoudt, J. Am. Chem. Soc. 1991, 113, 2385-2392.
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0002444335
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0344613348
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note
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-1. A total of 3912 reflections, 203 parameters (2.30 < Θ < 25.03°) were collected, of which 2538 reflections were unique (R1 = 0.0492), I > 2σ(I), wR2 = 0.1342 for all reflections
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0344181766
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α radiation, T = 213 K (for compound 3b) and 203 K (for compound 4)]. Both structures were solved by direct methods and refined by full-matrix, least-squares with SHELXTL-97.[26] The contribution of the disordered solvent in molecule 4 to the structure factors was taken into account by back-Fourier transformation with PLATON/SQUEEZE.[27] All non-hydrogen atoms were refined by use of anisotropic thermal parameters; hydrogen atoms were included by use of a riding model and fixed isotropic thermal parameters. The hydroxy H atoms were refined isotropically, while those attached to C atoms were positioned geometrically, with C-H = 0.98-0.99 Å, and refined as riding atoms. X-ray data have been deposited at the Cambridge Crystallographic Data Centre (deposition number CCDC-204902 for 3b and CCDC-204901 for 4). Copies of the data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/ retrieving.html [or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ [Fax: (internat.) +44-1223-336033; E-mail: deposit@ccdc.carn.ac.uk].
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T. Steiner, Angew. Chem. 2002, 114, 50-80 Angew. Chem. Int. Ed. 2002, 41, 48-76.
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0344181765
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We prefer the term "supracycle" as an abbreviation for "supramolecular cyclic structure", since the expression "molecular daisy chain" - an analogy suggested before - might give rise to misunderstandings: P. R. Ashton, R. Ballardini, V. Balzani, S. E. Boyd, A. Credi, M. T. Gandolfi, M. Gomez-Lopez, S. Iqbal, D. Philp, J. A. Preece, L. Prodi, H. G. Ricketts, J. F. Stoddart, M. S. Tolley, M. Venturi, A. J. P White, D. J. Williams, Chem. Eur. J. 1997, 3, 153-170.
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Tolley, M.S.14
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Williams, D.J.17
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36
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0000334793
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[18b] R. Ungaro, A. Casnati, F. Ugozzoli, A. Pochini, J.-F. Dozol, C. Hill, H. Roquette, Angew. Chem. 1994, 106, 1551-1553; Angew. Chem. Int. Ed. Engl. 1994, 33, 1506-1509.
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Ungaro, R.7
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39
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For recent reviews on metal-mediated self-assembly (in general limited to metal complexes as crucial links within the supramolecular structures), see: [19a] S. Leininger, B. Olenyuk, P. J. Stang, Chem. Rev. 2000, 100, 853-908.
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Leininger, S.1
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For a hexameric supracycle of porphyrins based on complexation as aggregating principle, see: R. Takahashi, Y. Kobuke, J. Am. Chem. Soc. 2003, 125, 2372-2373.
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