Sorption-desorption of cadmium in aqueous palygorskite, sepiolite, and calcite suspensions: Isotherm hysteresis

Chemosphere

Volumn 65, Issue 11, 2006, Pages 2178-2184

  Shirvani, Mehran ^a   Kalbasi, Mahmoud ^a   Shariatmadari, Hosein ^a   Nourbakhsh, Farshid ^a   Najafi, Bijan ^a  

^a ISFAHAN UNIVERSITY OF TECHNOLOGY   (Iran)

Author keywords

Cd; Hysteretic adsorption; Release; Reversibility

Indexed keywords

ADSORPTION ISOTHERMS; CADMIUM; CALCITE; CONCENTRATION (PROCESS); DESORPTION; SUSPENSIONS (FLUIDS);

HYSTERETIC ADSORPTION; PALYGORSKITE; REVERSIBILITY; SEPIOLITE;

SOIL POLLUTION CONTROL;

ATTAPULGITE; CADMIUM; CALCIUM CARBONATE; MAGNESIUM TRISILICATE;

ADSORPTION ISOTHERMS; CADMIUM; CALCITE; CONCENTRATION (PROCESS); DESORPTION; SOIL POLLUTION CONTROL; SUSPENSIONS (FLUIDS);

AQUEOUS SOLUTION; CADMIUM; CALCITE; DESORPTION; HYSTERESIS; ISOTHERM; PALYGORSKITE; SEPIOLITE; SORPTION;

ARTICLE; DESORPTION; DILUTION; HYSTERESIS; ISOTHERM;

EID: 33751013007     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2006.06.002     Document Type: Article

References (27)

1. Ainsworth C.C., Pilon J.L., Gassman P.L., and Van der Sluys W.G. Cobalt, cadmium and lead sorption to hydrous iron oxide: residence time effect. Soil Sci. Soc. Am. J. 58 (1994) 1615-1623
2. Alvarez-Ayuso E., and Garcia-Sanchez D.A. Sepiolite as a feasible soil additive for the immobilization of cadmium and zinc. Sci. Total Environ. 305 (2003) 1-12
3. Alvarez-Ayuso E., and Garcia-Sanchez D.A. Palygorskite as a feasible amendment to stabilize heavy metal polluted soils. Environ. Pollut. 125 (2003) 337-344
4. Appel C., and Ma L. Concentration, pH, and surface charge effects on cadmium and lead sorption in three tropical soils. J. Environ. Qual. 31 (2002) 581-589
5. Atanassova I.D. Adsorption and desorption of Cu at high equilibrium concentrations by soil and clay samples from Bulgaria. Environ. Pollut. 87 (1995) 17-21
6. Businelli M., Casciari F., Businelli D., and Gigliotti G. Mechanisms of Pb (II) sorption and desorption at some clays and goethite-water interfaces. Agronomie 23 (2003) 219-225
7. 2+ and subsequent solid solution formation. Geochim. Cosmochim. Acta. 51 (1987) 1477-1490
8. Essington M.E. Soil and Water Chemistry: An Integrative Approach (2004), CRC Press, Boca Raton, Florida
9. Filius A., Streck T., and Richter J. Cadmium sorption and desorption in limed topsoils as influenced by pH: Isotherms and simulated leaching. J. Environ. Qual. 27 (1998) 12-18
10. Gustafsson, J.P., 2005. Available from: .
11. Hutchison J.M., Seaman J.C., Aburime S.A., and Radcliffe D.E. Chromate transport and retention in variably saturated soil columns. Vadose Zone J. 2 (2003) 702-714
12. Khademi H., and Mermut A.R. Submicroscopy and stable isotope geochemistry of carbonates and associated palygorskite in selected Iranian Aridisols. Eur. J. Soil Sci. 50 (1998) 207-216
13. Kittrick J.A., and Hope E.W. A procedure for the particle size separation of soils for X-ray diffraction analysis. Soil Sci. 96 (1963) 312-325
14. Ma L., Southwick L.M., Willis G.H., and Selim H.M. Hysteresis characteristics of atrazine adsorption-desorption by a Sharkey soil. Weed Sci. 41 (1993) 627-633
15. Martin-Garin A., Van Cappellen P., and Charlet L. Aqueous cadmium uptake by calcite: A stirred flow-through reactor study. Geochim. Cosmochim. Acta. 67 (2003) 2763-2774
16. McBride M.B. Chemisorption and precipitation reactions. In: Sumner M.E. (Ed). Handbook of Soil Science (2000), CRC Press, Boca Raton, FL B265-B302
17. Moradi A., Abbaspour K.C., and Afyuni M. Modelling field-scale cadmium transport below the root zone of a sewage sludge amended soil in an arid region in Central Iran. J. Contam. Hydrol. 79 (2005) 187-206
18. Morton J.D., Semrau J.D., and Hayes K.F. An X-ray absorption spectroscopy study of the structure and reversibility of copper adsorbed to montmorillonite clay. Geochim. Cosmochim. Acta. 65 (2001) 2709-2722
19. 2+ on bentonite. In: Jenne E.A. (Ed). Adsorption of Metals by Geomedia: Variables, Mechanisms and Model Applications (1998), Academic Press, San Diego, CA 277-289
20. Padmanabham M. Adsorption-desorption behavior of copper (II) at the goethite-solution interface. Aust. J. Soil Res. 21 (1983) 309-320
21. Rhoads J.W. Cation exchange capacity. In: Page C.A. (Ed). Methods of Soil Analysis Part 2 (1986), ASA, Madison, WI. 149-158
22. Seuntjens P., Tirez K., Simunek J., van Genuchten M.Th., Cornelis C., and Geuzens P. Aging effects on cadmium transport in undisturbed contaminated sandy soil columns. J. Environ. Qual. 30 (2001) 1040-1050
23. Seybold C.A., and Mersie W. Adsorption and desorption of atrazine, deethylatrazine, deisopropylatrazine, hydroxyatrazine, and metolachlor in two soils from Virginia. J. Environ. Qual. 25 (1996) 1179-1185
24. Shirvani, M., Shariatmadari, H., Kalbasi., M., Nourbakhsh, F., Najafi, B., in press. Sorption of cadmium on palygorskite, sepiolite and calcite: equilibria and organic ligand affected kinetics. Colloid. Surf. A.
25. Strawn D.G., and Sparks D.L. Sorption kinetics of trace elements in soils and soil materials. In: Selim H.M., and Iskandar I. (Eds). Fate and Transport of Heavy Metals in the Vadose Zone (1999), Lewis Publishers, Chelsea, MI 1-28
26. Turin H.J., and Bowman R.S. Sorption behavior and competition of bromacil, napropamide, and prometryn. J. Environ. Qual. 26 (1997) 1282-1287
27. Xiangke W., Wenming D., Zhi L., Jinzhou D., and Zuyi T. Sorption and desorption of radiocesium on red earth and its solid components: relative contribution and hysteresis. Appl. Radiat. Isoto. 52 (2000) 813-819