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Volumn 128, Issue 44, 2006, Pages 14222-14223

A low-spin alkylperoxo-iron(III) complex with weak Fe-O and O-O bonds: Implications for the mechanism of superoxide reductase

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL GROUP; IRON COMPLEX; OXIDOREDUCTASE; SUPEROXIDE REDUCTASE; UNCLASSIFIED DRUG;

EID: 33750702519     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja064525o     Document Type: Article
Times cited : (44)

References (22)
  • 7
  • 21
    • 33750698029 scopus 로고    scopus 로고
    • note
    • III-OOR species during the manual mixing time in the EPR tube. In contrast, the UV-vis spectra for 2 are obtained within a few seconds after addition of ROOH. Moreover, the ∼5-fold increase in concentration of reactants in the EPR experiments compared to those used in the UV-vis will accelerate intermolecular decay pathways. Thus, it is reasonable to estimate e values for 2 based on 100% conversion despite the EPR quantitation measurements.
  • 22
    • 33750733693 scopus 로고    scopus 로고
    • note
    • Deuteration of 1 at the N-H positions does not change the v(Fe-O), ruling out hydrogen bonding as the cause of the low frequency.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.