"Kinetic NMR titration": Including chemical shift information in the kinetic analysis of supramolecular reaction systems such as organic replicators

Journal of the American Chemical Society

Volumn 128, Issue 43, 2006, Pages 14014-14015

  Stahl, Insa ^a   Von Kiedrowski, Günter ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACCURACY; ARTICLE; DIASTEREOISOMER; DIELS ALDER REACTION; ENANTIOMER; ISOMER; KINETICS; PARAMETER; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; SIGNAL DETECTION; SUPRAMOLECULAR CHEMISTRY; THERMODYNAMICS; TITRIMETRY;

EID: 33750491118     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja065894n     Document Type: Article

References (20)

1. For the classical example of an organic replicator, see: (a) Tjivikua, T.; Ballester, P.; Rebek, J., Jr. J. Am. Chem. Soc. 1990, 112, 1249-1250.
2. (b) Menger, F. M.; Eliseev, A. V.; Khanjin, N. A. J. Am. Chem. Soc. 1994, 116, 3613-3614.
3. (c) Reinhoudt, D. N.; Rudkevich, D. M.; de Jong, F. J. Am. Chem. Soc. 1996, 118, 6880-6889.
4. Terfort, A.; von Kiedrowski, G. Angew. Chem. 1992, 104, 626-628;
5. Angew. Chem., Int. Ed. Engl. 1992, 31, 654-656.
6. Wang, B.; Sutherland, I. O. Chem. Commun. 1997, 1495-1496.
7. Allen, V. C.; Philp, D.; Spencer, N. Org. Lett. 2001, 3, 777-780.
8. Kindermann, M.; Stahl, I.; Reimold, M.; Pankau, W. M.; von Kiedrowski, G. Angew. Chem. 2005, 117, 6908-6913;
9. Angew. Chem., Int. Ed. 2005, 441, 6750-6755.
10. (a) Wilcox, C. S. Frontiers in Supramolecular Organic Chemistry and Photochemistry, VCH: Weinheim, New York, Basel, Cambridge, 1991: pp 123-143.
11. (b) Santos, M. A.; Afonso, A.; Marques, M. M.; Wilcox, C. Supramol. Chem. 2000, 11, 201-215.
12. SimFit expanded program is available from the author (G.v.K.) on request.
13. For similar SimFit applications, see: (a) Sievers, D.; von Kiedrowski, G.; Nature 1994, 369, 221-224.
14. (b) Sievers, D.; von Kiedrowski, G. Chem-Eur. J. 1998, 4, 629-641.
15. (c) Schöneborn, H.; Bülle, J.; von Kiedrowski, G. ChemBioChem 2001, 2, 922-927.
16. (d) Severin, K.; Lee, D. H.; Kennan, A. J.; Ghadiri, M. R. Nature 1997, 289, 706-709.
17. (e) Yao, S.; Gosh, I.; Zutshi, R.; Chmielewski, J. Angew. Chem. 1998, 110, 489-492;
18. Angew. Chem., Int. Ed. 1998, 37, 478-481.
19. (f) Pearson, R. J.; Kassianidis, E.; Slavin, A. M. Z.; Philp, D. Biomol. Chem. 2004, 2, 3434-3441.
20. Stahl, I. Analysis and classification of minimal self-replicating systems based on Diels-Alder ligation chemistry. Ph.D. Thesis, Ruhr-Universität Bochum, 2005 (http://www-brs.ub.ruhr-uni-bochum.de/netahtml/HSS/Diss/StahlInsa/) .