Distinction of Tris(diimine)ruthenium(II) enantiomers chiral by virtue of helical chirality: Temperature-dependent deuterium NMR spectroscopy in partially oriented phases

Magnetic Resonance in Chemistry

Volumn 44, Issue 11, 2006, Pages 1044-1050

  Szalontai, Gábor ^a   Kovács, Margit ^a  

^a UNIVERSITY OF PANNONIA   (Hungary)

Author keywords

2H; 2H relaxation; Helical chirality; Liquid crystalline phase; NMR; Residual quadrupolar effect; Temperature and ligand size effects; Tris(diimine)ruthenium(II) enantiomers

Indexed keywords

CHIRALITY; CRYSTALLINE MATERIALS; DEUTERIUM; ENANTIOMERS; METAL COMPLEXES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RUTHENIUM COMPOUNDS; TEMPERATURE;

2H; 2H RELAXATION; DIIMINES; HELICAL CHIRALITY; LIQUID-CRYSTALLINE PHASIS; QUADRUPOLAR EFFECTS; RESIDUAL QUADRUPOLAR EFFECT; SIZES EFFECT; TEMPERATURE AND LIGAND SIZE EFFECT; TRIS(DIIMINE)RUTHENIUM(II) ENANTIOMER;

LIGANDS;

EID: 33750480833     PISSN: 07491581     EISSN: 1097458X     Source Type: Journal    
DOI: 10.1002/mrc.1892     Document Type: Article

References (22)

1. Meddour A, Canet I, Loewenstein A, Péchiné JP, Courtieu J. J. Am. Chem. Soc. 1994; 116: 9652.
2. Meddour A, Loewenstein A, Péchiné JP, Courtieu J. Tetrahedron Asymmetry 1997; 8: 485.
3. Merlet D, Ancian B, Courtieu J, Lesot P. J. Am. Chem. Soc. 1999; 121: 5249.
4. Lesot P, Merlet D, Loewenstein A, Courtieu J. Tetrahedron Asymmetry 1998; 9: 1871.
5. Meddour A, Atkinson D, Loewenstein A, Courtieu J. Chem. Eur. J. 1998; 4: 1142.
6. Meddour A, Canlet C, Blanco L, Courtieu J. Angew. Chem. Int. Ed. 1999; 38: 2391.
7. Canet JL, Canet I, Gelas J, Ripoche I, Troin Y. Tetrahedron Asymmetry 1997; 8: 2447.
8. Canet C, Merlet D, Lesot P, Meddour A, Loewenstein A, Courtieu J. Tetrahedron Asymmetry 2000; 11: 1911.
9. Lesot P, Merlet D, Sarfati M, Courtieu J, Zimmerman H, Luz Z. J. Am. Chem. Soc. 2002; 124: 10071.
10. Lesot P, Lafon O, Kagan HB, Fan CA. Chem. Commun. 2006; 4: 389.
11. (a) Samulski ET. Liquid Crystalline Order in Polymers. Academic Press: New York, 1978;
12. (b) Emsley JW, Lyndon JC. NMR Spectroscopy using liquid crystal solvents, Pergamon Press: Oxford, 1975;
13. (c) Emsley JW. Nuclear Magnetic Resonance of liquid crystals, Dordrecht: The Netherlands, 1985;
14. (d) Dong RY. Nuclear Magnetic Resonance Spectroscopy of Liquid Crystals, (Partially Ordered Systems), Spinger Verlag: Berlin, 1994.
15. Lacour J, Ginglinger C, Favanger F, Torche-Haldiman S. Chem. Commun. 1997; 23: 2285.
16. Szalontai G. Magn. Res. Chem. 2000; 38: 872.
17. Merlet D, Loewenstein A, Smadja W, Courtieu J, Lesot P. J. Am. Chem. Soc. 1998; 120: 963.
18. Szalontai G. Eur. J. Org. Chem. 2001; 18: 3511.
19. Browne WR, O'Connor CM, Killeen JS, Guckian AL, Burke M, James P, Burke M, Vos JG. Inorg. Chem. 2002; 41: 4245.
20. Braddock JN, Meyer TJ. J. Am. Chem. Soc. 1973; 95: 3158.
21. Watts RJ, Crosby GA. J. Am. Chem. Soc. 1971; 93: 3184.
22. Rutherford TJ, Pellegrini PA, Wright JA, Junk PC, Keene FR. Eur. J. Inorg. Chem. 1998; 11: 1677.