Palladium-catalyzed carboxylation of allyl stannanes and carboxylative coupling of allyl stannanes and allyl halides

Studies in Surface Science and Catalysis

Volumn 114, Issue , 1998, Pages 165-170

  Shi, Min ^a   Franks, Russell ^a   Nicholas, Kenneth M ^a  

^a UNIVERSITY OF OKLAHOMA   (United States)

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EID: 33750392245     PISSN: 01672991     EISSN: None     Source Type: Book Series    
DOI: 10.1016/s0167-2991(98)80738-6     Document Type: Article

References (25)

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5. 3 indicate an exothermic process for virtually all metals since a strong M-O bond is formed at the expense of a weaker M-C bond and a C-C σ-bond is formed at the expense of a comparably strong C-O π-bond.
6. 2 (33 atm), sealed, and heated at 70°C for 24 h with stirring. After cooling and release of the pressure, the solvent was removed under reduced pressure and the residue was passed through a short column of flash silica (1:1 ethyl acetate/hexane) to afford a spectroscopically pure mixture of the tin carboxylates.
7. A preliminary report of this study has appeared recently: Shi, M.; Nicholas, K.M. J. Am. Chem. Soc. 1997, 119, 5057.
8. a) ref. 1a, p. 54-60;
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20. 2; ref. 6 c-f.
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