Progress of organometallic complex catalysts based on β-diketone and its derivatives for olefin coordination polymerization

Petrochemical Technology

Volumn 35, Issue 9, 2006, Pages 896-907

  Chen, Shangtao ^a   Hu, Youliang ^a  

^a INSTITUTE OF CHEMISTRY   (China)

Author keywords

Diketone; Catalyst; Coordination polymerization; Non metallocene; Olefin polymerization; Polyolefin

Indexed keywords

EID: 33750339868     PISSN: 10008144     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (44)

1. Bourget-Merle L, Lappert M F, Severn J R. The Chemistry of β-Diketiminatometal Complexes. Chem Rev, 2002, 102(9):3031-3065.
2. Janiak C, Scharmann T G, Lange K C H. Zirconium β-Diketonate/ Methylaluminoxane Systems as Singlesite Catalysts for the Preparation of High-Molecular-Weight Polyethylene. Macromol Rapid Commun, 1994, 15(18):655-658.
3. Combs P, Jakob H, Nuber B, et al. Solution Structures and Isomer Distributions of Bis (β-Diketonato) Complexes of Titanium(IV) and Cobalt(III). Inorg Chem, 1994, 33(15):3396-3400.
4. 2B], (bzac = 1-Phenylbutane-1,3-Dionate). J Inorg Biochem, 2003, 95(2-3): 97-104.
5. Oouchi K, Mitani M, Hayakawa M, et al. Ethylene Oligomerization Catalyzed with Dichlorobis-(β-Diketonato) Zirconium/Organoaluminium Chloride Systems. Macromol, Chem Phys, 1996, 197(4): 1545-1551.
6. Wang Jun, Liu Zhongyang, Wang Dong, et al. Syndiospecific Polymerization of Styrene Based on Dichlorobis(1,3-Diketonato)Titanium/Methylaluminoxane Catalysts System: Effects of Substituents on Catalyst Activity. Polym Int, 2000, 49 (12):1665-1669.
7. 2-Supported Dichlorobis (4, 4, 4-Trifluoro-1-Phenyl-1, 3-Blutanedionato) Titanium Catalysts with Different Titanium Contents and Their Application to Propene Polymerization. Macromol Chem Phys, 1998, 199(8):1495-1499.
8. Mi Xia, Xu Deming, Yan Weidong, et al. Preparation of Polynorbornene with β-Diketonate Titanium/MAO Catalysts. Polym Bull, 2001, 47(5):521-527.
9. 2-Supported Dichloro Bis (β-Diketonato) Titanium Catalysts Activated by Ordinary Alkylaluminums. J Polym Sci, Part A: Polym Chem, 1998, 36 (1):129-135.
10. Shmulinson M, Galan-Fereres M, Lisovskii A, et al. Formation of Elastomeric Polypropylene Promoted by Racemic Acetylacetonate Group 4 Complexes. Organometallics, 2000, 19(7):1208-1210.
11. Chen Yaofeng, Wu Gang, Bazan G C. Remote Activation of Nickel Catalysts for Ethylene Oligomerization. Angew Chem Int Ed, 2005, 44(7):1108-1112.
12. 2Cl System. Macromolecules, 1979, 12(5):814-819.
13. Doi Y, Suzuki S, Soga K. "Living" Coordination Polymerization of Propene with a Highly Active Vanadium-Based Catalyst. Macromolecules, 1986, 19(12):2896-2900.
14. Wang Chunming, Friedrich S, Younkin T R, et al. Neutral Nickel (II)-Based Catalysts for Ethylene Polymerization. Organometallics, 1998, 17(15):3149-3151.
15. Younkin T R, Connor E T, Henderson J I, et al. Neutral Single-Component Nickel (II) Polyolefin Catalysts that Tolerate Heteroatoms. Science, 2000, 287(5 452):460-462.
16. Mitsui Chemical Inc. Olefin Polymerization Catalysts, Transition Metal Compounds, Processes for Olefin Polymerization, and Alpha-Olefin/Conjugated Diene Copolymers. Eur Pat Appl, EP 0874005. 1998.
17. Mitani M, Saito J, Ishii S I, et al. FI Catalysts: New Olefin Polymerization Catalysts for the Creation of Value-Added Polymers TH. Chem Record, 2004, 4(3):137-158.
18. Tohi Y, Makio H, Matsui S, et al. Polyethylenes with Uni-, Bi-, and Trimodal Molecular Weight Distributions Produced with a Single Bis (Phenoxy-Imine) Zirconium Complex. Macromolecules, 2003, 36(3):523-525.
19. 1P H NMR Spectroscopoy. Macromol Symp, 2004, 213:221-233.
20. Cherian A E, Lobkovsky E B, Coates G W. Synthesis of Allyl-Terininated Syndiotactic Polypropylene: Macromonomers for the Synthesis of Branched Polyolefins. Macromolecules, 2005, 38 (15): 6259-6268.
21. Makio H, Kashiwa N, Fujita T. FI Catalysts: A New Family of High Performance Catalysts for Olefin Polymerization. Adv Synth Catal, 2002, 344(5):477-493.
22. Matsui S, Mitani M, Saito J, et al. A Family of Zirconium Complexes Having Two Phenoxy-Imine Chelate Ligands for Olefin Polymerization. J Am Chem Soc, 2001, 123(28):6847-6856.
23. Ishii S, Mitani M, Saito J, et al. Zirconium Complexes Having Phenoxy/Cycloalkylimine Chelate Ligands for the Polymerization of Ethylene for Vinyl-Terminated Low Molecular Weight Polyethylenes. Chem Lett, 2002, 740-741.
24. Tian Jun, Hustad P D, Coates G W. A New Catalyst for Highly Syndiospecific Living Olefin Polymerization: Homopolymers and Block Copolymers from Ethylene and Propylene. J Am Chem Soc, 2001, 123(21):5134-5139.
25. Mitani M, Furuyama R, Mohri J, et al. Syndiospecific Living Propylene Polymerization Catalyzed by Titanium Complexes Having Fluorine-Containing Phenoxy-Imine Chelate Ligands. J Am Chem Soc, 2003, 125(14):4293-4305.
26. Mitani M, Mohri J, Yoshida Yasunori, et al. Living Polymerization of Ethylene Catalyzed by Titanium Complexes Having Fluorine-Containing Phenoxy-Imine Chelate Ligands. J Am Chem Soc, 2002, 124(13):3327-3336.
27. Li Xiaofang, Dai Ke, Ye Weiping, et al. New Titanium Complexes with Two Beta-Enaminoketonato Chelate Ligands: Syntheses, Structures, and Living Olefin Polymerization Activities. Organometallics, 2004, 23(6):1223-1330.
28. Zhu Yazheng, Liu Jingyu, Li Yuesheng, et al. Synthesis, Structure and Norbomene Polymerization Behavior of Nickel Complexes Bearing Two β-Ketoiminato Chelate Ligands. J Organomet Chem, 2004, 689(7):1295-1303.
29. Chen Shangtao, Zhang Xiaofan, Ma Hongwei, et al. A Series of New Zirconium Complexes Bearing Bis (Phenoxyketimine) Ligands: Synthesis, Characterization and Ethylene Polymerization. J Organomet Chem, 2005, 690(18):4184-4191.
30. Gao Haiyang, Guo Wenjuan, Bao Feng, et al. Synthesis, Molecular Structure, and Solution-Dependent Behavior of Nickel Complexes Chelating Anilido-Imine Donors and Their Catalytic Activity Toward Olefin Polymerization. Organometallics, 2004, 23 (26): 6273-6280.
31. 1-Symmetric Beta-Diketimines. Organometallics, 2004, 23(10):2238-2250.
32. Shaviv E, Botoshansky M, Eisen M S. β-Diketiminate Complexes of Group 4: Active Complexes for the Isomerization of α-Olefins and the Polymerization of Propylene Towards Elastomeric Polypropylene. J Organomet Chem, 2003, 683:165-180.
33. Scollard J D, McConville D H, Payne N C, et al. Polymerization of α-Olefins by Chelating Diamide Complexes of Titanium. Macromolecules, 1996, 29(15):5241-5243.
34. Jeon You Moon, Heo Jungseok, Lee Won Mok, et al. Titanium and Zirconium Complexes with the New Ancillary Diamido Ligand N, N′-Bis(Trimethylsilyl) Amidobenzylamido(2-): Syntheses, Structures and α-Olefin Polymerization Activities. Organometallics, 1999, 18(20):4107-4113.
35. Mecking S, Johnson L K, Wang Lin, et al. Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate. J Am Chem Soc, 1998, 120 (5):888-899.
36. Johnson L K, Mecking S, Brookhart M. Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium (II) Catalysts. J Am Chem Soc, 1996, 118(1):267-268.
37. Brooke S L, Brookhart M. Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene. J Am Chem Soc, 1998, 120 (16):4049-4050.
38. Britovsek G P J, Gibson V C, Kimberley B S. Novel Olefin Polymerization Catalysts Based on Iron and Cobalt. Chem Commun, 1998, (7):849-850.
39. Stibrany R T, Schulz D N, Kacker S, et al. Polymerization and Copolymerization of Olefins and Acrylates by Bis (Benzimidazole) Copper Catalysts. Macromolecules, 2003, 36(23):8584-8586.
40. Mehrkhodavandi P, Bonitatebus P J, Schrock R R. A Comparison of Cationic Zirconium Methyl and Isobutyl Initiators that Contain an Arylated Diamido-Pyridine Ligand for Polymerization of 1-Hexene. Elucidation of a Dramatic "Initiator Effect". J Am Chem Soc, 2000, 122(32):7841-7842.
41. Tshuva E Y, Goldberg I, Kol M. Zirconium Complexes of Amine-Bis(Phenolate) Ligands as Catalysts for 1-Hexene Polymerization: Peripheral Structural Parameters Strongly Affect Reactivity. Organometallics, 2001, 20(14):3017-3028.
42. Groysman S, Goldberg I, Kol M. From THF to Furan: Activity Tuning and Mechanistic Insight via Sidearm Donor Replacement in Group IV Amine Bis (Phenolate) Polymerization Catalysts. Organometallics, 2003, 22(15):3013-3015.