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Volumn 10, Issue 5, 2006, Pages 949-958

Asymmetric reductions involving borohydrides: A practical asymmetric reduction of ketones mediated by (L)-TarB-NO2: A chiral Lewis acid

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EID: 33750101246     PISSN: 10836160     EISSN: None     Source Type: Journal    
DOI: 10.1021/op060079d     Document Type: Review
Times cited : (31)

References (67)
  • 10
    • 0034697497 scopus 로고    scopus 로고
    • Blaser, H. U.; Schmidt, E.; Eds.; Wiley-VCH: Weinheim
    • Blaser, H. U.; Schmidt, E.; Eds. Asymmetric Catalysis on Industrial Scale; Wiley-VCH: Weinheim, 2004.
    • (2004) Asymmetric Catalysis on Industrial Scale
  • 13
    • 33750121778 scopus 로고
    • Morrison, J. D., Ed. Academic Press: New York, Chapters 2 and 3
    • Morrison, J. D., Ed. Asymmetric Synthesis; Academic Press: New York, 1983; Vol. 2, Chapters 2 and 3.
    • (1983) Asymmetric Synthesis , vol.2
  • 53
    • 33750105812 scopus 로고    scopus 로고
    • note
    • 49
  • 54
    • 33750139321 scopus 로고    scopus 로고
    • note
    • 2O: a broad peak at 32 ppm and another smaller peak at 10 ppm. 3-Nitrophenylboronic acid gives a broad peak at 28 ppm.
  • 56
    • 33750107465 scopus 로고    scopus 로고
    • note
    • 4.
  • 65
    • 33750134847 scopus 로고    scopus 로고
    • note
    • The importance of the carboxylic acid functionality was verified using the methyl ester of tartaric acid. Reductions from this conjugate showed full conversion of ketone to alcohol, but only 7% ee in the reduction of acetophenone.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.