Selectivity of thiophene/toluene competitive adsorptions onto NaY and NaX zeolites

Industrial and Engineering Chemistry Research

Volumn 45, Issue 20, 2006, Pages 6758-6764

  Laborde Boutet, C ^a   Joly, G ^a   Nicolaos, A ^b   Thomas, M ^b   Magnoux, P ^a  

^a UNIVERSITÉ DE POITIERS   (France)

^b IFP ENERGIES NOUVELLES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION SELECTIVITY; COMPETITIVE ADSORPTIONS; LANGMUIR MODEL;

ADSORBENTS; ADSORPTION; ADSORPTION ISOTHERMS; CONCENTRATION (PROCESS); DESULFURIZATION; ZEOLITES;

TOLUENE;

ADSORBENTS; ADSORPTION; ADSORPTION ISOTHERMS; CONCENTRATION (PROCESS); DESULFURIZATION; TOLUENE; ZEOLITES;

EID: 33749860445     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie060168e     Document Type: Article

References (36)

1. Directive 98/70/EC. Directive of the European parliament and of the council of 13th October 1998 relating to the quality of petrol and diesel fuels and amending council directive 93/12/EEC. Official J. Eur. Communities 1998, L350, 58.
2. Directive 2003/17/EC. Directive of the European parliament and of the council of 3rd March 2003 amending Directive 97/70/EC relating to the quality of petrol and diesel fuels - Text with EEA relevance. Official J. Eur. Communities 2003, L76, 10.
3. Babich, I. V.; Moulijn, J. A. Science and technology of novel processes for deep desulfurization of oil refinery streams: a review. Fuel 2003, 82, 607.
4. Ma, X.; Sun, L.; Song C. A new approach to deep desulfurization of gasoline, diesel fuel and jet fuel by selective adsorption for ultra-clean fuels and for fuel cell applications. Catal. Today 2002, 77, 107.
5. Brunet, S.; Mey, D.; Pérot, G.; Bouchy, C.; Diehl, F. On the hydrodesulfurization of FCC gasoline: a review. Appl. Catal., A: Gen. 2005, 278, 143.
6. Fredrick, C. Sulfur reduction: what are the options? Hydrocarbon Process. 2002, 26.
7. Padley, M. B.; Rochester, C. H.; Mutchings, G. J.; King, F. FTIR spectroscopic study of thiophene, SO2, and CO adsorption on Cu/Al2O3 catalysts. J. Catal. 1994, 148, 438.
8. Loccarino, E. P.; Lieberman, M.; Taylor, W. F. Pre-methanation purification study: removal of low concentration gaseous sulfur compounds (catalyst poison); Final report for the period July 1975-July 1977, Exxon Research and Engineering Company: 1978. http://www.fischer-tropsch.org/DOE/ DOE_reports/0059t1/0059_t1_toc.htm.
9. Wardencki, W.; Straszewski, R. Dynamic adsorption of thiophenes, thiols and sulfides from n-heptane solutions on molecular sieve 13X. J. Chromatogr. 1974, 91, 715.
10. Wardencki, W.; Straszewski, R. Sorption properties of some modified sieves 13X towards thiophene and benzene. J. Chromatogr. 1985, 329, 128.
11. Weitkamp, J.; Schwark, M.; Ernst, S. Removal of thiophene impurities from benzene by selective adsorption in zeolite ZSM-5. J. Chem. Soc., Chem. Commun. 1991, 1133.
12. Garcia, C. L.; Lercher, J. A. Adsorption and surface reactions of thiophene on ZSM-5 zeolites. J. Phys. Chem. 1992, 96, 2669.
13. King, D. L.; Faz, C.; Flynn, T. Desulfurization of gasoline feedstocks for application in fuel reforming. Soc. Automot. Eng. 2000, 2000-01-0002, 9.
14. Koranyi, T. I.; Jentys, A.; Vinek, H. Adsorption and reaction of thiophene over nickel and cobalt containing zeolites. Stud. Surf. Sci. Catal. 1995, 94, 582.
15. Geobaldo, F.; Palomino, G. T.; Bordiga, S.; Zecchina, A.; Areán, C. A. Spectroscopic study in the UV-Vis, near and mid IR of cationic species formed by interaction of thiophene, dithiophene and terthiophene with the zeolite H-Y. Phys. Chem. Chem. Phys. 1999, 1, 561.
16. Richardeau, D.; Joly, G.; Canaff, C.; Magnoux, P.; Guisnet, M.; Thomas, M.; Nicolaos, A. Adsorption and reaction over HFAU zeolites of thiophene in liquid hydrocarbon solutions. Appl. Catal., A: Gen. 2004, 263, 49.
17. Chica, A.; Strohmaier, K. G.; Iglesia, E. Adsorption, Desorption, and Conversion of Thiophene on H-ZSM5. Langmuir 2004, 20, 10982.
18. Chica, A.; Strohmaier, K. G.; Iglesia, E. Effects of zeolite structure and aluminium content on the thiophene adsorption, desorption, and surface reactions. Appl. Catal. B: Environ. 2005, 60, 223.
19. Hernández-Maldonado, A.; Yang, R. T. Desulfurization of commercial liquid fuels by selective adsorption via π complexation with Cu-(I)-Y zeolite. Ind. Eng. Chem. Res. 2003, 42, 3103.
20. Takahashi, A.; Yang, R. T. Cu(I)-Y-zeolite as a superior adsorbent for diene/olefin separation. Langmuir 2001, 17, 8405.
21. Yang, R. T.; Takahashi, A.; Yang, F. H. New sorbents for desulfurization of liquid fuels by π-complexation. Ind. Eng. Chem. Res. 2001, 40, 6236.
22. Takahashi, A.; Yang, F. H.; Yang, R. T. New sorbents for desulfurization by π-complexation: thiophene/benzene adsorption. Ind. Eng. Chem. Res. 2002, 41, 2487.
23. Hernández-Maldonado, A.; Yang, R. T. Desulfurization of liquid fuels by adsorption via π complexation with Cu(I)-Y and Ag-Y zeolites. Ind. Eng. Chem. Res. 2003, 42, 123.
24. Hernández-Maldonado, A.; Yang, F. H.; Qi, G.; Yang, R. T. Desulfurization of transportation fuels by π-complexation sorbents: Cu-(I)-, Ni(II)-, and Zn(II) zeolites. Appl. Catal., B: Environ. 2005, 56, 111.
25. Velu, S.; Watanabe, S.; Ma, X.; Sun, L.; Song, C. Development of selective adsorbents for removing sulfur from gasoline for fuel cell applications. Pet. Chem. Div. Prepr. 2003, 48, 56.
26. Ma, X.; Velu, S.; Kim, J. H.; Song, C. Deep desulfurization of gasoline by selective adsorption over solid adsorbents and impact of analytical methods on ppm-level sulfur quantification for fuel cell applications. Appl. Catal. B: Environ. 2005, 56, 137.
27. Xue, M.; Chitrakar, R.; Sakane, K.; Hirotsu, T.; Ooi, K.; Yoshimura, Y.; Feng, G.; Sumida, N. Selective adsorption of thiophene and 1-benzothiophene on metal-ion-exchanged zeolites in organic medium. J. Colloid Interface Sci. 2005, 285 (2), 487.
28. Reut, S.; Prakash, A. Evaluation of sorbents for thiophene removal from liquid hydrocarbons. Fuel Process. Technol. 2006, 87, 217.
29. Ettre, L. S. Nomenclature for chromatography. Pure Appl. Chem. 1993, 65, 819.
30. 3 adsorption on conjugated acid-base pair in cation exchanged Y-zeolites. Micropor. Mesopor. Mater. 1999, 30, 327.
31. + ion. II-Quantum chemical study of sorption complexes in faujasites. Zeolites 1982, 2, 114.
32. Barthomeuf, D.; de Mallmann, A. Molecular recognition in the interaction of aromatics with zeolites. Chem., Ecol. Health 1995, 279.
33. Gilles, F.; Blin, J. L.; Toufar, H.; Briend, M.; Su, B. L. Double interactions between ammonia and a series of alkali-exchanged faujasites evidenced by FT-IR and TPD-MS techniques. Colloids Surf. A: Physicoehem. Eng. Aspects 2004, 241, 245.
34. Kitagawa, T.; Tsunekawa, T.; Iwayama, K. Monte Carlo simulations on adsorptions of benzene and xylenes in sodium-Y zeolites. Micropor. Mater. 1996, 7, 227.
35. Uytterhoeven, L.; Dompas, D.; Mortier, W. J. Theoretical investigations on the interaction of benzene with faujasite. J. Chem. Soc., Faraday Trans. 1992, 88, 2753.
36. Ng, F. T. T.; Rahman, A.; Ohasi, T.; Jiang, M. A study of the adsorption of thiophenic sulfur compounds using flow calorimetry. Appl. Catal., B: Environ. 2005, 56, 127.