Intermediacy of radicals in rearrangement and decomposition of metal-alkyl species: Relevance to metal-mediated polymerization of polar vinyl monomers

Organometallics

Volumn 25, Issue 20, 2006, Pages 4722-4724

  Nagel, Megan ^a   Sen, Ayusman ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HOMOLYSIS; METAL-ALKYL SPECIES; NEUTRAL COMPOUNDS; POLAR VINYL MONOMERS;

ADDITION REACTIONS; DECOMPOSITION; MONOMERS; POLYMERIZATION;

FREE RADICALS;

EID: 33749855685     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om060519p     Document Type: Article

References (18)

1. (a) Boffa, L. S.; Novak, B. M. Chem. Rev. 2000, 100, 1479-1493.
2. (b) Ittel, S. D.; Johnson, L. K.; Brookhart, M. Chem. Rev. 2000, 100, 1169-1203.
3. (c) Gibson, V. C: Spitzmesser, S. K. Chem. Rev. 2003, 103, 283-316.
4. (a) Stibrany, R. T.; Schulz, D. N.; Kacker, S.; Patil, A. O.; Baugh, L. S.; Rucker, S. P.; Zushma, S.; Berluche, E.; Sissano, J. A. Macromolecules 2003, 36, 8584-8586.
5. (b) Younkin, T. R.; Connor, E. F.; Henderson, J. I.; Friedrich, S. K.; Grubbs, R. H.; Bansleben, D. A. Science 2000, 287, 460-462.
6. (c) Nagel, M.; Paxton, W. F.; Sen. A.; Zakharov, L.; Rheingold, A. L. Macromolecules 2004. 37, 9305-9307.
7. (a) Mecking, S.; Johnson, L. K.; Wang, L.; Brookhart, M. J. Am. Chem. Soc. 1998. 120, 888-899.
8. (b) Drent, E.; Rudmer, D.; Ginkel, R.; Oort, B.; Pugh, R. Chem. Commun. 2002, 744-745.
9. (a) Philipp, D. M.; Muller, R. P.; Goddard, W. A.; McAdon, M.; Mullins, M. J. Am. Chem. Soc. 2002, 124, 10198-10210.
10. (b) Michalak, A.; Ziegler, T. J. Am. Chem. Soc. 2001, 123, 12266-12278.
11. (a) Albéniz, A. C.; Espinet, P.; López-Fernández, R. Organometallics 2003, 22, 4206-4212.
12. (b) Elia, C.; Elyashiv-Barad, S.; Sen, A. López-Fernández, R.; Albéniz, A. C.; Espinet, P. Organometallics 2002, 21, 4249-4256.
13. (c) Tian, G.; Boone, H. W.; Novak, B. M. Macromolecules 2001, 34, 7656-7663.
14. (d) Also see: Yang. P.; Chan, B. C. K.; Baird, M. C. Organometallics 2004, 23, 2752-2761
15. (a) Mohring, V. M.; Fink, G. Angew. Chem., Int. Ed. Engl. 1985, 24, 1001-1003.
16. (b) Shultz, L. H.: Tempel, D. J.; Brookhart, M. J. Am. Chem. Soc. 2001, 123, 11539-11555.
17. (c) Waltman, A. W.; Younkin, T. R.: Grubbs, R. H. Organometallics 2004, 23, 5121-5123.
18. Michalak, A.; Ziegler, T. J. Am. Chem. Soc. 2001, 123, 12266-12278.