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Volumn 60, Issue 9, 2006, Pages 574-579

Recent optimization highlights of the Georgywood process

Author keywords

1,4 Elimination; 1,5 Diene cyclization; Georgywood; Homomyrcene; Methylaluminum dichloride

Indexed keywords


EID: 33749855504     PISSN: 00094293     EISSN: None     Source Type: Journal    
DOI: 10.2533/chimia.2006.574     Document Type: Article
Times cited : (9)

References (49)
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    • We are aware of other possibilities, which could have resulted in a selective synthesis of Homomyrcene 5a, e.g. the Pd-catalyzed elimination of the Z-isomer of 7 in the presence of 1 equiv. (!) propargylzinc bromide [9c] or 1 equiv. of allylstannane (!) [9a]. For impressive selectivities using dialkylamines (!) instead of an acetates as leaving groups see a) H. Kumobayashi, S. Mitsuhashi, S. Akutagawa, S. Ohtsuka, Chem. Lett. 1986, 157-160;
    • (1986) Chem. Lett. , pp. 157-160
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    • This definition is independent of any electronic preference imposed by the metal center and is based solely on steric considerations. C.P. Casey, G.T. Whiteker, Israel J. Chem. 1990, 30, 299-304.
    • (1990) Israel J. Chem. , vol.30 , pp. 299-304
    • Casey, C.P.1    Whiteker, G.T.2
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    • EP 0659732, priority 22.12.1993 to Givaudan-Roure S.A.
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    • Chem. Abstr. , vol.123 , pp. 112459
    • Christenson, P.A.1
  • 42
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    • Ed.: J.D. Morrison, Acad. Press: New York
    • e) P.A. Bartlett, in 'Asymmetric Synthesis', Ed.: J.D. Morrison, Acad. Press: New York, 1982; Vol. III, pp 341-409;
    • (1982) Asymmetric Synthesis , vol.3 , pp. 341-409
    • Bartlett, P.A.1
  • 49
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    • See http://www.albmolecular.com/features/telkreps/vol01/no02; R. Jason, Albany Molecular Research, Inc. 1997.
    • (1997)
    • Jason, R.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.