Synthesis and olfactory properties of (-)-(1R,2S)-Georgywood

Tetrahedron Asymmetry

Volumn 15, Issue 24, 2004, Pages 3967-3972

  Fráter, Georg ^a   Müller, Urs ^a   Schröder, Fridtjof ^a  

^a GIVAUDAN SCHWEIZ AG   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE DERIVATIVE; ALKADIENE; GEORGYWOOD; KETONE DERIVATIVE; METHACRYLIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CIRCULAR DICHROISM; CONFORMATION; DIELS ALDER REACTION; ENANTIOMER; OXIDATION; PHYSICAL CHEMISTRY; PRIORITY JOURNAL; RACEMIC MIXTURE; SMELLING; SYNTHESIS;

EID: 9944265713     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetasy.2004.11.003     Document Type: Article

References (17)

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12. The resolved enantiomers (-)-7 or (+)-7 have the tendency to crystallize as racemates. Crystallization would have given a certain enrichment in the mother liquor, but the crude enantiomers (-)-7 or (+)-7 were further converted as such, because they had sufficient enantiopurity, as deduced from the ee-values of the final Georgywood enantiomers (-)-1 or (+)-1
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17. CCDC 251423 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/ data_request/cif, by emailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033