Time-resolved infrared absorption study of cyclopentadienyl manganese tricarbonyl derivatives: Chelation of pendant sulfides in acetonitrile

Journal of Physical Chemistry A

Volumn 110, Issue 37, 2006, Pages 10669-10673

  To, Tung T ^a   Heilweil, Edwin J ^a   Burkey, Theodore J ^b  

^a NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^b University of Memphis   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPENTADIENYL MANGANESE TRICARBONYL; PENDANT SULFIDES; SOLVENT INTERACTION; VIBRATIONAL COOLING;

ABSORPTION SPECTROSCOPY; ACETONITRILE; CHELATION; HYDROGEN BONDS; INFRARED RADIATION; IRRADIATION; LIGHT ABSORPTION; SOLUTIONS; SULFUR COMPOUNDS; ULTRAVIOLET DEVICES;

MANGANESE COMPOUNDS;

EID: 33749603371     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp057360z     Document Type: Article

References (26)

1. To, T. T.; Barnes, C. E.; Burkey, T. J. Organometallics 2004, 23, 2708.
2. (a) To, T. T. "New photochromic organometallics based on linkage isomerization of cyclopentadienyl manganese carbonyl derivatives." Abstracts of pages of the American Chemical Society 229: U1022-U1022 397-INOR Part 1 Mar 13, 2005. A full paper is in preparation,
3. (b) Yeston, J. S.; To, T. T.; Burkey, T. J.; Heilweil, E. J. J. Phys. Chem. B 2004, 108, 4582.
4. (c) Jiao, T.; Pang, Z.; Burkey, T. J.; Johnston, R. F.; Heimer, T. A.; Kleiman, V. D.; Heilweil, E. J. J. Am. Chem. Soc. 1999, 121, 4618.
5. For leading references on photochromic materials in photonic devices, see Irie, M. Ed. Chem. Rev. 2000, 100, 1683.
6. For a recent review on the use of photochromic materials for optical switches, see Raymo, F. A.; Tomasulo, M. Chem.-Eur. J. 2006, 12, 3186.
7. (a) Perutz, R. N. Chem. Soc. Rev. 1993, 361.
8. (b) Lee, M,; Harris, C. B. J. Am. Chem. Soc. 1989, 111, 8963.
9. (c) Jiao; T. J.; Leu, G.-L.; Farrell, G. J.; Burkey, T. J. J. Am. Chem. Soc. 2001, 123,4960.
10. (d) Xie, X.; Simon, J. D. J. Am. Chem. Soc. 1990, 112, 1130.
11. Apparently, alkanes can bind to metal centers that have vibrational energy in excess of the metal-alkane bond if the energy is isolated in high-frequency oscillators: see ref 5b. Metal-alkane σ-complexes have been reported to have bond energies on the order of 10-15 kcal/mol. For leading references, see ref 5c.
12. Dougherty, T. P.; Heilweil, E. J. Chem. Phys. Lett. 1994, 227, 19.
13. Yeh, P.-H.; Pang, Z.; Johnston, R. F. J. Orgnomet. Chem. 1996, 509, 123.
14. Certain commercial equipment, instruments, or materials are identified in this paper to adequately specify the experimental procedure. In no case does such identification imply recommendation or endorsement by NIST, nor does it imply that the materials or equipment identified are necessarily the best available for the purpose.
15. max (ε)): 377 nm (770), 490 nm (109).
16. -1): 1940(s), 1876(s), 1693(vw).
17. (a) Keiter, R. L.; Benson, J. W.; Keiter, E. A.; Lin, W.; Jia, Z.; Olson, D. M.; Brandt, D. E.; Wheeler, J. L. Organometallics 1998, 17, 4291.
18. (b) Lewinski, J.; Bury, W.; Justyniak, I. Eur. J. Inorg. Chem. 2005. 4490.
19. Local heating followed by excitation can temporarily "soften" the cage allowing isomerization to occur. See refs 3 and 5 for details.
20. (a) Kovalenko, S. A.; Schanz, R.; Hennig, H.; Ernsting, N. P. J. Chem. Phys. 2001, 115 (7), 3256.
21. (b) Yarwood, J.; Ackroyd, R.; Arnold, K. E.; Doge, G.; Arndt, R. Chem. Phys. Lett. 1981, 77 (2), 239.
22. Giordano, P. J.; Wrighton, M. S. Inorg, Chem. 1977, 16, 160.
23. (a) Gross, R.; Kaim, W. J. Oganomet. Chem. 1987, 333, 347.
24. (b) Rybinskaya, M. I., Korneva, L. M. J. Organomet. Chem. 1982, 231, 25.
25. (a) Sorensen, A. A.; Yang, G. K. J. Am. Chem. Soc. 1991, 113, 7061.
26. (b) Teixeira, G.; Aviles, T.; Dias, A. R.; Pina, F. J. Organomet. Chem. 1988, 353, 83.