Ultrafast ring closure energetics and dynamics of cyclopentadienyl manganese tricarbonyl derivatives

Journal of the American Chemical Society

Volumn 121, Issue 19, 1999, Pages 4618-4624

  Jiao, Tianjie ^a   Pang, Zhen ^e   Burkey, Theodore J ^a   Johnston, Randy F ^b   Heimer, Todd A ^c   Kleiman, Valeria D ^c,d   Heilweil, Edwin J ^c  

^a University of Memphis   (United States)

^b UNION UNIVERSITY   (United States)

^c NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^d NAVAL RESEARCH LABORATORY   (United States)

^e NONE

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPENTADIENE DERIVATIVE; FUNCTIONAL GROUP;

ARTICLE; CALORIMETRY; CHEMICAL REACTION KINETICS; CONFORMATION; CYCLIZATION; DYNAMICS; ENERGY TRANSFER; ENTHALPY; INFRARED SPECTROSCOPY; PHOTOLYSIS; SOLVATION;

EID: 0033583720     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9832764     Document Type: Article

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21. We thank a reviewer for suggesting this explanation.
22. -1.
23. -1. Although the PAC and IR experiments were done in different solvents this apparently is only responsible for a minor change in the rate. Differences in rates obtained by PAC and IR experiments are attributed to the fact that IR experiments were not air free.
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