Electron-stimulated production of molecular oxygen in amorphous solid water on Pt(111): Precursor transport through the hydrogen bonding network

Journal of Chemical Physics

Volumn 125, Issue 12, 2006, Pages

  Petrik, Nikolay G ^a   Kavetsky, Alexander G ^a,b   Kimmel, Greg A ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^b KHLOPIN RADIUM INSTITUTE   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN BONDING NETWORK; PRECURSOR TRANSPORT; SOLID WATER; STIMULATED PRODUCTION;

ADSORPTION; ELECTRONS; HYDROGEN BONDS; MATHEMATICAL MODELS; OXYGEN; PLATINUM;

CRYSTALLINE MATERIALS;

EID: 33749267955     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.2345367     Document Type: Article

References (57)

1. D. T. Hall, P. D. Feldman, M. A. McGrath, and D. F. Strobel, Astrophys. J. 499, 475 (1998).
2. D. T. Hall, D. F. Strobel, P. D. Feldman, M. A. McGrath, and H. A. Weaver, Nature (London) 373, 677 (1995).
3. J. R. Spencer and W. M. Calvin, Astron. J. 124, 3400 (2002).
4. W. M. Calvin, R. N. Clark, R. H. Brown, and J. R. Spencer, J. Geophys. Res., [Planets] 100, 19041 (1995).
5. J. R. Spencer, W. M. Calvin, and M. J. Person, J. Geophys. Res., [Planets] 100, 19049 (1995).
6. Radiation Chemistry: Principles and Applications, edited by Farhataziz and M. A. J. Rodgers (VCH, New York, 1987).
7. M. T. Sieger, W. C. Simpson, and T. M. Orlando, Nature (London) 394, 554 (1998).
8. T. M. Orlando and M. T. Sieger, Surf. Sci. 528, 1 (2003).
9. N. G. Petrik, A. G. Kavetsky, and G. A. Kimmel, J. Phys. Chem. B 110, 2723 (2006).
10. G. A. Kimmel and T. M. Orlando, Phys. Rev. Lett. 75, 2606 (1995).
11. M. Domae, Y. Katsumura, K. Ishigure, and V. M. Byakov, Radiat. Phys. Chem. 48, 487 (1996).
12. S. M. Pimblott and J. A. LaVerne, J. Phys. Chem. A 101, 5828 (1997).
13. N. G. Petrik, A. B. Alexandrov, and A. I. Vall, J. Phys. Chem. B 105, 5935 (2001).
14. J. A. LaVerne and L. Tandon, J. Phys. Chem. B 107, 13623 (2003).
15. X. Y. Zhu, J. M. White, M. Wolf, E. Hasselbrink, and G. Ertl, J. Phys. Chem. 95, 8393 (1991).
16. M. Wolf, S. Nettesheim, J. M. White, E. Hasselbrink, and G. Ertl, J. Chem. Phys. 94, 4609 (1991).
17. G. Gilarowski, W. Erley, and H. Ibach, Surf. Sci. 351, 156 (1996).
18. N. G. Petrik and G. A. Kimmel, Phys. Rev. Lett. 90, 166102 (2003).
19. N. G. Petrik and G. A. Kimmel, J. Chem. Phys. 121, 3736 (2004).
20. J. T. Yates, Experimental Innovations in Surface Science: A Guide to Practical Laboratory Methods and Instruments (Springer-Verlag, New York, 1998).
21. Z. Dohnalek, G. A. Kimmel, P. Ayotte, R. S. Smith, and B. D. Kay, J. Chem. Phys. 118, 364 (2003).
22. G. A. Kimmel, K. P. Stevenson, Z. Dohnalek, R. S. Smith, and B. D. Kay, J. Chem. Phys. 114, 5284 (2001).
23. K. P. Stevenson, G. A. Kimmel, Z. Dohnalek, R. S. Smith, and B. D. Kay, Science 283, 1505 (1999).
24. N. G. Petrik and G. A. Kimmel, J. Chem. Phys. 123, 054702 (2005).
25. 2 ESD yields reach the maximum depends on the electron fluence due to the kinetics associated with the production of these species and electron-stimulated sputtering.
26. 2 is observed to desorb, after first diffusing through the film.
27. For these experiments it is preferable to consider small fluences since for larger fluences, electron-stimulated sputtering and mixing of the initially layered films are significant.
28. R. S. Smith, C. Huang, E. K. L. Wong, and B. K. Kay, Phys. Rev. Lett. 79, 909 (1997).
29. P. Ayotte, R. S. Smith, K. P. Stevenson, Z. Dohnálek, G. A. Kimmel, and B. D. Kay, J. Geophys. Res., [Planets] 106, 33387 (2001).
30. G. A. Kimmel, N. G. Petrik, Z. Dohnalek, and B. D. Kay, Phys. Rev. Lett. 95, 166102 (2005).
31. L. Kerwin and M. Cottin, Can. J. Phys. 36, 184 (1958).
32. V. F. Petrenko and R. W. Whitworth, Physics of Ice (Oxford University Press, Oxford, 1999).
33. C. Clay, S. Haq, and A. Hodgson, Phys. Rev. Lett. 92, 046102 (2004).
34. We will use the term "electron-stimulated migration" to refer to the movement of the precursors within the films. The mechanism for the migration, e.g., diffusive motion, migration in an electric field, etc., is not currently known.
35. P. A. Gerakines, W. A. Schutte, and P. Ehrenfreund, Astron. Astrophys. 312, 289 (1996).
36. P. Vassilev, M. J. Louwerse, and E. J. Baerends, J. Phys. Chem. B 109, 23605 (2005).
37. M. E. Tuckerman, D. Marx, and M. Parrinello, Nature (London) 417, 925 (2002).
38. R. E. Johnson, P. D. Cooper, T. I. Quickenden, G. A. Grieves, and T. M. Orlando, J. Chem. Phys. 123, 184715 (2005).
39. 2 ESD data treating both trapped and mobile OH's and found that those models can also account for the observations.
40. I. A. Taub and K. Eiben, J. Chem. Phys. 49, 2499 (1968).
41. H. C. Box, E. E. Budzinski, K. T. Lilga, and H. G. Freund, J. Chem. Phys. 53, 1059 (1970).
42. R. H. Prince, G. N. Sears, and F. J. Morgan, J. Chem. Phys. 64, 3978 (1976).
43. X. Pan, A. D. Bass, J. P. Jay-Gerin, and L. Sanche, Icarus 172, 521 (2004).
44. W. J. Zheng, D. Jewitt, and R. I. Kaiser, Astrophys. J. 639, 534 (2006).
45. B. C. Garrett, D. A. Dixon, D. M. Camaioni et al., Chem. Rev. (Washington, D.C.) 105, 355 (2005).
46. R. E. Johnson, T. I. Quickenden, P. D. Cooper, A. J. McKinley, and C. G. Freeman, Astrobiology 3, 823 (2003).
47. L. Khriachtchev, M. Pettersson, S. Jolkkonen, S. Pehkonen, and M. Rasanen, J. Chem. Phys. 112, 2187 (2000).
48. S. Pehkonen, M. Pettersson, J. Lundell, L. Khriachtchev, and M. Rasanen, J. Phys. Chem. A 102, 7643 (1998).
49. C. T. Reimann, J. W. Boring, R. E. Johnson, J. W. Garrett, K. R. Farmer, W. L. Brown, K. J. Marcantonio, and W. M. Augustyniak, Surf. Sci. 147, 227 (1984).
50. W. L. Brown, L. J. Lanzerotti, and R. E. Johnson, Science 218, 525 (1982).
51. W. L. Brown, L. J. Lanzerotti, J. M. Poate, and W. M. Augustyniak, Phys. Rev. Lett. 40, 1027 (1978).
52. W. L. Brown, W. M. Augustyniak, L. J. Lanzerotti, R. E. Johnson, and R. Evatt, Phys. Rev. Lett. 45, 1632 (1980).
53. M. S. Westley, R. A. Baragiola, R. E. Johnson, and G. A. Baratta, Nature (London) 373, 405 (1995).
54. M. S. Westley, R. A. Baragiola, R. E. Johnson, and G. A. Baratta, Planet. Space Sci. 43, 1311 (1995).
55. G. A. Grieves and T. M. Orlando, Surf. Sci. 593, 180 (2005).
56. M. S. Westley, G. A. Baratta, and R. A. Baragiola, J. Chem. Phys. 108, 3321 (1998).
57. G. A. Kimmel, Z. Dohnalek, K. P. Stevenson, R. S. Smith, and B. D. Kay, J. Chem. Phys. 114, 5295 (2001).