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In this paper, cis and trans are defined as shown in Figure 1 in order to describe the molecular conformations consistently, because E and Z can be interconverted simply by a change of the N-substituents.
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33749005536
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The concentration was 5 mg/mL for each experiment, and we confirmed that the concentration did not affect the ratio of the two conformers.
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22
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33749027917
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note
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2 increased the ratio of the trans conformer to 59 and 69% (183 K), respectively.
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