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For the use of a 3,5-dimethylpyrazole template providing five-membered chelation, see: (a) Sibi, M. P.; Shay, J. J.; Ji, J. Tetrahedron Lett. 1997, 38, 5955.
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For selected enantioselective transformations in which a 1,4-coordination of the achiral templates is involved, see: (a) Evans, D. A.; Fandrick, K. R. Org. Lett. 2006, 8, 2249.
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