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N-(3-trimethoxysilylpropyl)methacrylamide was prepared by adding methacryloyl chloride (15.6 ml, 161 mmol) in THF (15 ml) for 1 h to a mixture of APS (25 ml, 107 mmol) and triethylamine (22.5 ml, 161 mmol) in THF (50 ml) at 0°C. The mixture was filtered through PTFE membrane filter to remove any salts, and THF was distilled in vacuo to give the desired product as a brown viscous liquid (28.5 g, 98%)
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