Synthesis and transformations of ne spiro-4-piperidines. Acetyl migration in 1-acetyl-1′-benzyl-4-methyl-3, 4-dihydrospiro [(1H)quinoline-2,4′-piperidines] under debenzylation conditions

Letters in Organic Chemistry

Volumn 2, Issue 1, 2005, Pages 29-32

  Kouznetsov, Vladimir V ^a   Basilio, Díaz P ^a   Sanabria, Clara Marcela ^a   Vargas M , Leonor Y ^a   Poveda, Juan Carlos ^a   Stashenko, Elena E ^a   Bahsas, Alí ^b   Amaro Luis, Juan ^b  

^a UNIVERSIDAD INDUSTRIAL DE SANTANDER   (Colombia)

^b UNIVERSIDAD DE LOS ANDES   (Venezuela)

Author keywords

Acetyl migration; Debenzylation; Friedel Craft alkylation; Intramolecular alkene; Spiropiperidines

Indexed keywords

EID: 33748980390     PISSN: 15701786     EISSN: None     Source Type: Journal    
DOI: 10.2174/1570178053400234     Document Type: Review

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33. Basic character of nitrogen atoms in 3,4-dihydro-4-methylspiro[(1H)quinoline-2,4′-piperidine] was calculated in terms of the atomic charges on nitrogen atoms using the Partial Equalization of Orbital Electronegativity (PEOE) method. Piperidine nitrogen atom has major atomic charge (-0.3174).
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35. 2: C, 82.45; H, 8.81; N, 8.74%. Found: C, 82.51; H, 8.96; N, 8.75%.
36. 2O: C, 74.96; H, 8.88; N, 10.28%. Found: C, 74.71; H, 9.06; N, 10.05%.
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