Photochemical behaviors of tetraphenyldiphosphine in the presence of alkynes

Tetrahedron Letters

Volumn 47, Issue 23, 2006, Pages 3919-3922

  Kawaguchi, Shin ichi ^a   Nagata, Shoko ^a   Shirai, Takamune ^a   Tsuchii, Kaname ^a   Nomoto, Akihiro ^a   Ogawa, Akiya ^a  

^a Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE DERIVATIVE; NITROGEN; PHOSPHINE DERIVATIVE; SULFUR; TETRAPHENYLDIPHOSPHINE; UNCLASSIFIED DRUG;

AIR; ARTICLE; ATMOSPHERE; ATOM; BIOTRANSFORMATION; IRRADIATION; ISOMERIZATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PHOTOCHEMISTRY; PHOTODYNAMICS; REACTION ANALYSIS;

EID: 33748588424     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2006.03.165     Document Type: Article

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46. The exclusive Z selectivity observed in the bisphosphination of phenylacetylene may arise from the interaction between the alkyne and diphosphine in the ground or excited state.
47. 2), 3a: For (E)-isomer, δ -30.1 ppm (d, J = 418 Hz), -14.35 ppm (d, J = 426 Hz); For (Z)-isomer, δ -25.20 ppm (d, J = 161 Hz), -6.02 ppm (d, J = 157 Hz). Compound 3b: For (E)-isomer, δ -29.85 ppm (d, J = 300 Hz), -13.55 ppm (d, J = 300 Hz); For (Z)-isomer, δ -24.50 ppm (d, J = 157 Hz), -5.90 ppm (d, J = 161 Hz). Compound 3c: For (E)-isomer, δ -30.3 ppm (d, J = 444 Hz), -14.35 ppm (d, J = 422 Hz); For (Z)-isomer, δ -24.80 ppm (d, J = 161 Hz), -6.75 ppm (d, J = 157 Hz). Compound 3d: δ -24.55 ppm (d, J = 144 Hz), -3.51 ppm (d, J = 144 Hz).
48. 2: 530.1421, found: 530.1418;
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