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The rate constants for the SH2 reaction of 5-hexenyl radical with (PhS)2 and (PhSe)2 are determined to be 7.6 × 104 M-1 s-1 and 1.2 × 107 M-1 s-1, respectively.
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1, respectively. See: (a) Russell, G. A.; Tashtoush, H. J. Am. Chem. Soc. 1983, 105, 1398.
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the case of styrene, for example, the addition rate constants of PhS• and PhSe• are estimated to be 5.1 × 107 M-1 s-1 and 2.2 × 106 M-1 s-1, respectively
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The thioselenation of enynes was accompanied by the formation of acyclic thioselenation products: CH2dCHCH2XCH2C(SePh)dCHSPh, X) C(CO2Et)2: 7% (E/Z ) 79/21); X) O: 11% (E/Z ) 79/21
-
The thioselenation of enynes was accompanied by the formation of acyclic thioselenation products: CH2dCHCH2XCH2C(SePh)dCHSPh, X) C(CO2Et)2: 7% (E/Z ) 79/21); X) O: 11% (E/Z ) 79/21).
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28
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33847085176
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Clive, D. L. J.; Chittattu, G.; Farina, V.; Kiel, W. A.; Menchen, S. M.; Russell, C. G.; Singh, A.; Wong, C. K.; Curtis, N. J. J. Am. Chem. Soc. 1980, 102, 4438.
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32
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85113806278
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was irradiated with a tungsten lamp, PhSSePh was formed in situ (the ratio of (PhS)2/ (PhSe)2/PhSSePh was ca. 1/1/1.4 during the thioselenation of olefins
-
When a mixture of (PhS)2 and (PhSe)2 (1:1) was irradiated with a tungsten lamp, PhSSePh was formed in situ (the ratio of (PhS)2/ (PhSe)2/PhSSePh was ca. 1/1/1.4 during the thioselenation of olefins).
-
When a Mixture of (PhS)2 and (PhSe)2 (1:1)
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