Detection of adulteration of poppy seed oil with sunflower oil based on volatiles and triacylglycerol composition

Journal of Agricultural and Food Chemistry

Volumn 54, Issue 17, 2006, Pages 6385-6389

  Krist, Sabine ^a   Stuebiger, Gerald ^b   Bail, Stefanie ^a   Unterweger, Heidrun ^c  

^a UNIVERSITY OF VIENNA   (Austria)

^b VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

^c AUSTRIAN AGENCY FOR HEALTH AND FOOD SAFETY   (Austria)

Author keywords

pinene; Adulteration; MALDI MS; Poppy seed oil (Oleum papaveris); SPME GC MS; Sunflower oil (Oleum helianthus); Triacylglycerols

Indexed keywords

ALPHA-PINENE; PINENE; SUNFLOWER OIL; TERPENE; TRIACYLGLYCEROL; VEGETABLE OIL;

ARTICLE; CHEMISTRY; FOOD CONTAMINATION; MASS FRAGMENTOGRAPHY; MASS SPECTROMETRY; PAPAVER; PLANT SEED; VOLATILIZATION;

FOOD CONTAMINATION; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; MONOTERPENES; PAPAVER; PLANT OILS; SEEDS; SPECTROMETRY, MASS, MATRIX-ASSISTED LASER DESORPTION-IONIZATION; TRIGLYCERIDES; VOLATILIZATION;

HELIANTHUS; PAPAVER;

EID: 33748570435     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf060500x     Document Type: Article

References (40)

1. Rossell, J. B.; King, B.; Downes, M. J. Detection of Adulteration. J. Am. Oil Chem. Soc. 1983, 60, 333-339.
2. Grob, K.; Biedermann, M.; Bronz, M. Methods for the Recognition of Adulterated Edible Oils. Mitt. Geb. Lebensmittelunters. Hyg. 1994, 85, 340-350.
3. Grob, K.; Biedermann, M.; Bronz, M. Results of a control of Edible Oils: Frauds by Admixtures, Contaminations. Mitt. Geb. Lebensmittelunters. Hyg. 1994, 85, 351-365.
4. Anonymous. Auszüge aus den Jahresberichten der kantonalen Laboratorien. Mitt. Geb. Lebensmittelunters. Hyg. 2003, 93, 267-270.
5. Cserháti, T.; Forgács, E.; Deyl, Z.; Miksik, I. Chromatography in authenticity and traceability tests of vegetable oils and dairy products: A review. Biomed. Chromatogr. 2005, 19, 183-190.
6. Marriott, P. J.; Shellie, R.; Cornwell, C. Gas chromatographic technologies for the analysis of essential oils. J. Chromatogr., A 2001, 936, 1-22.
7. Ulbert, F.; Buchgraber, M. Authenticity of fats and oils. Eur. J. Lipid Sci. Technol. 2000, 102, 687-694.
8. Morin, O. Saflower, Sesame, Camelina, Poppy seed oil. In Oils & Fats Manual; Karleskind, A., Ed.; Lavoisier: Paris, France, 1996; p 155.
9. Firestone, D. Physical and chemical characteristics of oils, fats and waxes; AOCS Press: Champaign, IL, 1999; pp 81, 99-101.
10. Wagner, K.-H.; Isnardy, B.; Elmadfa, I. Effects of seed damage on the oxidative stability of poppy seed oil. Eur. J. Lipid Sci. Technol. 2003, 105, 219-224.
11. Sushma, V.; Santosh, K. A.; Sudhir, S. S.; Siddiqui, M. S.; Sushil, K. Poppy seed composition and uses. J. Med. Aromat. Plant Sci. 1999, 21, 442-446.
12. Maza, M. P.; Millan, F.; Alaiz, M.; Zamora, R.; Hidalgo, F. J.; Vioque, E. Poppy seed: Study of the oil and the residual flour in seeds processed in Spain. Grasas Aceites 1988, 39, 102-104.
13. Küsmenoglu, S.; Akay, Z.; Sener, B. Fatty acid composition in the seed oils of Papaver somniferum from different Provinces. FABAD J. Pharm. Sci. 2002, 27, 13-18.
14. Singh, S. P.; Khanna, K. R.; Dixit, B. S.; Srivastava, S. N. Fatty acid composition of opium poppy (Papaver somniferum) seed oil. Indian J. Agric. Sci. 1990, 60 (5), 358-359.
15. Nergiz, N.; Öyles, S. The proximate composition and some minor constituents of poppy seeds. J. Sci. Food Agric. 1994, 66 (2), 117-120.
16. Klein, H. Erfahrungen aus den Untersuchungen von Nahrungsfetten- und ölen aus dem Handel-Teil 1. Ernaehrung (Vienna, Austria) 1999, 23 (11), 452-460.
17. Seiler, G. J.; Brothers, M. J. Oil concentration and fatty acid composition of Achenes of Helianthus species (Asteraceae) from Canada. Econ. Bot. 1999, 53 (3), 273-280.
18. Merrien, A. Sunflower. In Oils & Fats manual; Karleskind, A., Ed.; Lavoisier: Paris, France, 1996; pp 118 ff.
19. Imai, H.; Watanabe, N.; Haga, I.I. Detection of adulteration of cottonseed oil by gas chromatography. J. Am. Oil Chem. Soc. 1974, 51, 326-330.
20. Arthur, C.; Pawliszyn, J. SPME with thermal desorption using fused silica fibres. Anal. Chem. 1990, 62, 2145-2148.
21. Bianchi, F.; Careri, M.; Mangia, A.; Musci, M. Development and validation of a solid-phase micro-extraction-gas chromatography-mass spectrometry method for the determination of furan in baby-food. J. Chromatogr. A 2006, 1102, 268-272.
22. Krist, S.; Unterweger, H.; Bandion, F.; Buchbauer, G. Volatile compound analysis of SPME headspace and extract samples from roasted Italian chestnuts (Castanea sativa Mill.) using GC-MS. Eur. Food Res. Technol. 2004, 219 (5), 470-473.
23. Krist, S.; Stuebiger, G.; Bail, S.; Unterweger, H. Analysis of volatile compounds and triacylglycerol composition of fatty seed oil gained from flax and false flax. Eur. J. Lipid Sci. Technol. 2006, 108, 48-60.
24. Ulberth, F.; Buchgraber, M. Analytical platforms to assess the authenticity of cocoa butter. Eur. J. Lipid Sci. Technol. 2003, 105, 32-42.
25. Hvattum, E. Analysis of triacylglycerols with non-aqueous reversed-phase liquid chromatography and positive ion electrospray tandem mass spectrometry. Rapid Commun. Mass Spectrom. 2001, 15, 187-190.
26. Jakab, A.; Nagy, K.; Héberger, K.; Vékey, K.; Forgács, E. Differentiation of vegetable oils by mass spectrometry combined with statistical analysis. Rapid Commun. Mass Spectrom. 2002, 16, 2291-2297.
27. Holcapek, M.; Jandera, P.; Zderadicka, P.; Hruba, L. Characterization of triacylglycerol and diacylglycerol composition of plant oils using high-performance liquid chromatography-atmospheric pressure chemical ionization mass spectrometry. J. Chromatogr., A 2003, 1010, 195-215.
28. Ayorinde, F. O. Determination of the molecular distribution of triacylglycerol oils using MALDI-MS. Lipid Technol. 2000, 12, 41-44.
29. Asbury, G. R.; Al-Saad, K.; Siems, W. F.; Hannan, R. M.; Hill, H. H. Analysis of Triacylglycerols and Whole Oils by Matrix-Assisted Laser Desorption/Ionization Time of Flight Mass Spectrometry. J. Am. Soc. Mass Spectrom. 1999, 10, 983-991.
30. Lay, J. O., Jr.; Liyanage, R.; Durham, B.; Brooks, J. Rapid characterization of edible oils by direct matrix-assisted laser desorption/ionization time-of-flight mass spectrometry analysis using triacylglycerols. Rapid Commun. Mass Spectrom. 2006, 20, 952-958.
31. Kris-Etherton, P. M.; Krummel, D.; Russell, M. E. The effect of diet on plasma lipids, lipoproteins, and coronary heart disease. J. Am. Diet. Assoc. 1988, 88, 1373-1400.
32. Harper, C. R.; Jacobson, T. A. The fats of life: The role of Ω-3 fatty acids in the prevention of coronary heart disease. Arch. Intern. Med. 2001, 161, 2185-2192.
33. Krist, S. Untersuchungen zum Aroma von Mohnölen und Samen diverser Mohnsorten. Doctoral Dissertation, University of Vienna, Vienna, Austria, 2002.
34. Doleschall, F.; Recseg, K.; Kemeny, Z.; Kovari, K. Comparison of differently coated SPME fibres applied for monitoring volatile substances in vegetable oils. Eur. J. Lipid Sci. Technol. 2003, 105, 333-228.
35. Zöllner, P.; Stübiger, G.; Schmid, E.; Pittenauer, E.; Allmaier, G. MALDI mass spectrometry of biomolecules and synthetic polymers using alkali hexacyanoferrate(II) complexes and glycerol as matrix. Int. J. Mass Spectrom. Ion Processes 1997, 169/ 170, 99-109.
36. Krist, S.; Stuebiger, G.; Unterweger, H.; Bandion, F.; Buchbauer, G.; Analysis of volatile compounds and triglycerides of seed oils extracted from different poppy varieties. J. Agric. Food Chem. 2005, 53, 8310-8316.
37. Grob, K.; Biedermann, M.; Bronz, M.; Schmid, J. P. Recognition of mild deodorization of edible oils by the loss of volatile components. Eur. Food Res. Technol. 1994, 199 (3), 191-194.
38. Cioni, P. L.; Flamini, G.; Caponi, C.; Ceccarini, L.; Morelli, I. Analysis of volatile fraction, fixed oil and tegumental waxes of the seeds of two different cultivars of Helianthus annus. Food Chem. 2005, 90, 713-717.
39. Beráth, J. Utilization of poppy seed. In Poppy. The Genus Papaver; Bernáth, J., Ed.; Harwood Academic Publishers: Amsterdam, 1998; pp 337-342.
40. Beare, R. J. L.; Gray, L.; Nera, E. A.; Levin, O. L. Nutritional properties of poppy seed oil relative to some other oils. Nutr. Metab. 1979, 23 (4), 335-346.