Synthesis and structural studies of ruthenium(II) 12S4 complexes with 4,4′-bipyridine: The crystal structures of [Ru(12S4)(bpy)Cl](Cl) · H2O and [{Ru(12S4)Cl}2-μ-(bpy)](PF6)2 · 2CH3CN

Inorganic Chemistry Communications

Volumn 9, Issue 10, 2006, Pages 992-995

  Janzen, Daron E ^a   Chen, Weinan ^a   VanDerveer, Donald G ^b   Mehne, Larry F ^c   Grant, Gregory J ^a  

^a UNIVERSITY OF TENNESSEE AT CHATTANOOGA   (United States)

^b CLEMSON UNIVERSITY   (United States)

^c Department of Information and Computer Sciences   (United States)

Author keywords

Binuclear complexes; Bridging ligands; Macrocyclic ligands; Metal organic frameworks; Ruthenium(II) complexes; Thiacrown ligands

Indexed keywords

EID: 33748559099     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2006.06.008     Document Type: Article

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18. 2 = 0.0756 for all data.
19. 2 = 0.1078 for all data.
20. 2 suggests an in/out invertomer as observed here. However, the large degree of disorder for the 12S4 ligand precludes any meaningful discussion of the orientation of the lone pair electrons on the sulfur.
21. 6), which shows a in/out lone pair orientation, but a fluxional 12S4 [15]. However, we would note that the ligand donor set around its Ru(II) center is symmetrical, similar to those complexes with an out/out orientation.