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Volumn 39, Issue 17, 2006, Pages 5669-5674

Photopolymerization without light. Polymerization of acrylates using oxalate esters and hydrogen-peroxide

Author keywords

[No Author keywords available]

Indexed keywords

CHEMILUMINESCENT LIGHTSTICK; OXALATE ESTERS; POLYMERIZABLE ACRYLATE MIXTURES; RADICAL CHAIN POLYMERIZATION;

EID: 33748535077     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma060905i     Document Type: Article
Times cited : (18)

References (44)
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    • Personal communication
    • (b) Personal communication.
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    • note
    • This term could be used only for situations where chemical reaction shares common intermediates with the corresponding photochemical process.
  • 6
    • 0037648162 scopus 로고    scopus 로고
    • Wiley/SITA Series in Surface Coatings Technology: John Wiley and Sons: Chichester, U.K.
    • The word "photopolymer" is generally used to mean a polymer or polymeric mixture that is generally formed by a photopolymerization process. The advantages of photopolymerization are well-known. Photopolymerizations are fast, they can be turned on and off, the systems form so-called "all-solids" polymers, and so forth. For a complete review the reader is directed to: Neckers, D. C.; Jager, W. Chemistry & Technology of UV & EB Formulations for Coatings, Inks, and Paints. Volume VII: Photointiation for Polymerization: UV and EB at the Millenium; Wiley/SITA Series in Surface Coatings Technology: John Wiley and Sons: Chichester, U.K., 1998.
    • (1998) Chemistry & Technology of UV & EB Formulations for Coatings, Inks, and Paints. Volume VII: Photointiation for Polymerization: UV and EB at the Millenium , vol.7
    • Neckers, D.C.1    Jager, W.2
  • 7
    • 33748557862 scopus 로고    scopus 로고
    • note
    • As requested by one of the reviewers, a more detailed discussion on the importance of remote cure follows. Development of the technology which enables polymerization without direct use of light and/or heat is important and represents a needed innovation in the area of coatings. We have had a strong indication from several manufacturers (through our collaborations) regarding the need for such technology. Any object having a complex 3-dimensional shape would be a challenge to cure with light as light requires direct line of sight. Painting of submarine ballast tanks and rear spoilers for cars already attached to the main body can serve as two examples of many applications where remote cure technology can be successfully used. Use of blue LED arrays and/or fiber optics will simply not work because both methodologies might lack sufficient power and the latter can only provide cure for a small spot. While curing of the coating required some carefully designed methodology, the application of the coating to the 3-dimensional object could be accomplished by a simple submersion.
  • 8
    • 33748522094 scopus 로고
    • Burr, J. G., Ed.; Marcel Dekker: New York; Chapter 5
    • Reviews: (a) Mohan, A. G. In Chemi- and Bioluminescence; Burr, J. G., Ed.; Marcel Dekker: New York, 1985; Chapter 5
    • (1985) Chemi- and Bioluminescence
    • Mohan, A.G.1
  • 25
    • 84859273299 scopus 로고
    • Herausgegeben von Georg Brauer; Translated Russian edition: Moscow
    • 2 (estimated): Handbuch der Präparativen Anorganischen Chemie. Herausgegeben von Georg Brauer; Translated Russian edition: Moscow, 1985. Vol. 1, p 179.
    • (1985) Handbuch der Präparativen Anorganischen Chemie , vol.1 , pp. 179
  • 33
    • 0018995262 scopus 로고
    • and references therein
    • (e) Kobayashi, S.; Imai, K. Anal. Chem. 1980, 52, 424-427 and references therein.
    • (1980) Anal. Chem. , vol.52 , pp. 424-427
    • Kobayashi, S.1    Imai, K.2
  • 37
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    • and references therein
    • (d) Schuster, G. B. Acc. Chem. Res. 1979, 12, 366-373 and references therein.
    • (1979) Acc. Chem. Res. , vol.12 , pp. 366-373
    • Schuster, G.B.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.