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85087193527
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note
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1H) (relaxation through the hydrogens attached to the polarized carbons) is meant,
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85087190192
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note
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1P values can be observed if the components are incorporated in different homogeneous interpenetrating networks. However, this is not a likely scenario for the resins used in this study.
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26
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0024941735
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3843106468
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(a) General reference
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(a) General reference,
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40
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0021510443
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To our knowledge "Fluoroprobe" is the most sensitive solvatochromic probe discovered so far; see: Mes, G. F.; de Jong, B.; van Ramesdonk, H. J.; Verhoeven, J. W.; Warman, J. M.; de Haas, M. P.; Horsman van den Dool, L. E. W. J. Am. Chem. Soc. 1984, 106, 6524.
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47
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3843102156
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note
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Apart from cross-linking other factors influence the "rigidity" of a polymer, and a general correlation between the rigidity or microviscosity of a network and the degree of cross-linking can not be made. For example, if 1 is dissolved in MMA a 115 nm shift (from 680 to 565 nm) is observed upon polymerization, despite the fact that PMMA is a linear polymer.
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48
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85087188480
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note
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30
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49
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3843121562
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3843143444
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Lungu, A.; Neckers, D. C. To be published
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Lungu, A.; Neckers, D. C. To be published.
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54
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0026202987
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Harrell, J. W., Jr.; Choudhury, M.; Ahuja, S.; Walker, W. J. Polym. Sci., Polym. Phys. Ed. 1991, 29, 1039.
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Walker, W.4
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55
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3843133597
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note
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Based on the ratio between fully saturated alkyl carbons and acrylate groups.
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57
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3843129178
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note
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From MM2 calculations, using fully stretched chains, side-chain lengths for EGDA, TMPTA, and BUDA of 8.3, 10.0, and 11.7 Å are obtained.
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58
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3843063009
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note
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Typical peak widths for 1 in polymers formed from these resins are 130-140 nm.
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