Chemistry and mineralogy of Titania-Rich slags. Part 1 - Hemo-ilmenite, sulphate, and upgraded Titania slags

Mineral Processing and Extractive Metallurgy Review

Volumn 28, Issue 1, 2007, Pages 1-58

  Guéguin, Michel ^a   Cardarelli, François ^a  

^a Rio Tinto Iron and Titanium   (Canada)

Author keywords

Karrooite; Pseudobrookite; Titanates; Titania slag; Titanium

Indexed keywords

MINERALOGY; PIGMENTS; SMELTING; SULFATE MINERALS; TITANIUM; TITANIUM DIOXIDE;

KARROOITE; PSEUDOBROOKITE; TITANATES; TITANIA SLAG;

SLAGS;

EID: 33748498428     PISSN: 08827508     EISSN: 15477401     Source Type: Journal    
DOI: 10.1080/08827500600564242     Document Type: Article

References (70)

1. Andersson, S., Collen, B., Kuylenstierna, U., and Magneli, A., 1957, "Phase analysis studies of the titanium-oxygen system." Acta. Chemica. Scandinavia, 11, pp. 1641.
2. Anderson, A. T., Cameron, E. N., Haggerty, S. E., Boyd, F. R., Finger, L. W., James, O. B., Keil, K., Prinz, M., Ramdohr, P., and Goresy, A. E., 1970, "Armalcolite: A new mineral from the Apollo 11 samples." Apollo 11 Lunar Conference Proceedings, 1, pp. 55-63.
3. Antonio, M. R., 1989, "Valence of chromium in slags and digestion residues," Analytical Report No. 756, Project #14050-02, BP America Research & Development Structural Analysis, Analytical and Environmental Sciences, Warrensville, OH, August 15.
4. Bergeron, M., 1986, "Minéralogie et géochimie de la suite anorthositique de la région du Lac Allard Québec: Évolution des membres mafiques et origine des gítes d'ilménite," Ph.D. Thesis, Université de Montréal, École Polytechnique.
5. Bergeron, M. and Priest, S. F., 1976, "Magnetic separation of ilmenite," US Patent 3,935,094, January 27.
6. 5, ein neues mineral." Zeitschrift der deutschen Gemmologischen Gesellschaft, 30, pp. 143-145.
7. 9." Neues Jahrbuch fur Mineralogie, Monatshefte, March, pp. 110-118.
8. Bessinger, D., Geldenhuis, J. M. A., Pistorius, P. C., Mulaba, A., and Hearne, G., 2001, "The decrepitation of solidified high titania slags." Journal of Non-Crystalline Solids, 282, pp. 132-142.
9. Borowiec, K., Grau, A. E., Guéguin, M., and Turgeon, J.-F., 1998, "Method to upgrade titania slag and resulting product," US Patent 5,830,420, November 3.
10. 2 containing product including rutile, pseudo-brookite and ilmenite," US Patent 6,531,110, March 11.
11. Briggs, R. A. and Sacco, A., Jr., 1993, "The oxidation of ilmenite and its relationship to the ferrous oxide-ferric oxide-titania phase diagram at 1073 and 1140 K." Metallurgical Transactions A: Physical Metallurgy and Materials Science, 24A(6), pp. 1257-1264.
12. Chase, M. W., Jr., 1998, "NIST-JANAF thermochemical tables, part I and II," Physical and Chemical Reference Data, Monograph No. 9, 4th Ed., New York: Springer.
13. 2 systems from 1400°C to 1600°C in reducing atmospheres." Journal of the American Ceramic Society, 83(6), pp. 1485-1488.
14. Cui, Z., Liu, Q., and Etsell, T. H., 2002, "Magnetic properties of ilmenite, hematite and oil sand minerals after roasting." Minerals Engineering, 15, pp. 1121-1129.
15. Desjardins, J.-F., 1986, "Study of the insoluble in Richards bay slag," QIT Internal Report R-11-86.
16. Desrosiers, R., Ajersch, F., and Grau, A. E., 1980, "Electrical conductivity of industrial slags of high titania content," Proceedings International Symposium on Metallurgical Slags, Part of the 19th Annual Conference of Metallurgists, Halifax, Nova Scotia, Canada, August 24-27.
17. De Villiers, J. P. R., Verryn, S. M. C., and Fernandes, M. A., 2004, "Disintegration in high-grade titania slags: Low temperature oxidation reactions of ferro-pseudobrookite." Mineral Processing and Extractive Metallurgy (Trans. Inst. Mining Metall. C), 113, pp. C66-C74.
18. Donald, H. L., 1976, "The crystal chemistry and structure of oxide minerals as exemplified by the Fe-Ti oxides," In Oxides Minerals. Short Course Notes, Vol. 3. (D. Rumble III, Ed.), Washington, DC: Mineralogical Society of America, pp. Hg1-Hg100.
19. 7." Acta. Crystallographica, B47, pp. 305-314.
20. Eriksson, G., Pelton, A. D., Woermann, E., and Ender, A., 1996, "Measurement and thermodynamic evaluation of phase equilibria in the Fe-Ti-O system." Ber. Bunsenges. Phys. Chem., 100, pp. 1839-1849.
21. Evans, H. T., Dwornik, E. J., and Milton, C., 1986, "Kassite from the diamond jo quarry, magnet cove, hot spring county, Arkansas: The problem of cafetite and kassite." American Mineralogist, 71(7-8), pp. 1045-1048.
22. Forman, S. A., Prince, A. T., and Bright, N. F. H., 1954, "The separation and identification of the titanoferous and siliceous constituents of slag from the Quebec Iron & Titanium Corporation," Research Report No. MD169, Canada Department of Mines and Technical Surveys Mines Branch (CANMET), Ottawa, ON, Canada.
23. Gaines, R. V., Skinner, H. C. W., Foord, E. E., Mason, B., and Rosenzweig, A., 1997, Dana's New Mineralogy: The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, 8th Ed., New York: Wiley-Interscience.
24. Grau, A. E. and Poggi, D., 1978, "Physico-chemical properties of molten titania slags." Canadian Metallurgical Quarterly, 17, pp. 97-102.
25. 2 systems." Canadian Metallurgical Quarterly, 18, pp. 313-321.
26. 3 at 1473 K." Journal of Solid State Chemistry, 17(4), pp. 343-352.
27. 5." Journal of Solid State Chemistry, 37, pp. 284-293.
28. Grey, I. E. and Reid, A. F., 1975, "The structure of pseudorutile and its role in the natural alteration of ilmenite." American Mineralogist, 60, pp. 898-906.
29. Guéguin, M., 1972, "Upgrading Sorelslag. Preliminary Results on Magnetic Separation Tests," QIT Internal Report R-29-1972.
30. Guéguin, M., 2000, "Phases de la scorie près de la cavité dans un bloc," RIT Internal Report R-33-2000.
31. Guéguin, M., 2001, "Scorie de coin de bloc," RIT Internal Report R-15-2001.
32. Guéguin, M., 2004a, "Séparation magnétique de la Sorelslag décrépitée. Composition, diffraction et étude SEM/EDS des fractions granulométriques," RIT Internal Report R-04-2004.
33. Guéguin, M., 2004b, "Beneficiation of titaniferous slags," PCT International Patent Application WO 2004/104239, December 2.
34. Guimond, R., 1964, "Titanium and QIT." Mining in Canada, 11, pp. 11-23.
35. Haggerty, S. E., 1976, "Oxidation of opaque mineral oxides in basalts," In Oxides Mineals. Short Course Notes, Vol. 3. (D. Rumble III, Ed.), Washington, DC: Mineralogical Society of America, pp. Hg1-Hg100.
36. Haggerty, S. E. and Lindsley, D. H., 1969, Carnegie Institution Washington Yearbook, 68, p. 247.
37. Hammond, P., 1952, "Allard lake ilmenite deposits." Economic Geology, 47, pp. 634-649.
38. Hayfield, P. C. S., 1983, "Electrode material, electrode and electrochemical cell," US Patent 4,422,917, December 27.
39. 4 with S = 1/2 pyrochlore lattice." Journal of the Physical Society of Japan, 71(8), pp. 1848-1851.
40. Johnson, R. E., Woermann, E., and Muan, A., 1971, "Equilibrium studies in the system magnesium oxide-iron oxide-titanium oxide." American Journal of Science, 271(3), pp. 278-292.
41. 2." Solid State Chemistry, 28, pp. 21-28.
42. 3+ on the stability of armalcolite," Proceedings of the Sixth Lunar Science Conference, Geochimica and Cosmochimica Acta, Suppl. 6, pp. 911-920.
43. 9 - A new mineral from Priol'khonie (Russia)." Zapiski Vserossiiskogo Mineralogicheskogo Obshchestva, 123(4), pp. 98-103.
44. Koneva, A. A. and Suvorova, L. F., 1995, "Rare chromium and vanadium oxides in metamorphic rocks of Priol'khonye (Lake Baikal area)." Zapiski Vserossiiskogo Mineralogicheskogo Obshchestva, 124(4), pp. 52-61.
45. Krivovichev, S. V., Yakovenchuk, V. N., Burns, P. C., Pakhomovsky, Y. A., and Menshikov, Y. P., 2003, "Cafetite: Crystal structure and revision of chemical formula." American Mineralogist, 88(2-3), pp. 424-429.
46. Kukharenko, A. A., Kondrat'eva, V. V., and Kovyazina, V. M., 1959, "Cafetite, a new hydrated calcium-iron titanate." Zapiski Vserossiiskogo Mineralogicheskogo Obshchestva, 88, pp. 444-453.
47. Lethuillier, P. and Massal, P., 1980, "Propriétés magnétiques de grenats et d'ilménites naturels prélevés dans des gisements variés." Bulletin de Minéralogie, 103(1), pp. 33-39.
48. Mandelbrot, B., 1986, "Comment j'ai decouvert les fractales." La Recherche, November, pp. 420-424.
49. Matsumoto, O., Ishida, IL, and Mitsuya, Y., 1972, "Study of oxide systems by means of the arc imaging furnace. I. Phases found in quenched specimens of the titanium dioxide-calcium oxide system." Denki Kagaku, 40(9), pp. 641-645.
50. 9, a new mineral." American Mineralogist, 63(11-12), pp. 1182-1186.
51. 5)." Zeitschrift für Anorganische und Allgemeine Chemie, 558, pp. 28-34.
52. Pauling, L., 1930, "The crystal structure of pseudobrookite." Z. Kristallogr., 73, pp. 97-112.
53. Peirce, W. M., Waring, R. K., and Fetterolf, D. L., 1949, "Titaniferous material for producing titanium dioxide," US Patent 2,476,453, July 19.
54. Reznichenko, V. A., Karyazin, I. A., Il'yashenko, S. F., and Olyunina, T. V., 1981, "Metallic inclusions in high-titanium slags." Russian Metallurgy, 4(1-2), pp. 16-20.
55. Robinson, P., Panish, P. T., and McEnroe, S. A., 2001, "Minor element chemistry of hemo-ilmenite and magnetite in cumulate rocks from the Sokndal region, South Rogaland, Norway." American Mineralogist, 86, pp. 1469-1476.
56. 3, system by neutron diffraction and Mossbauer effect." Journal of the Physical Society of Japan, 17(10), pp. 1598-1611.
57. Simons, B. and Woermann, E., 1978, "Iron titanium oxides in equilibrium with metallic iron." Contributions to Mineralogy and Petrology, 66(1), pp. 81-89.
58. 9 as a new mineral from a group of complex vanadium and titanium oxides." Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva, 110(5), pp. 607-612.
59. 3 powder mixtures during high-energy ball milling and post-annealing studied by x-ray diffraction." Journal of Alloys and Compounds, 370(1-2), pp. 296-301.
60. 5)." Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy, 22(10), pp. 1750-1751.
61. 2 at 1300°C." American Mineralogist, 49(7-8), pp. 1016-1030.
62. 5," Topical Report No. 7777, Project No. 8573, BP America Research & Development Structural Analysis, Analytical and Environmental Sciences, Warrensville, OH, February 23.
63. Teller, R. G., Antonio, M. E., Grau, A., Gueguin, M., and Kostiner, E., 1990a, "Structural analysis of metastable pseudobrookite ferrous titanium oxides with neutron diffraction and mossbauer spectroscopy." Journal of Solid. State Chemistry, 88, pp. 334-350.
64. Teller, R. G., Antonio, M. E., Grau, A., Gueguin, M., and Kostiner, E., 1990b, "The chemistry of the thermal decomposition of pseudobrookite ferrous titanium oxides." Journal of Solid. State Chemistry, 88, pp. 351-367.
65. Titan, GmbH, 1939, "Process for the manufacture of magnesium-titanium-spinel," Great Britain Patent 498,904, January 13.
66. Toromanoff, I. and Habashi, F., 1984, "The composition of slag from Sorel." Journal of Less Common Metals, 97, pp. 317-329.
67. Veselago, L. I., 1959, "Determination of bivalent and trivalent titanium in slags containg metallic iron and ferrous oxide." Titan I Ego Splavy., 2, pp. 152-157.
68. Wechsler, B. A., 1977, "Cation distribution and high-temperature crystal chemistry of armalcolite." American Mineralogist, 62, pp. 913-920.
69. 3) at high temperature and high pressure." American Mineralogist, 69, pp. 176-185.
70. 3, with different ordering states." American Mineralogist, 84, pp. 130-137.