Influence of chemical composition and sequence length on the transport properties of proton exchange membranes

Journal of Polymer Science, Part B: Polymer Physics

Volumn 44, Issue 16, 2006, Pages 2226-2239

  Roy, Abhishek ^a   Hickner, Michael A ^b   Yu, Xiang ^a   Li, Yanxiang ^a   Glass, Thomas E ^a   McGrath, James E ^a  

^a VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

^b SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

Block copolymer; Direct methanol fuel cell; Nuclear magnetic resonance; Proton exchange membrane; Sulfonated polymer

Indexed keywords

DIRECT METHANOL FUEL CELL (DMFC); ION EXCHANGE CAPACITY (IEC); PROTON EXCHANGE MEMBRANES; SULFONATED POLYMERS;

BLOCK COPOLYMERS; DIFFUSION; KETONES; NUCLEAR MAGNETIC RESONANCE; PROTONS; WATER;

POLYMERIC MEMBRANES;

EID: 33748328123     PISSN: 08876266     EISSN: None     Source Type: Journal    
DOI: 10.1002/polb.20859     Document Type: Article

References (40)

1. Winter, M.; Brodd, R. J. Chem Rev 2004, 104, 4245-4269.
2. Whittingham, M. S.; Savinell, R. F.; Zawodzinski, T. Chem Rev 2004, 104, 4243, 4244.
3. Mauritz, K. A.; Moore, R. B. Chem Rev 2004, 104, 4535-4585.
4. Yeo, R. S. J Electrochem Soc 1983, 130, 533-538.
5. Kim, Y. S.; Dong, L. M.; Hickner, M. A.; Glass, T. E.; Webb, V.; McGrath, J. E. Macromolecules 2003, 36, 6281-6285.
6. Wang, F.; Hickner, M.; Kim, Y. S.; Zawodzinski, T. A.; McGrath, J. E. J Membr Sci 2002, 197, 231-242.
7. Hickner, M. A.; Ghassemi, H.; Kim, Y. S.; Einsla, B. R.; McGrath, J. E. Chem Rev 2004, 104, 4587-4611.
8. Wang, F.; Hickner, M.; Ji, Q.; Harrison, W; Mecham, J.; Zawodzinski, T. A.; McGrath, J. E. Macromol Symp 2001, 175, 387-395.
9. Kim, Y. S.; Sumner, M. J.; Harrison, W. L.; Riffle, J. S.; McGrath, J. E.; Pivovar, B. S. J Electrochem Soc 2004, 151, A2150-A2156.
10. Kim, Y. S.; Hickner, M. A.; Dong, L. M.; Pivovar, B. S.; McGrath, J. E. J Membr Sci 2004, 243, 317-326.
11. Kim, Y. S.; Wang, F.; Hickner, M.; McCartney, S.; Hong, Y. T.; Harrison, W; Zawodzinski, T. A.; McGrath, J. E. J Polym Sci Part B: Polym Phys 2003, 41, 2816-2828.
12. Roy, A.; Einsla, B.; Harrison, W; McGrath, J. E. Am Chem Soc Div Fuel Chem Preprints 2004, 49, 614-615.
13. Li, Y. X.; Mukundan, T.; Harrison, W. L.; Hill, M.; Sankir, M.; Yang, J.; McGrath, J. E.; Am Chem Soc Div Fuel Chem Preprints, 2004, 49, 536, 537.
14. Xiang, Y.; Roy, A.; McGrath, J. E. Preprints Symp - Am Chem Soc Div Fuel Chem 2005, 50, 577-578.
15. Kreuer, K. D. Chem Mater 1996, 8, 610-641.
16. Kreuer, K. D. Solid State Ionics 2000, 136, 149-160.
17. Paddison, S. J. Annu Rev Mater Res 2003, 33, 289-319.
18. Van Grotthuss, C. J. D. Ann Chim 1806, 58, 54.
19. Kreuer, K. D.; Rabenau, A.; Weppner, W. Angew Chem Int Ed Engl 1982, 21, 208, 209.
20. Zawodzinski, T. A.; Neeman, M.; Sillerud, L. O.; Gottesfeld, S. J Phys Chem 1991, 95, 6040-6044.
21. Dong, L. M.; Kim, Y. S.; Wang, F.; Hickner, M.; Glass, T. E.; McGrath, J. E. Abstr Pap Am Chem Soc 2003, 225, U631.
22. Zawodzinski, T. A.; Davey, J.; Valerio, J.; Gottes-feld, S. Abstr Pap Am Chem Soc 1993, 205, PMSE-75.
23. Noshay, A.; McGrath, J. E. Block Copolymers: Overview and Critical Survey; Academic Press: New York, 1977; p 91.
24. Ghassemi, H.; Ndip, G.; McGrath, J. E. Polymer 2004, 45, 5855-5862.
25. Ghassemi, H.; McGrath, J. E. Polymer 2004, 45, 5847-5854.
26. Ghassemi, H.; Zawodzinski, T.; McGrath, J. E. Polymer, in press.
27. Pivovar, B. S.; Wang, Y. X.; Cussler, E. L. J Membr Sci 1999, 154, 155-162.
28. Ren, X. M.; Springer, T. E.; Zawodzinski, T. A.; Gottesfeld, S. J Electrochem Soc 2000, 147, 466-474.
29. Hickner, M. PhD Thesis, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, August 2003.
30. Stejskal, E. O.; Tanner, J. E. J Chem Phys 1965, 42, 288-292.
31. Zawodzinski, T. A.; Springer, T. E.; Neeman, M.; Sillerud, L. O. Isr J Chem 1992, 32, 281-289.
32. Matsukawa, S.; Yasunaga, H.; Zhao, C.; Kuroki, S.; Kurosu, H.; Ando, I. Prog Polym Sci 1999, 24, 995-1044.
33. Matsukawa, S.; Ando, I. Macromolecules 1999, 32, 1865-1871.
34. Zhao, C. H.; Matsukawa, S.; Kurosu, H.; Ando, I. Macromolecules 1998, 31, 3139-3141.
35. Ghi, P. Y.; Hill, D. J. T.; Maillet, D.; Whittaker, A. K. Polymer 1997, 38, 3985-3989.
36. Ghi, P. Y; Hill, D. J. T.; Whittaker, A. K. Biomacromolecules 2002, 3, 554-559.
37. Ghi, P. Y; Hill, D. J. T.; Whittaker, A. K. Biomacromolecules 2002, 3, 991-997.
38. Sankir, M.; Bhanu, V. A.; Harrison, W. L.; Ghassemi, H.; Wiles, K. B.; Glass, T. E.; Brink, A. E.; Brink, M. H.; McGrath, J. E. J Appl Polym Sci, 2006, 100, 4595-4602.
39. Springer, T. E.; Zawodzinski, T. A.; Wilson, M. S.; Gottesfeld, S. J Electrochem Soc 1996, 143, 587-599.
40. Rollet, A. L.; Blachot, J.; Delville, A.; Diat, O.; Guillermo, A.; Porion, P.; Rubatat, L.; Gebel, G. Eur Phys J E 2003, 12, S131-S134.