Photochemically induced decarboxylation in diesel soot extracts

Atmospheric Environment

Volumn 40, Issue 30, 2006, Pages 5837-5844

  Braun, A ^a   Wirick, A ^b   Kubatova A ^c   Mun, B S ^d   Huggins, F E ^a  

^a UNIVERSITY OF KENTUCKY   (United States)

^b STONY BROOK UNIVERSITY   (United States)

^c UNIVERSITY OF NORTH DAKOTA   (United States)

^d LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

Decarboxylation; Diesel soot extract; NEXAFS spectroscopy; Photolysis

Indexed keywords

CARBOXYLATION; EXHAUST SYSTEMS (ENGINE); EXTRACTION; MOLECULAR STRUCTURE; PHOTOLYSIS; RADIOLYSIS;

DECARBOXYLATION; DIESEL SOOT EXTRACTS; NEXAFS SPECTROSCOPY;

SOOT;

ALGINIC ACID; CARBON; CARBONIC ACID; CARBOXYL GROUP; CARBOXYLIC ACID;

DECARBOXYLATION; DIESEL; PHOTOCHEMISTRY; PHOTOLYSIS; SOOT; X-RAY SPECTROSCOPY;

AIR POLLUTION; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; DECARBOXYLATION; EXHAUST GAS; PARTICULATE MATTER; PHOTOCHEMISTRY; PRIORITY JOURNAL; RADIOLYSIS; ROENTGEN SPECTROSCOPY; SOOT; STATISTICAL ANALYSIS; SYNCHROTRON RADIATION;

EID: 33748208687     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2006.05.024     Document Type: Article

References (34)

1. Bamford H.A., Bezabeh D.Z., Schantz M.M., Wise S.A., and Baker J.E. Determination and comparison of nitrated-polycyclic aromatic hydrocarbons measured in air and diesel particulate reference materials. Chemosphere 50 (2003) 575-587
2. Braun A., Shah N., Huggins F.E., Huffman G.P., Wirick S., Jacobsen C., Kelly K.E., and Sarofim A.F. A study of diesel PM with X-ray microspectroscopy. Fuel 83 (2004) 997-1000
3. Braun A. Carbon speciation in airborne particulate matter with C (1 s) NEXAFS spectroscopy. Journal of Environmental Monitoring 7 11 (2005) 1059-1065
4. Braun A., Huggins F.E., Shah N., Chen Y., Wirick S., Mun S.B., Jacobsen C., and Huffman G.P. Advantages of soft X-ray absorption over TEM-EELS for solid carbon studies-a comparative study on diesel soot with EELS and NEXAFS. Carbon 43 1 (2005) 117-124
5. Braun A., Shah N., Huggins F.E., Kelly K.E., Sarofim A., Jacobsen C., Wirick S., Francis H., Ilavsky J., Thomas G.E., and Huffman G.P. X-ray scattering and spectroscopy studies on diesel soot from oxygenated fuel under various engine load conditions. Carbon 43 12 (2005) 2588-2599
6. Chameides W.L., and Bergin M. Climate change-soot takes center stage. Science 297 (2002) 2214-2215
7. Choudhury D.R. Characterization of polycyclic ketones and quinones in diesel emission particulates by gas chromatography/mass spectrometry. Environmental Science & Technology 16 (1982) 102-106
8. Cody G.D., Botto R.E., Ade H., Behal S., Disko M., and Wirick S. Inner-shell spectroscopy and imaging of a subbituminous coal-in-situ analysis of organic and inorganic microstructure using C(1 s)-NEXAFS, Ca(2p)-NEXAFS, Cl(2 s)-NEXAFS. Energy & Fuels 9 3 (1995) 525-533
9. Cody G.D., Botto R.E., Ade H., Behal S., Disko M., and Wirick S. C-NEXAFS microanalysis annd scanning X-ray microscopy of microheterogeneities in a high-volatile bituminous coal. Energy & Fuels 9 1 (1995) 75-83
10. Dhez O., Urquhart S., and Ade H. Calibrated NEXAFS spectra of some common polymers. Journal of Electron Spectroscopy and Related Phenomena 128 1 (2003) 85-96
11. Dockery D.W., Pope C.A., Xu X.P., Spengler J.D., Ware J.H., Fay M.E., Ferris B.G., and Speizer F.E. An association between air pollution and mortality in six US cities. New England Journal of Medicine 329 24 (1993) 1753-1759
12. Fernandes M.B., and Brooks P. Characterization of carbonaceous combustion residues: II. Nonpolar organic compounds. Chemosphere 53 (2003) 447-458
13. Francis J.T., and Hitchcock A.P. Inner-shell spectroscopy of para-benzoquinone, hydroquinone, and phenol-distinguishing quinoid and benzenoid structures. Journal of Physical Chemistry 96 (1992) 6598-6610
14. Glasius M., Lahaniati M., Calogirou A., Di Bella D., Jensen N.R., Hjorth J., Kotzias D., and Larsen B.R. Carboxylic acids in secondary aerosols from oxidation of cyclic monoterpenes by ozone. Environmental Science & Technology 34 (2000) 1001-1010
15. Gregor J.E., Fenton E., Brokenshire G., VanDen Brink P., and O'Sullivan B. Interactions of calcium and aluminium ions with alginate. Water Research 30 6 (1996) 1319-1324
16. Hatakeyama T., Hatakeyama H., and Takamura K. Non-freezing water content of mono- and divalent cation salts of polyelectrolyte-water systems studied by DSC. Thermochimica Acta 253 (1995) 137-148
17. Hunt A., Abraham J.L., Judson B., and Berry C.L. Toxicologic and epidemiologic clues from the characterization of the 1952 London smog fine particulate matter in archival autopsy lung tissues. Environmental Health Perspectives 111 9 (2003) 1209-1214
18. x in the presence of natural sunlight using gas-phase kinetics and gas-particle partitioning theory. Environmental Science & Technology 35 7 (2001) 1394-1405
19. Kawamura K., and Kaplan I.R. Motor exhaust emissions as a primary source for dicarboxylic acids in Los Angeles ambient air. Environmental Science & Technology 21 (1987) 105-110
20. Khairou K.S., and Hassan H.M. Temperature-dependence of the electrical conductivity for cross-linked mono- and divalent metal-alginate complexes. High Performance Polymers 14 (2002) 93-102
21. Kojima M., Takahashi K., and Nakamura K. Cationic dye-sensitized degradation of sodium hyaluronate through photon induced electron transfer in the upper excited state. Photochemistry and Photobiology 74 3 (2001) 369-377
22. Kubatova A., Steckler T.S., Gallagher J.R., Hawthorne S.B., and Picklo M.J. Toxicity of wide-range polarity fractions from wood smoke and diesel exhaust particulate obtained using hot pressurized water. Environmental Toxicology and Chemistry 23 (2004) 2243-2250
23. McLaren R., Clark S.A.C., Ishii I., and Hitchcock A.P. Absolute oscillator-strengths from K-shell electron energy-loss spectra of the fluoroethenes and 1,3-perfluorobutadiene. Physical Review A 36 4 (1987) 1683-1701
24. Pascual Le Tallec L., Korwin-Zmijowska C., and Adolphe M. Limitations of alginate gels as a culture model for the study of the effects of UVA radiation on human dermal fibroblasts. Cell Biology and Toxicology 13 (1997) 95-102
25. Paul J., Williams G.P., and Hoffmann F.M. Carbon dioxide activation and alkali compound formation. I. Vibrational characterization of oxalate intermediates. Surface Science 531 3 (2003) 244-264
26. Petzold A., Ström J., Schröder F.P., and Kärcher B. Carbonaceous aerosol in jet engine exhaust: emission characteristics and implications for heterogeneous chemical reactions. Atmospheric Environment 33 17 (1999) 2689-2698
27. Schauer J.J., Rogge W.F., Hildemann L.M., Mazurek M.A., Cass G.R., and Simoneit B.R.T. Source apportionment of airborne particulate matter using organic compounds as tracers. Atmospheric Environment 30 22 (1996) 3837-3855
28. Shah S.D., Cocker D.R., Miller J.W., and Norbeck J.M. Emission rates of particulate matter and elemental and organic carbon from in-use diesel engines. Environmental Science & Technology 38 (2004) 2544-2550
29. Smith D.M., and Chughtai A.R. Photochemical effects in the heterogeneous reaction of soot with ozone at low concentrations. Journal of Atmospheric Chemistry 26 (1997) 77-91
30. Soares J.P., Santos J.E., Chierice G.O., and Cavalheiro E.T.G. Thermal behavior of alginic acid and its sodium salt. Eclectica Quimica 29 2 (2004) 57-63
31. Stoehr, J., 1992. NEXAFS Spectroscopy, Springer Series in Surface Science 25, first ed., Springer, Berlin Heidelberg New York, pp 203-229. ISBN:3-540-54422-4.
32. Stoehr J., and Bauchspiess K.R. Unified picture of near-edge and extended X-ray-absorption fine structure in low-Z molecules. Physical Review Letters 67 24 (1991) 3376-3379
33. Unknown Correspondent to Nature. Pollution-controlling the motor car. Nature 220 (1968) 1266
34. Zhang X., Ade H., Jacobsen C., Kirz J., Lindaas L., Williams S., and Wirick S. Microxanes-chemical contrast in the scanning-transmission X-ray microscope. Nuclear Instruments & Methods in Physics Research A 347 (1994) 431-435